• Thumbnail for Nickel(II) nitrate
    alumina. Pyrolysis of the resulting material gives forms of Raney nickel and Urushibara nickel. In homogeneous catalysis, the hexahydrate is a precatalyst...
    6 KB (391 words) - 23:51, 11 February 2024
  • Thumbnail for Nickel
    reactions. Raney nickel, a finely divided nickel-aluminium alloy, is one common form, though related catalysts are also used, including Raney-type catalysts...
    89 KB (9,740 words) - 09:36, 21 June 2024
  • Thumbnail for Hydrogenation
    imine using a Raney nickel catalyst, a popular heterogeneous catalyst. Partial hydrogenation of a resorcinol derivative using a Raney-Nickel catalyst. Hydrogenation...
    38 KB (4,071 words) - 16:46, 23 June 2024
  • 1,2,6-Hexanetriol (category CS1 German-language sources (de))
    is added to the reaction mixture to hydrolyse the acetal groups and Raney nickel is added as a hydrogenation catalyst. The hydrogenation under 20 atm...
    8 KB (823 words) - 01:16, 12 July 2024
  • Thumbnail for Transamination
    R'NH− → RR'NH + NH2− Symmetric secondary amines can be prepared using Raney nickel (2RNH2 → R2NH + NH3). And finally, quaternary ammonium salts can be dealkylated...
    5 KB (570 words) - 08:40, 16 March 2024
  • achieved by dealloying of Nickel-Zinc or Nickel-Aluminium alloys in alkaline solution, commonly referred to as Raney nickel. In cell tests the best performing...
    18 KB (1,648 words) - 23:41, 19 May 2024
  • reaction requires alkali metal hydroxides or alkoxides. Catalysts such as Raney Nickel are required to facilitate the hydrogen transfer steps. While the Guerbet...
    4 KB (468 words) - 16:02, 6 January 2022
  • Thumbnail for Meclizine
    Meclizine (category CS1 German-language sources (de))
    N-alkylation with 3-methylbenzaldehyde. The reductive agent is hydrogen, and Raney nickel is used as a catalyst. Meclizine is obtained and used as a racemate,...
    19 KB (1,577 words) - 14:45, 1 July 2024
  • Thumbnail for Procaine
    Procaine (category CS1 German-language sources (de))
    Finally, the nitro group is reduced by hydrogenation over Raney nickel catalyst. Chloroprocaine Peter DeMarco Procaine blockade "How long does numbness last...
    12 KB (1,132 words) - 06:08, 12 January 2024
  • Thumbnail for 4-Aminophenol
    methods, to yield 4-aminophenol. One method involves hydrogenation over a Raney Nickel catalyst. A second method involves selective reduction of the nitro group...
    8 KB (529 words) - 22:26, 31 May 2023
  • Thumbnail for Marcel Delépine
    Marcel Delépine (category Academic staff of the Collège de France)
    1935 he described a general method for catalytic hydrogenation with Raney nickel. Also, when experimenting with thiocarbonic esters and related bodies...
    4 KB (361 words) - 19:12, 15 March 2023
  • analyzing the behavior of various sulfur compounds in presesence of Raney nickel catalysts, advisor Heinrich Hauptmann, and joined the Faculty of Philosophy...
    6 KB (480 words) - 12:13, 18 January 2024
  • Thumbnail for Oxybuprocaine
    Oxybuprocaine (category CS1 German-language sources (de))
    hydrogenation over Raney-Nickel completes the synthesis of Oxybuprocaine (8). Topical anesthetic Anvisa (2023-03-31). "RDC Nº 784 - Listas de Substâncias Entorpecentes...
    7 KB (514 words) - 19:25, 4 October 2023
  • Thumbnail for Devarda's alloy
    Devarda's alloy (category CS1 German-language sources (de))
    Nitrite test Nascent hydrogen Marsh test Detection of: Arsine Stibine Raney nickel, prepared from an Al, Ni alloy also dissolved in concentrated NaOH Zinc-copper...
    9 KB (832 words) - 01:02, 16 July 2024
  • cyclohexane is produced by hydrogenation of benzene in the presence of a Raney nickel catalyst. Producers of cyclohexane account for approximately 11.4% of...
