An allylic rearrangement or allylic shift is an organic chemical reaction in which reaction at a center vicinal to a double bond causes the double bond...

bond. The Overman rearrangement (named after Larry Overman) is a Claisen rearrangement of allylic trichloroacetimidates to allylic trichloroacetamides...

dimer Wikiquote has quotations related to Allyl group. Allylic strain Carroll rearrangement Allylic palladium complex Tsuji–Trost reaction Propargylic/Homopropargylic...

rearrangement reaction, although these are not necessarily realistic. In allylic rearrangement, the reaction is indeed ionic. Three key rearrangement...

The Sommelet-Hauser rearrangement is an example of a [2,3]-sigmatropic reaction. The Stevens rearrangement is a [1,2]-rearrangement. A [3,3]-sigmatropic...

The Carroll rearrangement is a rearrangement reaction in organic chemistry and involves the transformation of a β-keto allyl ester into a α-allyl-β-ketocarboxylic...

The Overman rearrangement is a chemical reaction that can be described as a Claisen rearrangement of allylic alcohols to give allylic trichloroacetamides...

reactants, giving rise to unexpected products. The classical example is allylic rearrangement. When 1 mole of HCl adds to 1 mole of 1,3-butadiene, in addition...

The reaction allows the formation of allylic alcohols from allylic sulfoxides in a 2,3-sigmatropic rearrangement. The reaction is a powerful way to create...

The [2,3]-Wittig rearrangement is the transformation of an allylic ether into a homoallylic alcohol via a concerted, pericyclic process. Because the reaction...

Allylic strain (also known as A1,3 strain, 1,3-allylic strain, or A-strain) in organic chemistry is a type of strain energy resulting from the interaction...

substitutions can be accompanied by an allylic rearrangement as seen in reactions such as the Ferrier rearrangement. This type of mechanism is called an...

The aza-Cope rearrangements are examples of heteroatom versions of the Cope rearrangement, which is a [3,3]-sigmatropic rearrangement that shifts single...

carbonyl compound is favored. A general scheme for the rearrangement is shown below. (1) This rearrangement differs from similar isomerizations of carbohydrates...

The Ireland–Claisen rearrangement is a chemical reaction of an allylic ester with strong base to give an γ,δ-unsaturated carboxylic acid. Several reviews...

The Tsuji–Trost reaction (also called the Trost allylic alkylation or allylic alkylation) is a palladium-catalysed substitution reaction involving a substrate...

low energy pathway for decomposition of the phosphonium salt. An allylic rearrangement mechanism (SN2') has also been implicated in allyl and propargyl...

reaction control model in 1948. They were reinvestigating a certain allylic rearrangement reported in 1930 by Jakob Meisenheimer. Solvolysis of gamma-phenylallyl...

compounds, where the next carbon is saturated but substituted once, allylic rearrangement and related reactions are observed. Allyl Grignard reagents (organomagnesiums)...

The Ferrier rearrangement is an organic reaction that involves a nucleophilic substitution reaction combined with an allylic shift in a glycal (a 2,3-unsaturated...

with a thiophil to generate an allylic alcohol in what is known as the Mislow–Evans rearrangement. A [2,3]-rearrangement may result in carbon-carbon bond...

THF with indium powder: The Barbier reaction is accompanied by an allylic rearrangement to a terminal alkene The reaction of 3-Bromocyclohexene with benzaldehyde...

trimerisation Alkyne zipper reaction Allan–Robinson reaction Allylic rearrangement Amadori rearrangement Amine alkylation Angeli–Rimini reaction Andrussov oxidation...

Acta 30, 75, (1997) Ferrier, Robert J. (2001). "Substitution-with-Allylic-Rearrangement Reactions of Glycal Derivatives". Glycoscience. Topics in Current...

and plasticizers. Allyl alcohol is the smallest representative of the allylic alcohols. Allyl alcohol is produced commercially by the Olin and Shell...

group to the cyanophosphate 10 paving the way for an intramolecular allylic rearrangement to unstable β-allyl phosphate 11 (toluene, sealed tube) which is...

also be used in epoxide ring opening reaction as shown below. The allylic rearrangement reaction carried out using aluminium hydride is a SN2 reaction,...

lithium aluminium hydride removed the remaining amide group in 26. An allylic rearrangement to alcohol 27 (isostrychnine) was brought about by hydrogen bromide...

Due to the rearrangement of the double bond, terminal olefins tend to give primary allylic alcohols: Cyclic alkenes prefer to undergo allylic oxidation...

of more electropositive metals, and do not spontaneously undergo allylic rearrangement or epimerization. Additionally, organosilanes are rarely toxic and...