Trimethylsilyl chloride, also known as chlorotrimethylsilane is an organosilicon compound (silyl halide), with the formula (CH3)3SiCl, often abbreviated...

of trimethylsilylating agents include trimethylsilyl chloride and bis(trimethylsilyl)acetamide. Trimethylsilyl groups on a molecule have a tendency to...

methyl groups and a tert-butyl group. As such it is more bulky that trimethylsilyl chloride. It is a colorless or white solid that is soluble in many organic...

cyanide. It is prepared by the reaction of lithium cyanide and trimethylsilyl chloride: LiCN + (CH3)3SiCl → (CH3)3SiCN + LiCl The molecule exhibits the...

2-(Trimethylsilyl)ethoxymethyl chloride (SEM-Cl) is an organochlorine compound with the formula C6H15ClOSi, which was developed by Bruce H. Lipshutz during...

reagent in organic synthesis. It is prepared by the hydrolysis of trimethylsilyl chloride. The molecule is the protypical disiloxane and resembles a subunit...

(Trimethylsilyl)methyl chloride is the organosilicon compound with the formula (CH3)3SiCH2Cl. A colorless, volatile liquid, it is an alkylating agent that...

reacts with the combination of SCl2 and sulfuryl chloride (SO2Cl2) to form S4N4, trimethylsilyl chloride, and sulfur dioxide: 2 S(N(Si(CH3)3)2)2 + 2 SCl2...

and 195°C, respectively. Dehydration can also be effected with trimethylsilyl chloride: CoCl 2•6H 2O + 12 (CH 3) 3SiCl → CoCl 2 + 6[(CH 3) 3SiCl] 2O +...

Europium(III) chloride is a precursor to other europium compounds. It can be converted to the corresponding metal bis(trimethylsilyl)amide via salt metathesis...

hydrated iron(III) chloride can be converted to the anhydrous form by treatment with thionyl chloride or trimethylsilyl chloride: FeCl3·6H2O + 12 (CH3)3SiCl...

+ H2O → (CH3)3SiOH + HO3SCF3 It is far more electrophilic than trimethylsilyl chloride. Related to its tendency to hydrolyze, TMSOTf is effective for...

(BSTFA). BSA is prepared by treating acetamide with trimethylsilyl chloride in the presence of a base (Me = CH3, Et = C2H5): MeC(O)NH2 + 2...

of hydrazoic acid. Trimethylsilyl azide is commercially available. It may be prepared by the reaction of trimethylsilyl chloride and sodium azide: (CH3)3Si−Cl...

(Trimethylsilyl)methyllithium, which is commercially available as a THF solution, is usually prepared by treatment of (trimethylsilyl)methyl chloride with...

dimethyldichlorosilane ((CH3)2SiCl2), and trimethylsilyl chloride ((CH3)3SiCl) are produced by the Direct process. The reaction of methyl chloride with a silicon-copper alloy...

of reacting methyl chloride with silicon. The more useful products of this reaction are those for x = 1 (trimethylsilyl chloride), 2 (dimethyldichlorosilane)...

electrophile is trimethylsilyl chloride. To increase the rate of reaction, trimethylsilyl triflate may also be used in the place of trimethylsilyl chloride as a...

carbonitride thin films or coatings. Bis(trimethylsilyl)amine is synthesized by treatment of trimethylsilyl chloride with ammonia: 2 (CH3)3SiCl + 3 NH3 →...

However, for the preparation of bulk trimethylsilylated material, trimethylsilyl chloride may be preferred due to its lower cost. TMSI reacts with alkyl...

(Me2SiCl2) is of particular value as a precursor to silicones, but trimethylsilyl chloride (Me3SiCl) and methyltrichlorosilane (MeSiCl3) are also valuable...

Ammonium chloride is an inorganic chemical compound with the chemical formula NH4Cl, also written as [NH4]Cl. It is an ammonium salt of hydrogen chloride. It...

typically trimethylsilyl (-SiMe3), as illustrated by the synthesis of a trimethylsilyl ethers from alcohols and trimethylsilyl chloride (Me = CH3):...

Especially important silyl chlorides are dimethyldichlorosilane (Me 2SiCl 2), methyltrichlorosilane (MeSiCl 3), and trimethylsilyl chloride (Me 3SiCl) are all...

(Me3Si)3SiLi + HCl → (Me3Si)3SiH + LiCl Alternatively, the reaction of trimethylsilyl chloride and trichlorosilane in the presence of lithium delivers the silane...

25 °C(lit.) storage temp. −20 °C Trimethylsilyl cyclopentadiene is prepared by the reaction trimethylsilyl chloride (Me3SiCl) with sodium cyclopentadienide...

preparing metal bis(trimethylsilyl)amides entails reactions of anhydrous metal chloride with an alkali metal bis(trimethylsilyl)amides via a salt metathesis...

halides. Hexamethyldisilane arises efficiently by treatment of trimethylsilyl chloride with sodium: 2 Me3SiCl + 2 Na → Me3Si−SiMe3 + 2 NaCl Tetraphenyldiphosphine...

These reactive centers are typically "capped" by reaction with trimethylsilyl chloride: 2 Si(CH3)3Cl + [Si(CH3)2O]n−2[Si(CH3)2OH]2 → [Si(CH3)2O]n−2[Si(CH3)2OSi(CH3)3]2...

to a good leaving group using p-toluenesulfonyl chloride. Subsequent deprotection of the trimethylsilyl ether 37 gave tosylate 38, which underwent cyclization...