• Thumbnail for Tosyl group
    toluenesulfonyl group (tosyl group, abbreviated Ts or Tos) is a univalent functional group with the chemical formula −SO2−C6H4−CH3. It consists of a tolyl group, −C6H4−CH3...
    8 KB (876 words) - 04:29, 2 December 2024
  • Thumbnail for P-Toluenesulfonic acid
    P-Toluenesulfonic acid (category P-Tosyl compounds)
    alcohols, and other polar organic solvents. The CH3C6H4SO2 group is known as the tosyl group and is often abbreviated as Ts or Tos. Most often, TsOH refers...
    9 KB (640 words) - 16:59, 22 October 2024
  • Thumbnail for One-pot synthesis
    final step the reaction medium is neutralized to pH 7 (magenta) the tosyl group is eliminated as well. Ishikawa, H.; Suzuki, T.; Hayashi, Y. (2009)....
    3 KB (322 words) - 16:57, 18 July 2023
  • Thumbnail for Tosyl azide
    Tosyl azide is a reagent used in organic synthesis. Tosyl azide is used for the introduction of azide and diazo functional groups. It is also used as...
    2 KB (171 words) - 14:21, 28 February 2024
  • Thumbnail for Brosyl group
    anion of p-bromophenylsulfonic acid (BrC6H4SO−3). Tosyl group Tosylic acid Triflic acid Sulfonyl group Smith, Michael B.; March, Jerry (2007). March's Advanced...
    1 KB (91 words) - 22:49, 7 October 2024
  • Thumbnail for Tosyl phenylalanyl chloromethyl ketone
    Tosyl phenylalanyl chloromethyl ketone (TPCK) is a protease inhibitor. Its structural formula is 1-chloro-3-tosylamido-4-phenyl-2-butanone. TPCK is an...
    3 KB (239 words) - 10:51, 4 September 2024
  • Thumbnail for 4-Toluenesulfonyl chloride
    functional group. In characteristic manner, TsCl converts alcohols (abbreviated ROH) into the corresponding toluenesulfonate esters, or tosyl derivatives...
    6 KB (422 words) - 16:14, 28 July 2024
  • cyclization then forms the 5-membered ring, which reacts to eliminate the tosyl group. The last step is tautomerization to the pyrrole.[citation needed] By...
    33 KB (3,142 words) - 17:38, 21 February 2024
  • the substrate is an aldehyde, then elimination of the excellent tosyl leaving group can occur readily. Upon quenching, the resulting molecule is an oxazole...
    4 KB (267 words) - 22:21, 27 September 2024
  • Thumbnail for Samarium(II) iodide
    coupled with simple alkenes to form five, six or eight membered rings. Tosyl groups can be removed from N-tosylamides almost instantaneously, using SmI2...
    11 KB (958 words) - 20:35, 17 September 2024
  • Tosylhydrazone (category P-Tosyl compounds)
    is a functional group with the general structure RR'C=N-NH-Ts where Ts is a tosyl group. Organic compounds having this functional group can be accessed...
    5 KB (657 words) - 15:37, 7 August 2024
  • Thumbnail for Protecting group
    Troc (trichloroethyl chloroformate ) group – Removed by Zn insertion in the presence of acetic acid Tosyl (Ts) group – Removed by concentrated acid (HBr...
    57 KB (6,755 words) - 02:59, 9 November 2024
  • Concerns that the proposed symbol Ts may clash with a notation for the tosyl group used in organic chemistry were rejected, following existing symbols bearing...
    70 KB (11,042 words) - 16:06, 4 January 2025
  • typical catalyst is (cymene)R,R-HNCHPhCHPhNTs, where Ts refers to a tosyl group (SO2C6H4Me) and R,R refers to the absolute configuration of the two chiral...
    13 KB (1,292 words) - 14:45, 29 February 2024
  • Thumbnail for Dendrimer
    converting the alcohol groups to tosylate groups with tosyl chloride and pyridine. The tosyl group then served as leaving groups in another reaction with...
    58 KB (6,913 words) - 18:27, 31 December 2024
  • Thumbnail for Hurd–Mori 1,2,3-thiadiazole synthesis
    3-thiadiazoles through the reaction of hydrazone derivatives with an N-acyl or N-tosyl group reacted with thionyl chloride. An analogous reaction gives 1,2,3-selenadiazoles...
