A transition metal fullerene complex is a coordination complex wherein fullerene serves as a ligand. Fullerenes are typically spheroidal carbon compounds...

elongated by 0.2 Å. In the fullerene complex Ru3(CO)9(C60), the fullerene binds to the triangular face of the cluster. In some complexes, the arene binds through...

A fullerene is an allotrope of carbon whose molecules consist of carbon atoms connected by single and double bonds so as to form a closed or partially...

inside a shell. Two types of endohedral complexes exist: endohedral metallofullerenes and non-metal doped fullerenes. In a traditional chemical formula notation...

Buckminsterfullerene is a type of fullerene with the formula C60. It has a cage-like fused-ring structure (truncated icosahedron) made of twenty hexagons...

Transition-metal dichalcogenide (TMD or TMDC) monolayers are atomically thin semiconductors of the type MX2, with M a transition-metal atom (Mo, W, etc...

square planar for some nickel complexes to octahedral for coordination complexes of cobalt. A range of transition metals can be found in biologically important...

it is for simple metals) n = 3 implies that the resistance is due to s-d electron scattering (as is the case for transition metals) n = 2 implies that...

Ti(C5H5)(C7H7) and (C60)Fe(C5H5Ph5) where the fullerene ligand is acting as a cyclopentadienyl analogue. Bis(benzene) complexes: M(C6H6)2, the best known example...

xenon gas. XeF 2 also forms coordination complexes with transition metal ions. More than 30 such complexes have been synthesized and characterized. Whereas...

MOFs increased their functionality by reacting organic units and metal-organic complexes with linkers. (4) Multifunctional MOFs incorporated multiple functionalities...

carbide coatings on a metal piece. The carbides of the group 4, 5 and 6 transition metals (with the exception of chromium) are often described as interstitial...

of the late transition metals, where metal-halide bonding is replete. Transition metal halide clusters are prevalent for the heavier metals: Zr, Hf, Nb...

(such as C25, a 25-carbon fullerene spheroid). The term is sometimes also used in reference to reactivity – for example, a complex that quickly reaches equilibrium...

copper(II) complexes oxidized H2. The 1960s witnessed the development of well defined homogeneous catalysts using transition metal complexes, e.g., Wilkinson's...

charge-transfer complex, λ-BETS2X compounds, graphite intercalation compounds and three-dimensional materials such as the alkali-doped fullerenes. Organic superconductors...

encountered in octahedral complexes of the transition metals. The phenomenon is very common in six-coordinate copper(II) complexes. The d9 electronic configuration...

compounds is +4, while +2 is found in carbon monoxide and transition metal carbonyl complexes. The largest sources of inorganic carbon are limestones,...

complexes between transition metals and carbonyl ligands. Metal carbonyls are complexes that are formed with the neutral ligand CO. These complexes are...

are stronger for endohedral metallo-fullerenes, in which a positively charged metal ion is trapped inside a fullerene cage and makes it more electronegative...

Different forms (allotropes) of pure carbon, such as diamond, graphite, fullerenes and carbon nanotubes are also excluded because they are simple substances...

example, diamond, graphite, and fullerenes are different allotropes of carbon. When a substance undergoes a phase transition (changes from one state of matter...

5, hydrated 18-crown-6 ether alkali metal ions, hydrated alkali metal ions, transition metal acetylene complexes, protonated ethylene, and IrO4+. Argon...

nanomaterials, such as fullerenes, and inorganic nanomaterials based on other elements, such as silicon. Examples of nanomaterials include fullerenes, carbon nanotubes...

and antimony, exhibiting behaviors typically associated with transition metal complexes. This is linked to a small energy gap between their filled and...

chemistry with transition metals. Coupling of sodium pentacyanocyclopentadiene (NaC5(CN)5) with transition metal halide salts generates metal complexes containing...

building blocks such as fullerenes, nanoparticles, and dendrimers becoming involved in synthetic systems. Supramolecular complexes are formed by non-covalent...

one each for the eight C−H bonds. Transition metal complexes that feature multiple bonds, such as the dihydrogen complex, have sigma bonds between the multiple...

heating and cooking. For instance, the class of nanomaterials called fullerenes are generated by burning gas, biomass, and candle. It can also be a byproduct...

superconducting pnictides (like fluorine-doped LaOFeAs) or organic superconductors (fullerenes and carbon nanotubes; though perhaps these examples should be included...