The bond-dissociation energy (BDE, D0, or DH°) is one measure of the strength of a chemical bond A−B. It can be defined as the standard enthalpy change...

average bond enthalpy, or bond strength. IUPAC defines bond energy as the average value of the gas-phase bond-dissociation energy (usually at a temperature...

energy of a sigma bond is the energy required for homolytic dissociation, but the actual excitation energy may be higher than the bond-dissociation energy...

the energy of the SOMO will be lowered, as will the bond dissociation energy. Bond dissociation energy is determined by multiple factors: Electronegativity...

generally stronger; the double bond of ethylene and triple bond of acetylene have been determined to have bond dissociation energies of 174 and 230 kcal/mol...

The energy required to break the bond is called the heterolytic bond dissociation energy, which is similar (but not equivalent) to homolytic bond dissociation...

groups to encourage the dynamic dissociation of the S−S bond; these chemistries can result in the bond dissociation energy being reduced to half (or even...

metal–metal bond lengths in these M2 molecules increase down the group from Ca2 to Ubn2. On the other hand, their metal–metal bond-dissociation energies generally...

benzylic positions is attributed to the low bond dissociation energy for benzylic C−H bonds. Specifically, the bond C6H5CH2−H is about 10–15% weaker than other...

from the original on 29 August 2016. Yu-Ran Luo and Jin-Pei Cheng "Bond Dissociation Energies" in CRC Handbook of Chemistry and Physics, 96th Edition...

reactive diatomic molecule diphosphorus, which has roughly half the bond-dissociation energy of dinitrogen. Huber, K. P.; Herzberg, G. (1979). Molecular Spectra...

value). Bond-dissociation energy Photodissociation, dissociation of molecules by photons (light, gamma rays, x-rays) Radiolysis, dissociation of molecules...

metal–metal bond-dissociation energies. The Uue–Uue bond should be slightly stronger than the K–K bond. From these M2 dissociation energies, the enthalpy...

In physics and chemistry, binding energy is the smallest amount of energy required to remove a particle from a system of particles or to disassemble a...

bond energy. For heteronuclear bonds, A−X, Pauling estimated the covalent contribution to the bond dissociation energy as being the mean of the bond dissociation...

etc. Bond-dissociation energy is the energy required to break one bond of a molecule or ion, usually separating an atom or atoms. Binding energy Look...

radical through homolytic dissociation of the carbon-cobalt bond. This bond is exceptionally weak, with a bond dissociation energy of 31 kcal/mol, which is...

allylic. The bond dissociation energy of C−H bonds on a doubly allylic centre is about 10% less than the bond dissociation energy of a C−H bond that is singly...

recorded ionization energy for a stable chemical compound. Bond-dissociation energy, the measure of the strength of a chemical bond calculated through...

(C6H5)2CH–H bond, which has a bond dissociation energy of 82 kcal mol−1 (340 kJ mol−1). This is well below the published bond dissociation energies for comparable...

energy decreases to 73 kcal/mol (305 kJ/mol). The single carbon to oxygen bond is shorter than that of the C−C bond. The bond dissociation energies for...

Carbon–fluorine bonds can have a bond dissociation energy (BDE) of up to 130 kcal/mol. The BDE (strength of the bond) of C–F is higher than other carbon–halogen...

entity Calculated: 1.381×10−23 J/K × 298.15 K / 2 = 2.1×10−21 J "Bond Lengths and Energies". Chem 125 notes. UCLA. Archived from the original on 23 August...

participate in bond formation the bond is shorter. Bond length is also inversely related to bond strength and the bond dissociation energy: all other factors...

therefore, very reactive with a bond-dissociation energy (117 kcal/mol or 490 kJ/mol) half that of dinitrogen. The bond distance has been measured at 1.8934...

fluoride. In comparison, the dissociation of difluorine to atomic fluorine requires cleaving a F–F bond with a bond dissociation energy of 36 kcal/mol. Consequently...

benzaldehyde and phosphorus pentachloride. The Ph3C-H bond is relatively weak, with a bond dissociation energy (BDE) of 81 kcal/mol, or about 24 kcal/mol less...

isoelectronic with dioxygen. The bond dissociation energy of H−NO is 49.5 kcal/mol (207 kJ/mol), which is unusually weak for a bond to the hydrogen atom. Nitroxyl...

rather than substitution takes place, due to the very high C–H bond dissociation energy (112 kcal/mol) that disfavors abstraction of a hydrogen atom. Addition...

incorrect predictions. Simple (Heitler–London) valence bond theory correctly predicts the dissociation of homonuclear diatomic molecules into separate atoms...