    2 KB (200 words) - 22:09, 22 September 2024
  • Ketenyl anion (category Functional groups)
    R group is more electron-withdrawing group, it becomes more likely to leave than tosyl group. For example, changing R group from cyclohexyl group (Cy)...
    20 KB (2,090 words) - 21:19, 19 March 2024
  • Thumbnail for Directed ortho metalation
    electrophilic N-tosylimine. The sulfoxide group is removed by hydrogenation with Raney nickel. ts is a tosyl group, ee stands for enantiomeric excess Contra-Friedel–Crafts...
    9 KB (1,041 words) - 06:11, 2 November 2024
  • Thumbnail for Plerixafor
    with tosyl groups. The product is treated with 1,4-bis(brommethyl)benzene and potassium carbonate in acetonitrile. After cleaving of the tosyl groups with...
    17 KB (1,685 words) - 07:47, 1 July 2024
  • Thumbnail for Sulfonyl group
    group is either a functional group found primarily in sulfones, or a substituent obtained from a sulfonic acid by the removal of the hydroxyl group,...
    2 KB (197 words) - 10:47, 9 October 2024
  • Thumbnail for Strychnine total synthesis
    hydrogen iodide and red phosphorus removed the tosyl group and hydrolysed both remaining ester groups to form diacid 13. Acetylation and esterification...
    39 KB (4,087 words) - 03:50, 29 February 2024
  • Thumbnail for Hydrazone
    Hydrazone (redirect from Tosyl hydrazone)
    aldehydes by the replacement of the oxygen =O with the =N−NH2 functional group. They are formed usually by the action of hydrazine on ketones or aldehydes...
    11 KB (1,154 words) - 13:23, 20 October 2024
  • completely missing an X chromosome Tennessine, symbol Ts, a chemical element Tosyl, a group in organic chemistry Transition state, of a chemical reaction Adobe...
    3 KB (413 words) - 12:18, 31 December 2024
  • original series of a particular media, in contrast to a spin-off Tosyl, a chemical group Gy's sampling theory (abbreviation) Star Trek: The Original Series...
    2 KB (286 words) - 18:49, 6 December 2024
  • Thumbnail for Aziridines
    Aziridines (category IARC Group 2B carcinogens)
    cycloaddition. When the N-substituent is an electron-withdrawing group such as a tosyl group, the carbon-nitrogen bond breaks, forming another zwitterion...
    16 KB (1,680 words) - 13:29, 4 September 2024
  • Thumbnail for Skeletal formula
    the use of Ts to represent tosyl never causes confusion); OTs is the tosylate group A protecting group or protective group is introduced into a molecule...
    28 KB (3,597 words) - 19:40, 16 December 2024
  • Thumbnail for Mitsunobu reaction
    1016/S0040-4039(01)81842-6. Hegedus, L. S.; Holden, M. S.; McKearin, J. M. (1984). "cis-N-TOSYL-3-METHYL-2-AZABICYCLO[3.3.0]OCT-3-ENE". Organic Syntheses. 62: 48; Collected...
    15 KB (1,591 words) - 22:35, 30 October 2024
  • Thumbnail for Proteinase K
    EDTA or by other serine protease inhibitors like Nα-Tosyl-Lys Chloromethyl Ketone (TLCK) and Nα-Tosyl-Phe Chloromethyl Ketone (TPCK)[citation needed]. Protease...
    10 KB (1,063 words) - 20:45, 11 September 2024
  • Sulfonyl halide (category Functional groups)
    C6H6 → RSO2C6H5 + HCl A readily available arylsulfonyl chloride source is tosyl chloride. The desulfonation of arylsulfonyl chlorides provides a route to...
    14 KB (1,485 words) - 20:44, 17 December 2024
  • Thumbnail for Alcohol (chemistry)
    H2O}}} Other types of ester are prepared in a similar manner−for example, tosyl (tosylate) esters are made by reaction of the alcohol with 4-toluenesulfonyl...
    35 KB (3,855 words) - 08:18, 21 November 2024