• Thumbnail for Norbornene
    Norbornene or norbornylene or norcamphene is a highly strained bridged cyclic hydrocarbon. It is a white solid with a pungent sour odor. The molecule consists...
    5 KB (429 words) - 16:45, 1 October 2024
  • Thumbnail for Ethylidene norbornene
    Ethylidene norbornene (ENB) is an organic compound that consists of an ethylidene (CH3C(H)=) group attached to norbornene. It is a colorless liquid. The...
    2 KB (196 words) - 22:08, 26 September 2024
  • Thumbnail for Nadic anhydride
    Nadic anhydride, also known as 5-norbornene-2,3-dicarboxylic anhydride, is an organic acid anhydride derivative of norbornene. Nadic anhydride exhibits endo-exo...
    4 KB (312 words) - 14:58, 7 November 2024
  • Thumbnail for Vinyl norbornene
    Vinyl norbornene (VNB) is an organic compound that consists of a vinyl group attached to norbornene. It is a colorless liquid. The compound exists as...
    2 KB (151 words) - 22:08, 26 September 2024
  • 4-Trimethylbenzene Mesitylene (1,3,5-trimethylbenzene) Ethylidene norbornene Tetravinylmethane Vinyl norbornene This set index page lists chemical structure articles...
    560 bytes (68 words) - 01:03, 30 November 2023
  • Thumbnail for EPDM rubber
    manufacture of EPDM rubbers are ethylidene norbornene (ENB), dicyclopentadiene (DCPD), and vinyl norbornene (VNB). Varying diene contents are reported...
    14 KB (1,380 words) - 10:43, 30 September 2024
  • Thumbnail for Catellani reaction
    mediator, norbornene. The Catellani reaction is catalyzed by palladium and norbornene, although in most cases superstochiometric amounts of norbornene are used...
    11 KB (1,156 words) - 22:20, 27 September 2024
  • Thumbnail for Bredt's rule
    molecules only form in large ring systems. For example, two of the following norbornene isomers violate Bredt's rule, and are too unstable to prepare: The rule...
    8 KB (813 words) - 07:48, 8 November 2024
  • Thumbnail for Cyclic olefin copolymer
    copolymerization of cyclic monomers such as 8,9,10-trinorborn-2-ene (norbornene) or 1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethanonaphthalene (tetracyclododecene)...
    9 KB (986 words) - 18:20, 1 May 2024
  • Thumbnail for Olefin metathesis
    Ring-opening metathesis usually involves a strained alkene (often a norbornene) and the release of ring strain drives the reaction. Ring-closing metathesis...
    39 KB (4,096 words) - 05:27, 16 January 2024
  • Thumbnail for Diels–Alder reaction
    production of cyclopentadiene. Cyclopentadiene is a precursor to various norbornenes, which are common monomers. The Diels–Alder reaction is also employed...
    62 KB (7,088 words) - 00:41, 15 November 2024
  • a bioorthogonal reaction using a nitrile oxide as a 1,3-dipole and a norbornene as a dipolarophile. Its primary use has been in labeling DNA and RNA in...
    44 KB (5,098 words) - 05:29, 19 February 2024
  • Thumbnail for Benzene
    Methylcyclopentene Methylcyclohexene Isopropylcyclohexene Bicycloalkenes Norbornene Cycloalkynes Cyclopropyne Cyclobutyne Cyclopentyne Cyclohexyne Cycloheptyne...
    91 KB (9,586 words) - 15:55, 18 November 2024
  • Thumbnail for Alicyclic compound
    cyclohexene, cycloheptene, cyclooctene, and so on. Bicyclic alkenes include norbornene and norbornadiene. Two more examples are shown below, methylenecyclohexane...
    3 KB (271 words) - 17:53, 16 July 2024
  • center can be radical, anionic or cationic. Some cyclic monomers such as norbornene or cyclooctadiene can be polymerized to high molecular weight polymers...
