Ferrocene is an organometallic compound with the formula Fe(C5H5)2. The molecule is a complex consisting of two cyclopentadienyl rings sandwiching a central...
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Ferrocene-containing dendrimers are dendrimers that contain ferrocene substituents. Some ferrocene-containing dendrimers feature ferrocene cores and others...
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Decamethylferrocene (redirect from Decamethyl Ferrocene)
anions (Cp*−, (CH3)5C−5). It can also be viewed as a derivative of ferrocene, with a methyl group replacing each hydrogen atom of its cyclopentadienyl...
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ferrocene, commonly abbreviated dppf, is an organophosphorus compound commonly used as a ligand in homogeneous catalysis. It contains a ferrocene moiety...
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slightly above room temperature. Cobaltocene was discovered shortly after ferrocene, the first metallocene. Due to the ease with which it reacts with oxygen...
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Antiknock agent (section Ferrocene)
additive) MTBE Ethanol Methylcyclopentadienyl manganese tricarbonyl (MMT) Ferrocene Iron pentacarbonyl Toluene Isooctane BTEX - a hydrocarbon mixture of benzene...
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D. Dunitz, L. E. Orgel and R. A. Rich, who confirmed the structure of ferrocene by X-ray crystallography. The correct structure, in which the molecule...
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Ferrocenophanes (redirect from Ansa ferrocenes)
Ferrocenophanes, also called ansa ferrocenes (from ansa: handle in greek), are organometallic compounds which are derived from ferrocene. They are a subset of ansa-metallocenes...
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Ferrocenium tetrafluoroborate (category Ferrocenes)
oxidizing agents, and the reduced product, ferrocene, is inert and readily separated from ionic products. The ferrocene–ferrocenium couple is often used as a...
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1'‑Bis(diphenylphosphino)ferrocene]palladium(II) dichloride is a palladium complex containing the bidentate ligand 1,1'-bis(diphenylphosphino)ferrocene (dppf), abbreviated...
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a staggered conformation. The first metallocene to be classified was ferrocene, and was discovered simultaneously in 1951 by Kealy and Pauson, and Miller...
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a reduction potential of 0.67 V versus ferrocene/ferrocenium (acetonitrile solution) or 0.70 V versus ferrocene/ferrocenium (dichloromethane solution)...
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neighboring metal iron forms an air-stable, low-spin derivative in the form of ferrocene (Fe(C5H5)2). When conducted under an atmosphere of carbon monoxide, reduction...
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bound the metal centre; or, in organometallic compounds, such as the ferrocene [Fe(C2H5)2], where two cyclopentadienyl anions are bound to the FeII centre...
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1,1'-Ferrocenediisocyanate (redirect from 1,1'-Ferrocene diisocyanate)
the formula Fe(C5H4NCO)2. It is the simplest diisocyanate derivative of ferrocene. It can be synthesized by the Curtius rearrangement of the diacyl azide...
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Acetylferrocene (category Ferrocenes)
organoiron compound with the formula (C5H5)Fe(C5H4COCH3). It consists of ferrocene substituted by an acetyl group on one of the cyclopentadienyl rings. It...
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Dunitz, Orgel, and Rich described the structure of the "sandwich complex" ferrocene by X-ray crystallography where an iron atom is "sandwiched" between two...
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1901 but there wasn't much interest in the topic until the discovery of ferrocene in the 1950s. The cyclopentadienyl anion is a planar, cyclic, regular-pentagonal...
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to the discovery of ferrocene, a very stable compound which foreshadowed the synthesis of many related sandwich compounds. Ferrocene is formed by reaction...
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Polyferrocenes (category Ferrocenes)
Polyferrocenes are polymers containing ferrocene units. Ferrocene offers many advantages over pure hydrocarbons when used as a building block of macromolecular...
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above. A QRE with ferrocene or another internal standard, such as cobaltocene or decamethylferrocene, referenced back to ferrocene is ideal for nonaqueous...
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Ferrocenecarboxaldehyde (redirect from Ferrocene aldehyde)
compound with the formula (C5H5)Fe(C5HCHO). The molecule consists of ferrocene substituted by an formyl group on one of the cyclopentadienyl rings. It...
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Oil bleaching (section Ferrocene and bleaching)
do this, a compound called ferrocene was used, which dyed the oil red. The fuel oil coloured by the addition of ferrocene became unsuitable for use as...
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Ferrocenecarboxylic acid (category Ferrocenes)
is the simplest carboxylic acid derivative of ferrocene. It can be prepared in two steps from ferrocene by acylation with a 2-chlorobenzoyl chloride followed...
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catalysts, such as 1,1'-bis(diphenylphosphino)ferrocene (dppf) to form [1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloride (PdCl2(dppf)). Another...
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+7. Iron also forms many coordination complexes; some of them, such as ferrocene, ferrioxalate, and Prussian blue have substantial industrial, medical...
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neurotoxic substance and is fatal if swallowed/inhaled and causes manganism. Ferrocene Dimethyl methylphosphonate Toluene Isooctane Triptane Lead scavengers...
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Ugi's amine (category Ferrocenes)
“planar chirality” for use in substituted ferrocene terminology, which is necessary for ferrocenes in which ferrocene's innate plane of symmetry is broken by...
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for the preparation of metallocenes. For example, the preparation of ferrocene and zirconocene dichloride: 2 NaC5H5 + FeCl2 → Fe(C5H5)2 + 2 NaCl ZrCl4(thf)2...
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oxidizing agent: vs. ferrocene/ferrocenium, [NO]+ in CH2Cl2 solution has a redox potential of 1.00 V (or 1.46–1.48 V vs SCE), vs. ferrocene/ferrocenium, [NO]+...
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