Norbornene or norbornylene or norcamphene is a highly strained bridged cyclic hydrocarbon. It is a white solid with a pungent sour odor. The molecule consists...
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Ethylidene norbornene (ENB) is an organic compound that consists of an ethylidene (CH3C(H)=) group attached to norbornene. It is a colorless liquid. The...
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Nadic anhydride (redirect from 5-norbornene-2,3-dicarboxylic anhydride)
Nadic anhydride, also known as 5-norbornene-2,3-dicarboxylic anhydride, is an organic acid anhydride derivative of norbornene. Nadic anhydride exhibits endo-exo...
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Vinyl norbornene (VNB) is an organic compound that consists of a vinyl group attached to norbornene. It is a colorless liquid. The compound exists as...
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4-Trimethylbenzene Mesitylene (1,3,5-trimethylbenzene) Ethylidene norbornene Tetravinylmethane Vinyl norbornene This set index page lists chemical structure articles...
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manufacture of EPDM rubbers are ethylidene norbornene (ENB), dicyclopentadiene (DCPD), and vinyl norbornene (VNB). Varying diene contents are reported...
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mediator, norbornene. The Catellani reaction is catalyzed by palladium and norbornene, although in most cases superstochiometric amounts of norbornene are used...
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molecules only form in large ring systems. For example, two of the following norbornene isomers violate Bredt's rule, and are too unstable to prepare: The rule...
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Cyclic olefin copolymer (redirect from Ethylene-norbornene copolymer)
copolymerization of cyclic monomers such as 8,9,10-trinorborn-2-ene (norbornene) or 1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethanonaphthalene (tetracyclododecene)...
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Ring-opening metathesis usually involves a strained alkene (often a norbornene) and the release of ring strain drives the reaction. Ring-closing metathesis...
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production of cyclopentadiene. Cyclopentadiene is a precursor to various norbornenes, which are common monomers. The Diels–Alder reaction is also employed...
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a bioorthogonal reaction using a nitrile oxide as a 1,3-dipole and a norbornene as a dipolarophile. Its primary use has been in labeling DNA and RNA in...
44 KB (5,098 words) - 05:29, 19 February 2024
Methylcyclopentene Methylcyclohexene Isopropylcyclohexene Bicycloalkenes Norbornene Cycloalkynes Cyclopropyne Cyclobutyne Cyclopentyne Cyclohexyne Cycloheptyne...
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cyclohexene, cycloheptene, cyclooctene, and so on. Bicyclic alkenes include norbornene and norbornadiene. Two more examples are shown below, methylenecyclohexane...
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center can be radical, anionic or cationic. Some cyclic monomers such as norbornene or cyclooctadiene can be polymerized to high molecular weight polymers...
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available, this colorless compound may be prepared by the reaction of norbornene with formic acid, followed by hydrolysis of the resultant exo-norbornyl...
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force of the reaction is relief of ring strain in cyclic olefins (e.g. norbornene or cyclopentene). A variety of heterogeneous and homogeneous catalysts...
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Ziller, J. W. (1992). "Ring-opening metathesis polymerization (ROMP) of norbornene by a Group VIII carbene complex in protic media" (PDF). Journal of the...
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6 β-hydrogen atoms due to the unfavorable formation of the olefin, 1-norbornene. According to Bredt's rule, one of the sp2 carbons of the double-bonded...
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electrophilic alkene, it forms an adduct with cyclopentadiene. The resulting norbornene derivative is an intermediate in the synthesis of the anticholinergic...
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to some commercial fragrances, including myrac aldehyde ("lyral") and norbornene-2-carboxaldehyde. The monomer 3,4-epoxycyclohexylmethyl-3',4'-epoxycyclohexane...
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the endo position. However, the scope of such reactions was limited to norbornene-type olefins. Ethylene and cyclohexene also reacted but the resulting...
29 KB (3,687 words) - 04:23, 18 October 2024
Methylcyclopentene Methylcyclohexene Isopropylcyclohexene Bicycloalkenes Norbornene Cycloalkynes Cyclopropyne Cyclobutyne Cyclopentyne Cyclohexyne Cycloheptyne...
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phosphine ligand is obtained from ring-opening metathesis polymerization of a norbornene derivative, and has been used in the copper co-catalyzed Sonogashira reaction...
48 KB (5,450 words) - 14:18, 26 September 2024
gives cyclopentene. Diels–Alder reaction with butadiene gives ethylidene norbornene, a comonomer in the production of EPDM rubbers. Cyclopentadiene can substitute...
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as a building block in organic synthesis. Norcamphor is prepared from norbornene via the 2-formate ester, which is oxidized. It is a useful precursor to...
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Dicyclopentadiene polymerizes. Copolymers are formed with ethylene or styrene. The "norbornene double bond" participates. Using ring-opening metathesis polymerization...
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Functional groups like alkyne, norbornene, maleimide, nitrite, and cyanate have been used for this purpose. Maleimide and norbornene end-capped oligomers can...
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the Steric Properties of a Metathesis Catalyst for Copolymerization of Norbornene and Cyclooctene toward Complete Alternation". Organometallics. 29 (12):...
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are prepared by copolymerization of ethene and cycloolefins (usually norbornene) produced by using metallocene catalysts. The resulting polymers are amorphous...
57 KB (6,215 words) - 15:24, 5 November 2024