    20 KB (2,254 words) - 02:40, 2 May 2024
  • Thumbnail for Exo-Norborneol
    available, this colorless compound may be prepared by the reaction of norbornene with formic acid, followed by hydrolysis of the resultant exo-norbornyl...
    3 KB (111 words) - 16:03, 6 January 2022
  • force of the reaction is relief of ring strain in cyclic olefins (e.g. norbornene or cyclopentene). A variety of heterogeneous and homogeneous catalysts...
    7 KB (747 words) - 02:23, 20 October 2023
  • Ziller, J. W. (1992). "Ring-opening metathesis polymerization (ROMP) of norbornene by a Group VIII carbene complex in protic media" (PDF). Journal of the...
    21 KB (1,737 words) - 16:22, 22 October 2024
  • 6 β-hydrogen atoms due to the unfavorable formation of the olefin, 1-norbornene. According to Bredt's rule, one of the sp2 carbons of the double-bonded...
    16 KB (1,879 words) - 01:25, 22 March 2024
  • Thumbnail for Methyl vinyl ketone
    electrophilic alkene, it forms an adduct with cyclopentadiene. The resulting norbornene derivative is an intermediate in the synthesis of the anticholinergic...
    6 KB (400 words) - 19:23, 1 April 2024
  • Thumbnail for Acrolein
    to some commercial fragrances, including myrac aldehyde ("lyral") and norbornene-2-carboxaldehyde. The monomer 3,4-epoxycyclohexylmethyl-3',4'-epoxycyclohexane...
    22 KB (2,126 words) - 13:56, 8 October 2024
  • Thumbnail for Cyclopentadienylcobalt dinitrosyl
    the endo position. However, the scope of such reactions was limited to norbornene-type olefins. Ethylene and cyclohexene also reacted but the resulting...
    29 KB (3,687 words) - 04:23, 18 October 2024
  • Thumbnail for Hydrocarbon
    Methylcyclopentene Methylcyclohexene Isopropylcyclohexene Bicycloalkenes Norbornene Cycloalkynes Cyclopropyne Cyclobutyne Cyclopentyne Cyclohexyne Cycloheptyne...
    24 KB (2,586 words) - 20:12, 5 September 2024
  • phosphine ligand is obtained from ring-opening metathesis polymerization of a norbornene derivative, and has been used in the copper co-catalyzed Sonogashira reaction...
    48 KB (5,450 words) - 14:18, 26 September 2024
  • gives cyclopentene. Diels–Alder reaction with butadiene gives ethylidene norbornene, a comonomer in the production of EPDM rubbers. Cyclopentadiene can substitute...
    13 KB (1,040 words) - 05:40, 13 August 2024
  • Thumbnail for Norcamphor
    as a building block in organic synthesis. Norcamphor is prepared from norbornene via the 2-formate ester, which is oxidized. It is a useful precursor to...
    2 KB (86 words) - 09:29, 23 October 2024
  • Thumbnail for Dicyclopentadiene
    Dicyclopentadiene polymerizes. Copolymers are formed with ethylene or styrene. The "norbornene double bond" participates. Using ring-opening metathesis polymerization...
    13 KB (1,082 words) - 18:58, 13 November 2024
  • Thumbnail for Step-growth polymerization
    Functional groups like alkyne, norbornene, maleimide, nitrite, and cyanate have been used for this purpose. Maleimide and norbornene end-capped oligomers can...
    28 KB (3,709 words) - 07:02, 8 September 2024
  • Thumbnail for Organic chemistry
    the Steric Properties of a Metathesis Catalyst for Copolymerization of Norbornene and Cyclooctene toward Complete Alternation". Organometallics. 29 (12):...
    39 KB (4,396 words) - 06:25, 11 November 2024
  • Thumbnail for Polyethylene
    are prepared by copolymerization of ethene and cycloolefins (usually norbornene) produced by using metallocene catalysts. The resulting polymers are amorphous...
    57 KB (6,215 words) - 15:24, 5 November 2024