• In organic chemistry, a cyclophane is a hydrocarbon consisting of an aromatic unit (typically a benzene ring) and a chain that forms a bridge between two...
    17 KB (1,857 words) - 21:31, 5 September 2024
  • Thumbnail for Catenane
    Catenane (category Cyclophanes)
    ether cyclophane based on para phenylene or naphthalene. X-ray diffraction shows that due to pi-pi interactions the aromatic group of the cyclophane is held...
    12 KB (1,342 words) - 23:07, 8 November 2023
  • Thumbnail for (2.2)Paracyclophane
    (2.2)Paracyclophane (category Cyclophanes)
    [2.2]Paracyclophane is a cyclophane that is applied in bio- and materials science. It was first synthesized by Brown and Farthing in 1949 by pyrolyzing...
    4 KB (236 words) - 14:52, 7 September 2024
  • Thumbnail for Cation–π interaction
    involved looking at the interactions of charged, nitrogenous molecules in cyclophane host–guest chemistry. It was found that even when anionic solubilizing...
    35 KB (4,104 words) - 14:03, 23 August 2024
  • Thumbnail for Crown ether
    Catenane derived from cyclobis(paraquat-p-phenylene)(a cyclophane with two viologen units) and a cyclic polyether (bis(para-phenylene-34-crown-10)). Carbon...
    14 KB (1,508 words) - 21:53, 26 April 2024
  • Thumbnail for Xylylene
    p-Xylylene dimerizes with moderate efficiency to give p-cyclophane: Further heating of the p-cyclophane gives poly(para-xylylene). o-Xylylenes (o-quinodimethanes)...
    8 KB (834 words) - 21:36, 29 December 2023
  • Thumbnail for Molecular shuttle
    wire are bulky triisopropylsilyl groups. The bead is a tetracationic cyclophane based on two bipyridine groups and two para-phenylene groups. The bead...
    2 KB (233 words) - 20:21, 13 February 2024
  • Staab (1978). "Versuche zur Darstellung zwitterionischer Donor-Acceptor-Cyclophane: Die diastereomeren 12,15-Bis(dimethylamino) - [2](2,5) - p...
    5 KB (465 words) - 17:27, 18 February 2024
  • Thumbnail for Parylene
    during the coating process by evaporating the cyclic dimer [2.2]para-cyclophane at a relatively low temperature, then decomposing the vapor at 450–700 °C...
    39 KB (4,773 words) - 00:29, 19 March 2024
  • Cylindrocyclophanes (category Cyclophanes)
    Cylindrocyclophanes are a class of cyclophane, a group of aromatic hydrocarbons composed of two benzene rings attached in a unique structure. Cylindrocyclophanes...
    10 KB (1,067 words) - 12:05, 23 July 2022
  • Thumbnail for Meta-selective C–H functionalization
    or para- C-H functionalization does not work because the corresponding cyclophane-like cyclic pre-transition state is highly strained. Thus, while ortho-selectivity...
    17 KB (1,947 words) - 20:49, 22 July 2024
  • Oregon. He is known for his work on aromatic compounds, particularly cyclophanes, and a name reaction, the Boekelheide reaction, is named after him. Boekelheide...
    7 KB (516 words) - 01:10, 16 May 2024
  • include tetrahedranes, propellanes, cubane-type clusters, fenestranes and cyclophanes. March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure...
    2 KB (224 words) - 10:09, 6 June 2023
  • Figure 4. Cyclophane anthracene adduct...
    6 KB (782 words) - 13:31, 22 September 2024
  • Thumbnail for Superphane
    Superphane (category Cyclophanes)
    Superphane is a 6-fold bridged cyclophane with all arene positions in the benzene dimer taken up by ethylene spacers. The compound has been of some scientific...
    5 KB (478 words) - 17:16, 22 January 2023
  • Thumbnail for Tubocurarine chloride
    Tubocurarine chloride (category Cyclophanes)
    Tubocurarine (also known as d-tubocurarine or DTC) is a toxic benzylisoquinoline alkaloid historically known for its use as an arrow poison. In the mid-1900s...
