• Thumbnail for Samarium(II) iodide
    Samarium(II) iodide is an inorganic compound with the formula SmI2. When employed as a solution for organic synthesis, it is known as Kagan's reagent...
    11 KB (958 words) - 20:35, 17 September 2024
  • Thumbnail for Reductions with samarium(II) iodide
    Reductions with samarium(II) iodide involve the conversion of various classes of organic compounds into reduced products through the action of samarium(II)...
    17 KB (1,966 words) - 20:27, 29 August 2024
  • Thumbnail for Samarium
    SmSe and SmTe, as well as samarium(II) iodide. Discovered in 1879 by French chemist Paul-Émile Lecoq de Boisbaudran, samarium was named after the mineral...
    72 KB (8,262 words) - 12:49, 25 October 2024
  • Samarium(III) iodide is an inorganic compound, a salt of samarium and hydroiodic acid with the chemical formula SmI 3. Samarium(III) iodide is prepared...
    3 KB (239 words) - 11:28, 3 January 2024
  • Reductive desulfonylation is typically accomplished with active metals or salts (sodium amalgam, aluminium amalgam, magnesium, samarium(II) iodide),...
    20 KB (2,248 words) - 12:28, 15 January 2024
  • Thumbnail for Nickel(II) iodide
    especially in conjunction with samarium(II) iodide. Like many nickel complexes, those derived from hydrated nickel iodide have been used in cross coupling...
    5 KB (382 words) - 00:57, 25 September 2023
  • Kristy Turner (category Articles with short description)
    degree with Prof. David J. Procter on Solid-phase approaches to heterocycles using a sulfur linker cleaved by reduction with samarium (II) iodide at University...
    8 KB (548 words) - 12:48, 2 August 2022
  • reduce alkali cations) compounds. Of these divalent lanthanides, Samarium(II) iodide, SmI2, is a common reducing agent that is used in a variety of synthetic...
    5 KB (663 words) - 21:51, 12 June 2022
  • Thumbnail for Iodine
    Iodine (category Articles with short description)
    tetraiodide, or an organic iodide. For example, molybdenum(IV) oxide reacts with aluminium(III) iodide at 230 °C to give molybdenum(II) iodide. An example involving...
    104 KB (11,657 words) - 18:48, 27 October 2024
  • Thumbnail for Neodymium(II) iodide
    Neodymium(II) iodide or neodymium diiodide is an inorganic salt of iodine and neodymium the formula NdI2. Neodymium uses the +2 oxidation state in the...
    11 KB (905 words) - 20:24, 3 January 2024
  • Thumbnail for Europium
    Europium (category Articles with short description)
    light), colorless europium(II) bromide (EuBr2), and green europium(II) iodide (EuI2). Europium forms stable compounds with all of the chalcogens, but...
    38 KB (4,709 words) - 22:39, 9 August 2024
  • Thumbnail for Ytterbium
    Ytterbium (category Articles with short description)
    the Aldol and Diels–Alder reactions. Ytterbium(II) iodide (YbI2) may be used, like samarium(II) iodide, as a reducing agent for coupling reactions. Ytterbium(III)...
    41 KB (5,222 words) - 10:29, 13 August 2024
  • Magnesium(I) dimer (category Articles with short description)
    be more selective when compared to other reducing agents, such as samarium(II) Iodide, SmI2,  that also acts as a one electron reductant. Mg(I) dimers...
    26 KB (2,795 words) - 06:49, 23 July 2024
  • Pinacol coupling reaction (category Articles with short description)
    tartaric acid derivatives can be obtained with high diastereoselectivity in a system of samarium(II) iodide and HMPA. A titanium-catalyzed photocatalytic...
    8 KB (891 words) - 19:54, 11 March 2024
  • compounds Samarium(II) chloride (SmCl2) Samarium(II) iodide (SmI2) Samarium(III) chloride hexahydrate (SmCl3·6H2O) Samarium(III) nitrate (Sm(NO3)3) Samarium(III)...
    26 KB (2,476 words) - 14:08, 21 September 2024
  • Lanthanide (category All articles with dead external links)
    Many of the iodides form soluble complexes with ethers, e.g. TmI2(dimethoxyethane)3. Samarium(II) iodide is a useful reducing agent. Ln(II) complexes can...
