In chemistry, a Zintl phase is a product of a reaction between a group 1 (alkali metal) or group 2 (alkaline earth metal) and main group metal or metalloid...

that contains lead, or a Zintl phase compound with lead as the anion. Plumbides can be formed when lead forms a Zintl phase compound with a more metallic...

case of aluminium, tin, and bismuth, respectively). They can also form Zintl phases (half-metallic compounds formed between highly electropositive metals...

electropositive elements) affords polyarsenic compounds, which are members of the Zintl phases. See Category:Arsenides for a list. Greenwood, Norman N.; Earnshaw, Alan...

him to the discovery of the Zintl phases. The structure of Zintl phases were ionic, and the structure of the anion (aka Zintl ion) could result an electronic...

Quite recently, the aromaticity of planar Si56- rings occurring in the Zintl phase Li12Si7 was experimentally evidenced by Li solid state NMR. Metal aromaticity...

alkaline earth metal acetylides of the general formula MC≡CM are salt-like Zintl phase compounds, containing C2− 2 ions. Evidence for this ionic character can...

Potential uses include electrodes in lithium batteries. Li12Si7 has a Zintl phase with planar Si56− rings. Li NMR spectroscopy suggests these rings are...

1998). "Ba3AlO4H: Synthesis and Structure of a New Hydrogen-Stabilized Phase". Journal of Solid State Chemistry. 141 (2): 570–575. Bibcode:1998JSSCh...

synthesis and characterization of two broad classes of materials, notably Zintl phases and condensed transition metal halide clusters. Both classes of materials...

Peter; Schnelle, Walter; Zhao, Jing-Tai; Grin, Yuri (5 October 2015). "Zintl-Phase Sr3LiAs2H: Crystal Structure and Chemical Bonding Analysis by the Electron...

These can be classed as interstitial hydrides, Hydrogenated zintl phases, or Zintl phase hydrides. In the related silanides, SiH3− anions or groups occur...

with Increased Electron Count and Their Comparison with the Nominal Zintl Phase La3In5". Inorg. Chem. 40 (27): 7020–7026. doi:10.1021/ic010804v. PMID 11754285...

Hume-Rothery) compounds Size packing phases. e.g. Laves phases, Frank–Kasper phases and Nowotny phases Zintl phases The definition of a metal is taken to...

typeface designer (Palatino, Optima, Zapfino) Eduard Zintl, chemist and discoverer of the Zintl phase University and State Library Darmstadt "Welcome". Technische...

universe. In retrospect, the first nanoclustered ions discovered were the Zintl phases, intermetallics studied in the 1930s.[citation needed] The first set...

complex metallic alloy has to be, but the broadest definition includes Zintl phases, skutterudites, and Heusler compounds on the most simple end, and quasicrystals...

give a layered solid with the empirical formula GeH. The Ca sites in Zintl-phase CaGe2 interchange with the hydrogen atoms in the HCl solution, producing...

under 414K results in the release of hydrogen and the formation of a Zintl-phase MSi. If an alkali silande is rapidly heated to 500K another irreversible...

Asbrand, Matthias; Eisenmann, Brigitte (1993). "Na2[SnAs2], the first Zintl phase with a [SnAs2] framework based on adamantane analogous [Sn4As10] units"...

semimetal line, or the staircase. While it has also been called the Zintl border or the Zintl line these terms instead refer to a vertical line sometimes drawn...

tetrelarsenides, pnictidosilicates, or tetrelpnictides. They can be classed as Zintl phases or intermetallics. They are analogous to the nitridosilicates, phosphidosilicates...

for example in Laves phase and Hume-Rothery phases. Ligand-free intermetalloid clusters include also endohedrally filled Zintl clusters. A synonym for...

Nikolaus; Gärtner, Stefanie (2019-04-25). "Synthesis of the Tetragonal Phase of Zintl's NaTl and Its Structure Determination from Powder Diffraction Data"...

Darmstadt. Together with Herbert Schäfer, she extended the definition of Zintl phases. Eisenmann studied chemistry at the Ludwig Maximilian University of Munich...

obtained with reagent prepared from lithium and acetylene. Li2C2 is a Zintl phase compound and exists as a salt, with the formula [Li+]2[−C≡C−]. Its reactivity...

compounds are alloys with a defined stoichiometry and crystal structure. Zintl phases are also sometimes considered alloys depending on bond types. American...

(12 November 2019). "K2Ge3As3: Fiberlike Crystals of a Narrow-Band-Gap Zintl Phase with a One-Dimensional Substructure ∞1{(Ge3As3)2–}". Chemistry of Materials...

Raudaschl-Sieber, Gabriele; Fässler, Thomas F. (2024-04-19). "Na 3 Ge 2 P 3 : A Zintl Phase Featuring [P 3 Ge–GeP 3 ] Dimers as Building Blocks". Inorganic Chemistry...

give a layered solid with the empirical formula GeH. The Ca sites in Zintl phase CaGe2 interchange with the H atoms in the HCl solution, which leaves...