• Metal acetylacetonates are coordination complexes derived from the acetylacetonate anion (CH 3COCHCOCH− 3) and metal ions, usually transition metals. The...
    25 KB (2,762 words) - 21:04, 12 August 2024
  • Thumbnail for Tris(acetylacetonato)iron(III)
    ferric coordination complex featuring acetylacetonate (acac) ligands, making it one of a family of metal acetylacetonates. It is a red air-stable solid that...
    6 KB (511 words) - 13:21, 19 August 2024
  • direct metal-carbon bonds. Metal β-diketonates, metal alkoxides, metal dialkylamides, transition metal carboxylate complexes, metal acetylacetonates, and...
    1 KB (180 words) - 13:35, 28 December 2023
  • Thumbnail for Aluminium acetylacetonate
    octahedral tris(acetylacetonate)s. Aluminium acetylacetonate can be used as the precursor to crystalline aluminium oxide films using low-pressure metal organic...
    2 KB (160 words) - 14:31, 19 January 2024
  • Thumbnail for Acetylacetone
    CH3C(O)CH2C(O)CH3 + NaCl Because of the ease of these syntheses, many analogues of acetylacetonates are known. Some examples are benzoylacetone, dibenzoylmethane (dbaH)[clarification...
    13 KB (1,027 words) - 16:33, 30 May 2024
  • Thumbnail for Sodium acetylacetonate
    tetraacetylethane. With metal salts, it reacts to give metal acetylacetonate complexes. Alkylation of sodium acetylacetonate can result in both O-alkylation...
    3 KB (217 words) - 15:52, 6 March 2024
  • coordination number characteristic of barium. Barium acetylacetonate has been examined in metal organic chemical vapour deposition of BaTiO3 thin films...
    3 KB (254 words) - 19:52, 12 May 2024
  • Thumbnail for Dibenzoylmethane
    give six-membered rings. With metal salts, the conjugate base of DBM forms complexes akin to the metal acetylacetonates.[citation needed] Dibenzoylmethane...
    5 KB (458 words) - 10:05, 25 April 2024
  • Thumbnail for Epoxide
    hdl:1874/20149. S2CID 94240406. Indictor N., Brill W. F. (1965). "Metal Acetylacetonate Catalyzed Epoxidation of Olefins with t-Butyl Hydroperoxide". J...
    22 KB (2,324 words) - 21:50, 25 August 2024
  • Thumbnail for Transition metal complexes of aldehydes and ketones
    Related to η1-O-bonded complexes of aldehydes and ketones are metal acetylacetonates and related species, which can be viewed as a combination of ketone...
    4 KB (424 words) - 15:46, 12 August 2023
  • Thumbnail for Tris(acetylacetonato)titanium(III)
    Tris(acetylacetonato)titanium(III) (category Acetylacetonate complexes)
    complex of titanium(III) featuring acetylacetonate (acac) ligands, making it one of a family of metal acetylacetonates. It is a blue air-sensitive solid...
    2 KB (217 words) - 16:28, 23 January 2023
  • Thumbnail for Rhodium acetylacetonate
    Rhodium acetylacetonate is the coordination complex with the formula Rh(C5H7O2)3, which is sometimes known as Rh(acac)3. The molecule has D3-symmetry...
    2 KB (157 words) - 10:38, 20 June 2024
  • Thumbnail for Triacetylmethane
    forms an enolate. The enolate forms a variety of metal complexes related to the metal acetylacetonates. "Triacetylmethane". pubchem.ncbi.nlm.nih.gov. Arnett...
    3 KB (183 words) - 02:56, 2 August 2022
  • Thumbnail for Tris(acetylacetonato)cobalt(III)
    (2017). "An Historic and Scientific Study of the Properties of Metal(III) Tris-acetylacetonates". Structural Chemistry. 28: 201–212. doi:10.1007/s11224-016-0864-0...
    4 KB (305 words) - 10:39, 1 March 2024
  • Thumbnail for Thulium acetylacetonate
    a more plausible formula based on the behavior of other lanthanide acetylacetonates. The dihydrate has been characterized by X-ray crystallography. Upon...