    18 KB (1,559 words) - 10:45, 19 April 2024
  • Thumbnail for Xylitol
    Purified xylose is catalytically hydrogenated into xylitol using a Raney nickel catalyst. The conversion changes the sugar (xylose, an aldehyde) into...
    28 KB (2,772 words) - 03:25, 25 June 2024
  • Thumbnail for Mercaptobenzothiazole
    upon the addition of base, reflecting deprotonation. Treatment with Raney nickel results in monodesulfurization, giving benzothiazole: C6H4(NH)SC=S +...
    12 KB (1,134 words) - 13:47, 12 January 2024
  • Thumbnail for Pyridine
    Pyridine (category CS1 German-language sources (de))
    bipyridines. Radical dimerization of pyridine with elemental sodium or Raney nickel selectively yields 4,4'-bipyridine, or 2,2'-bipyridine, which are important...
    76 KB (7,637 words) - 04:04, 15 July 2024
  • Thumbnail for Sodium azide
    phosphine, such as triphenylphosphine in the Staudinger reaction, with Raney nickel or with hydrogen sulfide in pyridine. Oseltamivir, an antiviral medication...
    22 KB (2,230 words) - 01:40, 8 July 2024
  • Thumbnail for Tert-Amyl alcohol
    Favorskii reaction to give 2-Methylbut-3-yn-2-ol, then hydrogenation with Raney nickel catalyst to give Tert-Amyl alcohol. Fusel alcohols like TAA are grain...
    15 KB (1,315 words) - 16:02, 17 April 2024
  • Thumbnail for Dextromethorphan
    was patented by Roche in 1950. The traditional synthetic route uses Raney nickel and has been further improved over time, for example by the use of ibuprofen...
    51 KB (4,622 words) - 08:08, 10 July 2024
  • Thumbnail for Metronidazole
    Metronidazole (category CS1 German-language sources (de))
    ethylenediamine and acetic acid, followed by treatment with lime, then Raney nickel. 2-Methylimidazole is nitrated to give 2-methyl-4(5)-nitroimidazole (2)...
    56 KB (5,105 words) - 00:28, 10 July 2024
  • Thumbnail for Hydrofuramide
    antihypertensive drug compound. Catalytic hydrogenation of hydrofuramide with Raney nickel in the presence of ammonia in ethanol yields mixtures of furfurylamine...
    6 KB (541 words) - 14:46, 28 October 2022
  • Thumbnail for Aldol reaction
    Aldol reaction (category CS1 German-language sources (de))
    is N,N-diisopropylethylamine. The thioether is removed in step 2 by Raney Nickel / hydrogen reduction Crimmins M. T.; King B. W.; Tabet A. E. (1997)....
    38 KB (4,009 words) - 23:36, 9 July 2024
  • Thumbnail for Fencamfamin
    functional groups can also be achieved simultaneously by the use of Raney nickel, and this transformation has recently been optimized by Russian chemists...
    11 KB (1,146 words) - 20:51, 10 March 2024
  • Thumbnail for Catalysis
    higher-order oxides, graphitic carbon, transition metal oxides, metals such as Raney nickel for hydrogenation, and vanadium(V) oxide for oxidation of sulfur dioxide...
    46 KB (5,233 words) - 21:50, 14 July 2024
  • Thumbnail for Ibuprofen
    catalytic hydrogenation of isobutylacetophenone is performed with either Raney nickel or palladium on carbon to lead into the key-step, the carbonylation of...
    60 KB (5,851 words) - 18:25, 7 July 2024
  • Thumbnail for Strychnine total synthesis
    benzylmercaptide) which was then reduced to unsaturated ester 18 by Raney nickel and hydrogen. Further reduction with hydrogen / palladium on carbon afforded...
    39 KB (4,087 words) - 03:50, 29 February 2024
  • List of organic reactions (category CS1 German-language sources (de))
    Irvine–Purdie methylation PUREX Quelet reaction Ramberg–Bäcklund reaction Raney nickel Rap–Stoermer condensation Raschig phenol process Rauhut–Currier reaction...
    38 KB (3,429 words) - 20:03, 6 June 2024
  • Thumbnail for Protecting group
    catalytic hydrogenation (palladium hydroxide on activated carbon), or Raney nickel in ethanol Ethoxyethyl ethers (EE) – Cleavage more trivial than simple...
    57 KB (6,755 words) - 23:19, 9 April 2024