    19 KB (2,043 words) - 16:59, 9 September 2023
  • Thumbnail for Seyferth–Gilbert homologation
    1021/jo501803f Lidija Bondarenko; Ina Dix; Heino Hinrichs; Henning Hopf (2004). "Cyclophanes. Part LII:1 Ethynyl[2.2]paracyclophanes – New Building Blocks for Molecular...
    6 KB (529 words) - 03:16, 22 March 2024
  • Thumbnail for Lythranidine
    Lythranidine (category Cyclophanes)
    first isolated from the plant Lythrum anceps. It contains a 17-membered cyclophane ring. Several laboratory syntheses have been reported. Fujita, E; Fuji...
    4 KB (166 words) - 21:03, 11 July 2024
  • Thumbnail for Cyclobis(paraquat-p-phenylene)
    Cyclobis(paraquat-p-phenylene) (category Cyclophanes)
    (formally a derivative of paraquat) belongs to the class of cyclophanes, and consists of aromatic units connected by methylene bridges. It is...
    9 KB (938 words) - 15:02, 7 September 2024
  • Thumbnail for Α-Cyclodextrin
    "Surveying macrocyclic chemistry: from flexible crown ethers to rigid cyclophanes". Chemical Society Reviews. 46 (9): 2367–2650. doi:10.1039/c7cs00185a...
    5 KB (372 words) - 23:07, 6 March 2024
  • (superatoms) of a simplified skeleton by multiatomic structures". Whilst the cyclophane name describes only a limited number of sub-structures of benzene rings...
    3 KB (323 words) - 20:56, 19 October 2023
  • Thumbnail for Aromaticity
    Aromatic properties are tested to the limit in a class of compounds called cyclophanes. A special case of aromaticity is found in homoaromaticity where conjugation...
    22 KB (2,764 words) - 21:10, 20 June 2024
  • therefore convenient for use in supramolecular systems. More complex cyclophanes, and cryptands can be synthesised to provide more tailored recognition...
    35 KB (3,889 words) - 22:05, 25 November 2023
  • Thumbnail for Stevens rearrangement
    elimination. In one application a double-Stevens rearrangement expands a cyclophane ring. The ylide is prepared in situ by reaction of the diazo compound...
    6 KB (697 words) - 02:43, 6 April 2023
  • Thumbnail for Macrocycle
    "Surveying macrocyclic chemistry: from flexible crown ethers to rigid cyclophanes". Chemical Society Reviews. 46 (9): 2459–2478. doi:10.1039/c7cs00185a...
    27 KB (3,288 words) - 22:37, 24 August 2024
  • compound, the color transition can be made in about 180 milliseconds. The cyclophane version of HABI reverts to colorless just as fast as the UV light is off...
    949 bytes (119 words) - 19:39, 27 October 2022
  • Thumbnail for Fraser Stoddart
    distinctive colouring has led to coining the term 'little blue box' for cyclophane, an important π-acceptor used to synthesize mechanically bonded structures...
    40 KB (3,227 words) - 00:49, 14 August 2024
  • Calixarene (category Cyclophanes)
    IUPAC definition calixarenes: Originally macrocyclic compounds capable of assuming a basket (or 'calix') shaped conformation. They are formed from p-hydrocarbyl...
    19 KB (2,105 words) - 07:28, 26 May 2024
  • Thumbnail for N-Formylpiperidine
     451. Lidija Bondarenko; Ina Dix; Heino Hinrichs; Henning Hopf (2004). "Cyclophanes. Part LII:1 Ethynyl[2.2]paracyclophanes – New Building Blocks for Molecular...
    3 KB (157 words) - 20:03, 27 December 2022
  • Thumbnail for Supramolecular catalysis
    PMID 9122156. Diederich, F.; Mattei, P. (1997). "Catalytic Cyclophanes. Part XI. A Flavo-thiazolio-cyclophane as a Biomimetic Catalyst for the Preparative-scale...
    36 KB (3,876 words) - 09:47, 26 September 2024