Trimethylaluminium is one of the simplest examples of an organoaluminium compound. Despite its name it has the formula Al2(CH3)6 (abbreviated as Al2Me6...

pyrophoric. It is an industrially important compound, closely related to trimethylaluminium. The structure and bonding in Al2R6 and diborane are analogous (R...

depending on the steric bulk of the groups attached. For example, trimethylaluminium exists as a dimer, but trimesitylaluminium adopts a monomeric structure...

two-electron bonds. This pattern is seen for dimethyl beryllium and trimethylaluminium. In the case of methyl lithium, the methyl group can be shared (bonded...

such as triethylborane (Et3B), and organoaluminium compounds such as trimethylaluminium (Me3Al). A naturally occurring organometallic complex is methylcobalamin...

alkene polymerization. MAO is prepared by the incomplete hydrolysis of trimethylaluminium, as indicated by this idealized equation: n Al(CH3)3 + n H2O → (Al(CH3)O)n...

derivatives of metal and nonmetal hydrides (diethylaluminium hydride, trimethylaluminium, triethylaluminium, butyllithium), with a few exceptions (i.e. dimethylmercury...

equilibrium mixture of the monomer and dimer. These dimers, such as trimethylaluminium (Al2Me6), usually feature tetrahedral Al centers formed by dimerization...

the formula Ga(CH3)3. It is a colorless, pyrophoric liquid. Unlike trimethylaluminium, TMG adopts a monomeric structure. When examined in detail, the monomeric...

reacts with a variety of Lewis acids such as iodine, phenol, and trimethylaluminium, and its base parameters in the ECW model are EB = 1.80 and CB = 1...

the formula In(CH3)3. It is a colorless, pyrophoric solid. Unlike trimethylaluminium, but akin to trimethylgallium, TMI is monomeric. TMI is prepared by...

organometallic chemistry. Illustrative organoaluminium compounds are the dimer trimethylaluminium, the monomer triisobutylaluminium, and the titanium-aluminium compound...

Trimethylborane can be made on a small scale with a 98% yield by reacting trimethylaluminium in hexane with boron tribromide in dibutyl ether as a solvent. Yet...

selected organometallic compounds, most often triethylaluminium, trimethylaluminium, and some other alkyl and aryl derivatives of aluminium, magnesium...

deposition, Al2O3 films can be prepared by the chemical exchange between trimethylaluminium (Al(CH3)3) and H2O: 2 Al(CH3)3 + 3 H2O → Al2O3 + 6 CH4 H2O in the...

there are only 12 valence electrons. A similar situation exists in trimethylaluminium. The electron deficiency in such compounds is similar to metallic...

titanocene that arises from the reaction of titanocene dichloride with trimethylaluminium. It is used for the "olefination" reactions. Arenes, such as C6(CH3)6...

-magnesium halide methylmagnesium chloride Alkylaluminium Al2R6 -aluminium trimethylaluminium Silyl ether R3SiOR -silyl ether trimethylsilyl triflate...

Milder methylating agents include tetramethyltin, dimethylzinc, and trimethylaluminium. Chemistry portal Biology portal Bisulfite sequencing – the biochemical...

as called agostic complexes. This bonding pattern is also seen in trimethylaluminium, which forms a dimer Al2(CH3)6 with the carbon atoms of two of the...

illustration of one reaction cycle of the ALD process, using the trimethylaluminium (TMA) -water process to make thin aluminium oxide films as (simplified)...

Zirconocene dichloride catalyzes the carboalumination of alkynes by trimethylaluminium to give a (alkenyl)dimethylalane, a versatile intermediate for further...

designed to minimize the production of waste products. Aluminium Trimethylaluminium (TMA or TMAl), Liquid Triethylaluminium (TEA or TEAl), Liquid Gallium...

Uranium hexafluoride tetraethyl lead tetramethyl lead tetrabutyl tin trimethylaluminium dimethylmercury Diethylzinc triethylborane Chromate Permanganate Ferroin...

equilibrium mixture of the monomer and dimer. These dimers, such as trimethylaluminium (Al2Me6), usually feature tetrahedral Al centers formed by dimerization...

Growth temperature ranges between 800 and 1100 °C. Introduction of trimethylaluminium and/or trimethylindium is necessary for growing quantum wells and...

Transcription mediated amplification Trimethylamine, (CH3)3N, a simple amine Trimethylaluminium, (CH3)3Al Trimesic acid Psychedelic or hallucinogenic drugs that are...

the Corey lactone (1) by reaction with methyl Grignard reagent or trimethylaluminium. The resulting mixture of tertiary carbinols (2) is transformed to...

geometry and follows the octet rule. By contrast, triethylaluminium and trimethylaluminium feature bridging alkyl groups and these compounds violate the octet...

Barbados, Saint Vincent, and Grenada were used to photograph the trimethylaluminium trails released from the projectile during launch, which provided...