In chemistry, dehydrohalogenation is an elimination reaction which removes a hydrogen halide from a substrate. The reaction is usually associated with...

Alkynes are prepared from 1,1- and 1,2-dihaloalkanes by double dehydrohalogenation. The reaction provides a means to generate alkynes from alkenes,...

refrigerant in air conditioners. It is prepared by fluorination and dehydrohalogenation reactions starting with 1,1,1,3,3-pentachloropropane. Cheryl Hogue...

is a chemical compound formed by the loss of hydrogen chloride (dehydrohalogenation) from DDT, of which it is one of the more common breakdown products...

n-BuI, which can react with the RLi reagent formed, and by competing dehydrohalogenation reactions, in which n-BuLi serves as a base: 2 C4H9Br + RLi → 2 C4H9R...

In organic chemistry, an epoxide is a cyclic ether, where the ether forms a three-atom ring: two atoms of carbon and one atom of oxygen. This triangular...

reacts in a coupling reaction with epichlorohydrin, followed by dehydrohalogenation. Epoxy resins produced from such epoxy monomers are called glycidyl-based...

formation of urethane foams and epoxy resins. It is also useful in dehydrohalogenation reactions and Swern oxidations. Triethylamine is readily alkylated...

which is recycled typically. Sodium amide is a standard base for dehydrohalogenations. It induces the loss of two equivalents of hydrogen bromide from...

while iodine is the least reactive of them all. The facility of dehydrohalogenation follows the reverse trend: iodine is most easily removed from organic...

empirical rule for predicting the favored regiochemistry in the dehydrohalogenation of alkyl iodides, though it turns out that the rule is applicable...

amine to dichlorocarbene, a reactive intermediate generated by the dehydrohalogenation of chloroform. Two successive base-mediated dehydrochlorination steps...

trichloroethane to give aluminium trichloride, which in turn catalyses the dehydrohalogenation of the remaining trichloroethane to vinylidene chloride and hydrogen...

well. In the presence of a strong base, alkyl chlorides undergo dehydrohalogenation to give alkenes or alkynes. Alkyl chlorides react with magnesium...

palladium(0) to give allylpalladium chloride dimer, (C3H5)2Pd2Cl2. Dehydrohalogenation gives cyclopropene. Allyl chloride is highly toxic and flammable...

also been detected on the Moon. This compound may be made by the dehydrohalogenation of 1,4-dichloro-2-butyne by potassium hydroxide (in alcoholic medium)...

triflate). When an alkyl halide is used, the reaction is called a dehydrohalogenation. For unsymmetrical products, the more substituted alkenes (those...

diastereoisomer predominates). An example of modest stereoselectivity is the dehydrohalogenation of 2-iodobutane which yields 60% trans-2-butene and 20% cis-2-butene...

chloramine with the formula C5H10NCl. The resulting chloramine undergoes dehydrohalogenation to afford the cyclic imine. 13C NMR: (CDCl3, ppm) 47, 27.2, 25.2[citation...

[Specific proton acceptors as auxiliary bases in alkylation and dehydrohalogenation reactions]. Chemische Berichte (in German). 91 (2). Wiley-VCH: 380–392...

with C70 and higher fullerenes, but not with C60. It is useful for dehydrohalogenations. 1,5-Diazabicyclo[4.3.0]non-5-ene DABCO Kaupmees, K.; Trummal, A...

terminal acetylenes and active methylene compounds. It is useful in dehydrohalogenation reactions. Illustrating the latter behavior, potassium tert-butoxide...

of trimethylaniline by dibromoethane followed by ring closure and dehydrohalogenation. Nolan, Steven P. (2006). N-Heterocyclic Carbenes in Synthesis. Wiley-VCH...

Base-induced bimolecular dehydrohalogenation (an E2 type reaction mechanism). The optimum geometry for the transition state requires the breaking bonds...

reagent to give magnesium salts and an extended alkyl compound. In dehydrohalogenation reactions, the halogen and an adjacent proton are removed from halocarbons...

cycloaddition with dichloro ketene diazomethane insertion reaction dehydrohalogenation reaction with DMF Luche reduction to alcohol with sodium borohydride...

otherwise it dimerises to biphenylene. Early routes to benzyne involved dehydrohalogenation of aryl halides: Such reactions require strong base and high temperatures...

at the secondary position, which allows the molecule to undergo dehydrohalogenation easily to give propene, which escapes as a gas and can rupture closed...

base to induce dehydrochlorination to 2-chlorobuta-1,3-diene. This dehydrohalogenation entails loss of a hydrogen atom in the 3 position and the chlorine...

propargylic halides by SN2′ displacement by an organocuprate from dehydrohalogenation of certain dihalides from reaction of a triphenylphosphinyl ester...