organic chemistry, an alkyne is an unsaturated hydrocarbon containing at least one carbon—carbon triple bond. The simplest acyclic alkynes with only one triple...

The azide-alkyne Huisgen cycloaddition is a 1,3-dipolar cycloaddition between an azide and a terminal or internal alkyne to give a 1,2,3-triazole. Rolf...

Alkyne metathesis is an organic reaction that entails the redistribution of alkyne chemical bonds. The reaction requires metal catalysts. Mechanistic studies...

copper-catalyzed reaction of an azide with an alkyne to form a 5-membered heteroatom ring: a Cu(I)-catalyzed azide-alkyne cycloaddition (CuAAC). The first triazole...

An alkyne trimerisation is a [2+2+2] cycloaddition reaction in which three alkyne units (C≡C) react to form a benzene ring. The reaction requires a metal...

organometallic chemistry, a transition metal alkyne complex is a coordination compound containing one or more alkyne ligands. Such compounds are intermediates...

The alkyne zipper reaction is an organic reaction that involves isomerization of a non terminal alkyne into a terminal alkyne. This reaction was first...

catalyst to synthesize indoles from an ortho-iodoaniline and a disubstituted alkyne. It is also known as Larock heteroannulation. The reaction is extremely...

(alkanes), or unsaturated, with double bonds (alkenes) or triple bonds (alkynes). If other elements (heteroatoms) are bound to the carbon chain, the most...

+ O2 → 2PhC2C2Ph + 2Cu2O In the related Eglinton reaction two terminal alkynes are coupled by a copper(II) salt such as cupric acetate. 2 R − ≡ − H →...

and some alkynes also undergo polymerization by opening of the multiple bonds to produce polyethylene, polybutylene, and polystyrene. The alkyne acetylene...

on alkynes. Again the mode of action is syn and secondary reaction products are aldehydes from terminal alkynes and ketones from internal alkynes. In...

magnesium and the alkyne Me3SiC2SiMe3, in THF. This synthesis was immediately used to make other similar titanocene and zirconocene alkyne complexes. Under...

formula C2H2 and structure H−C≡C−H. It is a hydrocarbon and the simplest alkyne. This colorless gas is widely used as a fuel and a chemical building block...

In organic chemistry, a cycloalkyne is the cyclic analog of an alkyne (−C≡C−). A cycloalkyne consists of a closed ring of carbon atoms containing one or...

hydridoborate ionic complex. Metal free hydrogenation of unactivated internal alkynes to cis-alkenes is readily achieved using FLP-based catalysts. The condition...

with various forms of lead or sulfur. It is used for the hydrogenation of alkynes to alkenes (i.e. without further reduction into alkanes). It is named after...

whereby an alkoxy group located on the α-carbon of an alkyne is replaced by another nucleophile. The alkyne reacts first with dicobalt octacarbonyl, from which...

ways in which substituent molecules can be added to an alkene (R2C=CR2) or alkyne (RC≡CR). The concepts of syn and anti addition are used to characterize...

catalyzed by the enzyme acetylcholinesterase, beginning with an azide and an alkyne. He discovered several chemical reactions which have transformed asymmetric...

(alkyne). It is called a conjugated enyne when the double and triple bonds are conjugated. The term is a contraction of the terms alkene and alkyne. The...

propene and argentum, which refers to the typical reaction of the terminal alkynes with silver salts. The term homopropargylic designates in the same manner...

reaction between an enolizable carbonyl such as an ester or ketone and an alkyne or alkene, giving a cyclic product with a new carbon-carbon bond. As initially...

series of chemical reactions designed to transform an aldehyde into an alkyne.[1][2][3] The formation of the 1,1-dibromoolefins via phosphine-dibromomethylenes...

aldol condensation. The Prins reaction occurs when a nucleophilic alkene or alkyne reacts with an aldehyde as electrophile. The product of the Prins reaction...

compound with the formula CH3CH2C≡CH. It is a terminal alkyne. The compound is a common terminal alkyne substrate in diverse studies of catalysis. It is a...

Phenylacetylene is an alkyne hydrocarbon containing a phenyl group. It exists as a colorless, viscous liquid. In research, it is sometimes used as an analog...

well as copper co-catalyst to form a carbon–carbon bond between a terminal alkyne and an aryl or vinyl halide. R1: aryl or vinyl R2: arbitrary X: I, Br, Cl...

for unsubstituted triazoles is the Huisgen azide-alkyne 1,3-dipolar cycloaddition: a azide and an alkyne react at high temperature to form a ring. However...

alkyne and a haloalkyne catalyzed by a copper(I) salt such as copper(I) bromide and an amine base. The reaction product is a 1,3-diyne or di-alkyne....