In organometallic chemistry, a sandwich compound is a chemical compound featuring a metal bound by haptic, covalent bonds to two arene (ring) ligands....

Half sandwich compounds, also known as piano stool complexes, are organometallic complexes that feature a cyclic polyhapto ligand bound to an MLn center...

others). Metallocenes are a subset of a broader class of compounds called sandwich compounds. In the structure shown at right, the two pentagons are the...

also called the "sandwich standard error" Sandwich theorem Sandwich assay, a type of immunoassay Sandwich compounds in chemistry Sandwich (horse) (born 1928)...

varied, including cyanide complexes, carbonyl complexes, sandwich and half-sandwich compounds. Prussian blue or "ferric ferrocyanide", Fe4[Fe(CN)6]3, is...

compound. In it, the U-Cl bond is an ionic bond, while the bonds with the three cyclopentadienyl ligands are covalent of the type found in sandwich compounds...

varied, including cyanide complexes, carbonyl complexes, sandwich and half-sandwich compounds. Prussian blue or "ferric ferrocyanide", Fe4[Fe(CN)6]3, is...

with some metals, including yttrium, lanthanides, and actinides. The sandwich compound uranocene (U(COT)2) features two η8-COT ligands. In bis(cyclooctatetraene)iron...

nucleophilic substitution. Organocobalt compounds are known with alkene, allyl, diene, and Cp ligands. A famous sandwich compound is cobaltocene, a rare example...

is a common ligand for ruthenium. The parent compound is [(η6-cymene)RuCl2]2. This half-sandwich compound is prepared by the reaction of ruthenium trichloride...

an organometallic compound with the formula Fe(C5H5)2. The molecule is a complex consisting of two cyclopentadienyl rings sandwiching a central iron atom...

(Cp2Fe2(CO)4). Monometallic compounds featuring only one Cp ring are often known as half sandwich compounds or as piano stool compounds, one example being...

Unlike the prevalence of cobalt(II) complexes, compounds of rhodium(II) are rare. The sandwich compound rhodocene is one example, even it exists in equilibrium...

Organouranium chemistry Chromocene Metallocene Osmocene Rhodocene Sandwich compound Hieber, W.; Fischer, E. O. (1952). "Ũber den Mechanismus der Kohlenoxydreaktion...

The Knölker complex is an organoiron compound, which is a catalyst for transfer hydrogenation. The complex features an hydroxycyclopentadienyl ligand bound...

of Sandwich, PC, FRS (13 November 1718 – 30 April 1792) was a British statesman who succeeded his grandfather Edward Montagu, 3rd Earl of Sandwich as...

[(thf)3Ca{μ-C6H3-1,3,5-Ph3}Ca(thf)3] also described in 2009 is an inverse sandwich compound with two calcium atoms at either side of an arene. Olefins tethered...

experiments and correctly arrived at a cationic bisarene chromium sandwich compound (ArH2Cr+). Bis(benzene)chromium itself was discovered around the same...

MgCp2, is an organometallic compound with the formula Mg(η5-C5H5)2. It is an example of an s-block main group sandwich compound, structurally related to...

sides of a central metal atom. Such organometallic compounds are also known as sandwich compounds. The rapid growth of organometallic chemistry is often...

is an organoruthenium compound with the formula (C5H5)2Ru. This pale yellow, volatile solid is classified as a sandwich compound and more specifically...

Plutonium also forms a sandwich complex with 1,4-bis(trimethylsilyl)cyclooctatetraenyl (1,4-COT’’) and its 1,3 isomer. This compound is prepared by the oxidation...

(Benzene)ruthenium dichloride dimer is the organoruthenium compound with the formula [(C6H6)RuCl2]2. This red-coloured, diamagnetic solid is a reagent...

dibenzenechromium. The compound played an important role in the development of sandwich compounds in organometallic chemistry and is the prototypical complex containing...

catalyst 1973 Nobel prize Geoffrey Wilkinson and Ernst Otto Fischer on sandwich compounds 1981 Nobel prize Roald Hoffmann and Kenichi Fukui for creation of...

In chemistry, decomplexation refers to the removal of a ligand from a coordination complex. Decomplexation is of particular interest when the ligand has...

Bis(cyclooctatetraene)iron is an organoiron compound with the formula Fe(C8H8)2, abbreviated Fe(COT)2. It is an air-sensitive black solid that is soluble...

Chandrasekhar. (1988-07-01). "Electronic structure of triple-decker sandwich compounds with P5, P6, As5, and CnHn as middle rings". Organometallics. 7 (7):...

v t e Cobalt compounds Cobalt(I) HCo(CO)4 Cobalt(II) CoBr2 Co(CN)2 CoCO3 CoC2O4 CoCl2 Co(ClO3)2 Co(ClO4)2 CoF2 Co(HCO2)2 CoI2 Co(NO3)2 Co3(PO4)2 Co(OAc)2...

Methylcyclopentadienyl manganese tricarbonyl (MMT or MCMT) is an organomanganese compound with the formula (C5H4CH3)Mn(CO)3. Initially marketed as a supplement for...