    6 KB (430 words) - 19:42, 5 February 2024
  • transition metal chemistry, as documented in over 366 scientific papers. In the 1960s his group demonstrated that certain metal acetylacetonates undergo...
    5 KB (486 words) - 18:57, 18 February 2024
  • Thumbnail for Samarium(III) acetylacetonate
    a more plausible formula based on the behavior of other lanthanide acetylacetonates. The dihydrate has been characterized by X-ray crystallography. Upon...
    4 KB (374 words) - 04:45, 28 February 2024
  • Thumbnail for Holmium acetylacetonate
    lanthanide acetylacetonates. The dihydrate has been characterized by X-ray crystallography. Attempts to dehydrate other lanthanide acetylacetonates results...
    4 KB (269 words) - 22:20, 5 February 2024
  • Thumbnail for Chromium(III) acetylacetonate
    Chromium(III) acetylacetonate is the coordination compound with the formula Cr(C5H7O2)3, sometimes designated as Cr(acac)3. This purplish coordination...
    7 KB (580 words) - 13:32, 8 September 2023
  • Thumbnail for Nickel(II) bis(acetylacetonate)
    techniques. Palladium(II) bis(acetylacetonate) Platinum(II) bis(acetylacetonate) R. C. Mehrotra; R. Bohra; D. P. Gaur (1978). Metal β-Diketones and Allied Derivatives...
    10 KB (980 words) - 15:41, 11 March 2024
  • Thumbnail for Dicarbonyl
    conjugate base derived from 1,3-ketones can serve as ligand s to form metal acetylacetonate coordination complexes. In the DeMayo reaction 1,3-diketones react...
    12 KB (1,359 words) - 16:11, 15 March 2024
  • Thumbnail for Platinum(II) bis(acetylacetonate)
    Platinum(II) bis(acetylacetonate) is the coordination compound with the formula Pt(O2C5H7)2, abbreviated Pt(acac)2. The homoleptic acetylacetonate complex of...
    4 KB (257 words) - 10:33, 20 June 2024
  • Thumbnail for Dysprosium acetylacetonate
    Bos (December 1967). "A novel synthesis of some anhydrous rare earth acetylacetonates". Inorganic and Nuclear Chemistry Letters. 3 (12): 545–548. doi:10...
    5 KB (425 words) - 13:38, 31 December 2023
  • Thumbnail for Neodymium(III) acetylacetonate
    V. Yu.; Zelenov, V. I. Electrochemical synthesis of rare-earth metal acetylacetonates. Russian Journal of General Chemistry (Translation of Zhurnal Obshchei...
    4 KB (319 words) - 15:53, 4 February 2024
  • (2017). "An Historic and Scientific Study of the Properties of Metal(III) Tris-acetylacetonates". Structural Chemistry. 28: 201–212. doi:10.1007/s11224-016-0864-0...
    12 KB (1,170 words) - 16:44, 19 February 2024
  • Thumbnail for Iridium acetylacetonate
    reactions. Iridium acetylacetonate V. G. Isakova, I. A. Baidina, N. B. Morozova, I. K. Igumenov "γ-Halogenated iridium(III) Acetylacetonates" Polyhedron 2000...
    3 KB (299 words) - 17:57, 24 September 2023
  • Thumbnail for Transition metal chloride complex
    In chemistry, a transition metal chloride complex is a coordination complex that consists of a transition metal coordinated to one or more chloride ligand...
    61 KB (3,477 words) - 14:14, 21 May 2024
  • D electron count (category Transition metals)
    transition metal center in a coordination complex. The d electron count is an effective way to understand the geometry and reactivity of transition metal complexes...
    14 KB (1,701 words) - 03:27, 4 October 2023
  • Thumbnail for NacNac
    stabilize low valent main group and transition metal complexes. Unlike the situation for the acetylacetonates, the steric properties of the coordinating atoms...
    5 KB (437 words) - 21:49, 2 February 2024
  • rise to another more significant chemical product. Since several years metal-organic compounds are widely used as molecular precursors for the chemical...
    38 KB (584 words) - 13:12, 11 June 2024