lithium amides are more common and more soluble than the other alkali metal analogs. Potassium amides are prepared by transmetallation of lithium amides with...

for preparing metal bis(trimethylsilyl)amides entails reactions of anhydrous metal chloride with an alkali metal bis(trimethylsilyl)amides via a salt metathesis...

(H−C(=O)−N(−CH3)2). Some uncommon examples of amides are N-chloroacetamide (H3C−C(=O)−NH−Cl) and chloroformamide (Cl−C(=O)−NH2). Amides are qualified as primary, secondary...

are produced by the reaction of Li metal with the appropriate amine: 2 Li + 2 R2NH → 2 LiNR2 + H2 Lithium amides are very reactive compounds. Specifically...

alkali metal. Azanide has a H–N–H bond angle of 104.5°. The alkali metal derivatives are best known, although usually referred to as alkali metal amides. Examples...

reactions. BiPh3 has been used to synthesize alkaline-earth metal amides and alkaline-earth metal cyclopentadienides. The difference between HgPh2 and BiPh3...

inorganic compound with the chemical formula KNH2. Like other alkali metal amides, it is a white solid that hydrolyzes readily. It is a strong base. Potassium...

superbase has a reactive metal exchanged for a hydrogen on a heteroatom, such as oxygen (unstabilized alkoxides) or nitrogen (metal amides such as lithium diisopropylamide)...

14, 2017). "High-performance light-emitting diodes based on carbene-metal-amides" (PDF). Science. 356 (6334): 159–163. arXiv:1606.08868. Bibcode:2017Sci...

Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "amides". doi:10.1351/goldbook.A00266 Buncel, E.; Menon, B. (1977). "Carbanion mechanisms:...

Matthew; Levine, Robert (1950). "Condensations Effected by the Alkali Amides. IV. The Reactions of Esters with Lithium Amide and Certain Substituted...

occurs typically in compounds such as butyl lithium, alkoxides, and metal amides such as sodium amide. Bases of carbon, nitrogen and oxygen without resonance...

1246/cl.2012.70. Ichikawa, Takayuki (2010). "Thermodynamic properties of metal amides determined by ammonia pressure-composition isotherms" (PDF). J. Chem...

meter are used. For very strong bases, such as organolithium reagent, metal amides, and hydrides, water is generally not a suitable solvent and indicators...

LiCl. These mixed Mg/Li amides of the type R2NMgCl⋅LiCl are used in organic chemistry as non-nucleophilic bases for metalation reactions of aromatic and...

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by directly reacting a metal with nitrogen or ammonia (sometimes after heating), or by thermal decomposition of metal amides: 3 Ca + N2 → Ca3N2 3 Mg...

Mercuric amidochloride is an inorganic compound with the formula Hg(NH2)Cl. It arises from the reaction of mercury(II) chloride and ammonia (Calomel reaction)...

electrophile.: 382  It reacts explosively with reducing agents such as metal amides, metals, hydrides, etc. Its hydrolysis in water occurs very slowly, unlike...

Acid–base-catalysed hydrolyses are very common; one example is the hydrolysis of amides or esters. Their hydrolysis occurs when the nucleophile (a nucleus-seeking...

Heavy Metal is an American science fantasy comics magazine, first published in 1977. The magazine is known primarily for its blend of dark fantasy, science...

by directly reacting a metal with nitrogen or ammonia (sometimes after heating), or by thermal decomposition of metal amides: 3 Ca + N2 → Ca3N2 3 Mg...

to the hydroxide ion in water. Ammonium salts behave as acids, and metal amides behave as bases. Some non-aqueous solvents can behave as bases, i.e....

Tris(dimethylamino)aluminium dimer, formally bis(μ-dimethylamino)tetrakis(dimethylamino)dialuminium, is an amide complex of aluminium. This compound may...

linked to one of the other ligands on the same metal centre in such a way that the angle at this metal between the centroid of the pi-system and the additional...

properties are strongly influenced by the organic ligands but the compound lacks metal-carbon bonds. It is used in chemical vapor deposition to prepare titanium...

normal, roughness, and metalness maps. They’re then baked with perspective from hi-poly 3D meshes," a workflow unique to Amid Evil. Rance described applying...

Tris(dimethylamino)gallium dimer, formally bis(μ-dimethylamino)tetrakis(dimethylamino)digallium, is an amide complex of gallium. This compound may be used...

with metal precursors containing built-in bases, such as alkoxides, metal amides, or metal acetate. The proligand may also be treated with a metal halide...

adsorbed monomer. Nucleophilic initiators include covalent or ionic metal amides, alkoxides, hydroxides, cyanides, phosphines, amines and organometallic...