    107 KB (10,324 words) - 11:27, 28 October 2024
  • Thumbnail for Strychnine total synthesis
    Strychnine total synthesis (category Cleanup tagged articles with a reason field from March 2020)
    Syntheses of Strychnine and Englerin A: the Power of Reductive Cyclizations Triggered by Samarium Iodide". Angewandte Chemie International Edition. 50 (34):...
    39 KB (4,087 words) - 03:50, 29 February 2024
  • Thumbnail for Samarium(II) chloride
    Samarium(II) chloride (SmCl2) is a chemical compound, used as a radical generating agent in the ketone-mediated intraannulation reaction. Reduction of...
    3 KB (201 words) - 11:25, 3 January 2024
  • Thumbnail for Cobalt
    Cobalt (category Articles with French-language sources (fr))
    cobalt(II) are known: cobalt(II) fluoride (CoF2, pink), cobalt(II) chloride (CoCl2, blue), cobalt(II) bromide (CoBr2, green), cobalt(II) iodide (CoI2,...
    116 KB (11,878 words) - 18:48, 21 October 2024
  • Thumbnail for Europium(III) chloride
    Europium(III) chloride (category Chemical articles with multiple compound IDs)
    x-ray crystal structure of bis(pentamethylcyclopentadienyl) complexes of samarium and europium: (C5Me5)2Sm and (C5Me5)2Eu". Organometallics. 5 (7): 1285...
    7 KB (531 words) - 21:09, 4 February 2023
  • Thumbnail for Danishefsky Taxol total synthesis
    Subsequent oxidative cleavage with lead tetraacetate gave ketone 46. The epoxide protecting group was removed with samarium (II) iodide to give α-ß-unsaturated...
    15 KB (1,399 words) - 13:35, 26 August 2024
  • Thumbnail for Iron
    Iron (category Articles with short description)
    −20 °C, with oxygen and water excluded. Complexes of ferric iodide with some soft bases are known to be stable compounds. The standard reduction potentials...
    150 KB (17,078 words) - 12:22, 24 August 2024
  • Thumbnail for Mukaiyama Taxol total synthesis
    oxidation. The ring-closing reaction was a Reformatskii reaction with Samarium(II) iodide and acetic acid to acetate 18. The stereochemistry of this particular...
    11 KB (1,294 words) - 19:02, 27 November 2023
  • stereoselectivity. (12) Diastereoselective reduction of styrenes is possible with samarium(II) iodide. A distant alkene is untouched during this reaction, which provides...
    12 KB (1,352 words) - 00:01, 9 September 2023
  • Thumbnail for Holton Taxol total synthesis
    α-hydroxylactone 16 in 90% yield. The hydroxyl group was reductively removed using samarium(II) iodide to give an enol, and chromatography of this enol on...
    16 KB (1,478 words) - 18:34, 27 September 2023
  • Oxidation state (category Pages with missing ISBNs)
    bromo-relatives), as well as salts of such acids with group 1 and 2 metals. It also covers iodides, sulfides, and similar simple salts of these metals...
    47 KB (8,636 words) - 02:26, 27 October 2024
  • Thumbnail for Americium
    Americium (category Articles with short description)
    isotypic to LaF3 (space group P63/mmc) and the iodide to BiI3 (space group R3). The bromide is an exception with the orthorhombic PuBr3-type structure and...
    77 KB (9,268 words) - 15:13, 11 October 2024
  • Thumbnail for Uranium
    Uranium (redirect from Uranium(V) iodide)
    uranium are prepared by reaction with additional chlorine. All uranium chlorides react with water and air. Bromides and iodides of uranium are formed by direct...
    110 KB (12,380 words) - 11:06, 17 October 2024
  • Thumbnail for Einsteinium
    Einsteinium (category Articles with short description)
    curium and berkelium. Einsteinium(II) compounds can be obtained, for example, by reducing einsteinium(III) with samarium(II) chloride. Eighteen isotopes and...
    67 KB (7,944 words) - 07:00, 24 October 2024
  • Europium compounds (category Articles with short description)
    trihalide with hydrogen gas or europium: 2 EuX3 + H2 → 2 EuX2 + 2 HX Europium(II) iodide can also be obtained by direct treating the reagent with ammonium...
    42 KB (4,438 words) - 16:44, 19 February 2024