tert-Butyldiphenylsilyl, also known as TBDPS, is a protecting group for alcohols. Its formula is C16H19Si-. The tert-butyldiphenylsilyl group was first...
5 KB (582 words) - 23:47, 28 November 2023
Silyl ether (redirect from Tert-butyldimethylsilyl)
chemistry. Common silyl ethers are: trimethylsilyl (TMS), tert-butyldiphenylsilyl (TBDPS), tert-butyldimethylsilyl (TBS/TBDMS) and triisopropylsilyl (TIPS)...
10 KB (1,269 words) - 22:55, 13 August 2024
regenerate diols or aminoalcohols, as in this example (where TBDPS = tert-butyldiphenylsilyl): CuCl2 also catalyses the free radical addition of sulfonyl chlorides...
30 KB (2,743 words) - 19:48, 20 January 2025
group is protected as a tert-butyldimethyl silyl ether (TBS) in 3. The C5 and C6 atoms are added as tert-butyldiphenylsilyl (TBDPS) protected iodoethanol...
18 KB (2,207 words) - 18:17, 25 November 2024
ethers) — Similar conditions to TBS but longer reaction times. tert‑Butyldiphenylsilyl (TBDPS) — Similar conditions to TBS but even longer reaction times...
57 KB (6,755 words) - 14:58, 18 February 2025
Aldehyde 6 was obtained from allyl alcohol (4) by protection as the tert-butyldiphenylsilyl ether (5) followed by ozonolysis. Wittig reagent 3 and aldehyde...
18 KB (1,520 words) - 17:15, 19 January 2024
intramolecular Pauson–Khand reaction to cyclise an enyne containing a tert-butyldiphenylsilyl (TBDPS) protected primary alcohol. The preparation of the cyclic...
20 KB (1,669 words) - 17:18, 4 July 2024
"Allylic alcohols by alkene transfer from zirconium to zinc: 1-[(tert-butyldiphenylsilyl)oxy]-dec-3-en-5-ol". Organic Syntheses. 9 (74): 205. 1998. Retrieved...
19 KB (1,696 words) - 14:36, 8 February 2025
fluoride was used for its primary alcohol to selectively remove the tert-butyldiphenylsilyl (TBDPS) protecting group. The Sharpless procedure was used to oxidize...
4 KB (338 words) - 16:03, 3 November 2023
"Allylic Alcohols by Alkene Transfer from Zirconium to Zinc: 1-[(tert-Butyldiphenylsilyl)oxy]-dec-3-en-5-ol". Organic Syntheses. 74: 205. doi:10.15227/orgsyn...
12 KB (1,161 words) - 17:43, 11 August 2024
subsequently replacing the C.30 protecting group with a more stable one, tert-butyldiphenylsilyl (TBDPS). Thereafter, the carboxylic acid can successfully attach...
19 KB (2,198 words) - 18:42, 21 October 2024