proposed in which in the first slow step a proton is abstracted from nitroalkane 1 to a carbanion 2 followed by protonation to an aci-nitro 3 and finally...

In enzymology, a nitroalkane oxidase (EC 1.7.3.1) is an enzyme that catalyzes the chemical reaction a nitroalkane + H2O + O2 ⇌ {\displaystyle \rightleftharpoons...

reaction describing the acid hydrolysis of a salt of a primary or secondary nitroalkane (R−NO2) to an aldehyde (R−CH=O) or a ketone (R2C=O) and nitrous oxide...

Belgian chemist Louis Henry (1834–1913), it is the combination of a nitroalkane and an aldehyde or ketone in the presence of a base to form β-nitro alcohols...

Tetrachlorodinitroethane is a chlorinated nitroalkane produced by nitration of tetrachloroethylene with dinitrogen tetroxide or fuming nitric acid. It's...

the iodoalkane which is again treated with AgNO2 to get the nitroalkane. The nitroalkane is then treated with nitrous acid which is obtained by NaNO2...

reaction. The Knoevenagel condensation reaction of benzaldehydes with nitroalkanes is a classic general method for the preparation of nitroalkenes, which...

solvent-dependent. Quinones are produced from catechols and hydroquinones and even nitroalkanes are oxidized. CAN provides an alternative to the Nef reaction; for example...

nitro-Mannich reaction (or aza-Henry reaction) is the nucleophilic addition of a nitroalkane (or the corresponding nitronate anion) to an imine, resulting in the...

This exothermic reaction produces the four industrially significant nitroalkanes: nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane. The reaction...

350–450 °C. This exothermic reaction produces four industrially significant nitroalkanes: nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane. The reaction...

Trinitromethane, also referred to as nitroform, is a nitroalkane and oxidizer with chemical formula HC(NO2)3. It was first obtained in 1857 as the ammonium...

Vijayarajan; Watson, Donald A. (2017). "Nickel-Catalyzed C-Alkylation of Nitroalkanes with Unactivated Alkyl Iodides". Journal of the American Chemical Society...

Minor impurities include oxygen-containing substances such as amides and nitroalkanes. Oleylamine reacts with carboxylic acid to form its carboxylate salt...

the functional group RC(NO2)=NOH. They are prepared by the reaction of nitroalkanes with base and nitrite sources: RCH2NO2 + HNO2 → RC(NO2)=NOH + H2O The...

two proposed pathways for the reaction of d-amino acid oxidase with nitroalkane anions. Path A involved a nucleophilic attack on the coenzyme flavin...

1021/ie50459a035. A. S. Kende & J. S. Mendoza (1991). "Controlled reduction of nitroalkanes to alkyl hydroxylamines or amines by samarium diiodide". Tetrahedron...

can be synthesised by dehydrogenation of oximes or by dehydration of nitroalkanes.: 934–936  They can be used to synthesise isoxazoles.: 1201–1202  Nitriles...

aldehyde 20 to nitroalkene 21 occurs through enamine catalysis, yielding nitroalkane 25. Condensation of α,β-unsaturated aldehyde 22 with the organocatalyst...

in which alkyl halides react with metallic nitrites to a mixture to nitroalkanes and nitrites. Nitrite salts can react with secondary amines to produce...

of aromatic carboxylic acids from sulfonic acid and formates (1869). Nitroalkanes from alkyl iodides and silver nitrite (1872), used to distinguish 1°...

are highly explosive and very shock-sensitive, and may be dissolved in nitroalkanes to reduce their shock-sensitivity. Trinitroethanol reacts with carbon...

doi:10.1021/jo00357a040. Kende, A (1991). "Controlled reduction of nitroalkanes to alkyl hydroxylamines or amines by samarium diiodide". Tetrahedron...

by the reaction of propane and nitric acid. This reaction forms four nitroalkanes: nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane. 1-nitropropane...

Tetranitromethane or TNM is an organic oxidizer with chemical formula C(NO2)4. Its chemical structure consists of four nitro groups attached to one carbon...

2-Nitropropane (2-NP) is an organic compound with the formula (CH3)2CH(NO2). It is used as a solvent. It is a colorless liquid and is classified as a nitro...

Heptanitrocubane /ˌhɛptəˌnaɪtroʊˈkjuːbeɪn/ is an experimental high explosive based on the cubic eight-carbon cubane molecule and closely related to octanitrocubane...

pendant chiral backbones have shown to activate systems with tethered nitroalkane and ester motifs to induce asymmetric IMA. The utility of this transformation...

increasing a diesel fuel's cetane number. A few examples are nitrates, nitroalkanes, nitrocarbonates and peroxides. One of the main cetane improver additives...

Astronautics. doi:10.2514/6.1980-1293. Reich, Hans. "Bordwell pKa table: "Nitroalkanes"". University of Wisconsin Chemistry Department. Archived from the original...