In organosulfur chemistry, thioacetals are the sulfur (thio-) analogues of acetals (R−CH(−OR)2). There are two classes: the less-common monothioacetals...

Example of desulfurization of thioacetals using Raney nickel...

ylides in the Wittig reaction to give the alkenes With thiols to give the thioacetal With hydrazine or 1-disubstituted derivatives of hydrazine to give hydrazones...

S-acetal refers to compounds of type R1R2C(SR)(SR') (R,R' ≠ H, also known as thioacetal and thioketals. Hemiaminal Orthoformate IUPAC, Compendium of Chemical...

nickel is used in organic synthesis for desulfurization. For example, thioacetals will be reduced to hydrocarbons in the last step of the Mozingo reduction:...

aluminium chloride. Thioacetals and thioketals feature C−S−C−S−C bond sequence. They represent a subclass of sulfides. The thioacetals are useful in "umpolung"...

atoms). Examples include acetylenes (H−CC−R), methyl sulfides (H−CH2SR), thioacetals (H−CH(SR)2, e.g. dithiane), methylphosphines (H−CH2PR2), furans, thiophenes...

Ultraviolet–visible spectroscopy Organometallic chemistry Acetals Hemiacetals Thioacetals Ketals Alcohols and alkyl halides, diols, thiols Alkanes and cycloalkanes...

tyrosine. He influenced the organosulfur chemistry by the synthesis of thioacetals and thioketals. These substances were subsequently used by other scientists...

reductive dealkylation of sulfides, especially benzyl derivatives and thioacetals. Thiophenols are produced by S-arylation or the replacement of diazonium...

condensation of mercaptoethanol with formaldehyde, as typical for synthesis of thioacetals. 2-Methyl-4-propyl-1,3-oxathiane is a component of the flavor of passion...

reduction. Thioacetal Liu, Bin; Thayumanavan, S. (December 2020). "Mechanistic Investigation on Oxidative Degradation of ROS-Responsive Thioacetal/Thioketal...

unpleasant stench and are poisonous, which severely limit their applications. Thioacetals and the mixed S,O-acetals are, unlike the pure O,O-acetals, very much...

Wolfrom, M. L.; Karabinos, J. V. (June 1944). "Carbonyl Reduction by Thioacetal Hydrogenolysis". Journal of the American Chemical Society. 66 (6): 909–911...

"A Vastly Increased Chemical Variety of RNA Modifications Containing a Thioacetal Structure". Angewandte Chemie International Edition in English. 57 (26):...

compound, for example in the diazo-thioketone coupling. It also converts thioacetals to their parent carbonyl compounds. The Hofmann rearrangement is a decarbonylation...

be reversed when the carbonyl group is converted into a dithiane or a thioacetal. In synthon terminology the ordinary carbonyl group is an acyl cation...

reduction of phenothiazine to diphenylamine: Ni2B can also be used to cleave thioacetals. Since Ni2B is non-pyrophoric, stable in air, and give high yields in...

and epidithiapiperazinedione. Fukuyama and Kishi first synthesized the thioacetal 1 from glycine sarcosine anhydride via a six-step synthesis with an overall...

α-sulfonylated carbonyl groups. Carboxylic acid derivatives, acetals, thioacetals, amines, alcohols, and isolated double bonds are all inert to Al/Hg....

chromophore that is attached to the dimerized cyclic peptide core and a thioacetal bridge. It intercalates into DNA at two specific sites, thereby blocking...

the monoadduct is the main product. Without the addition of alcohol a thioacetal is generated. In presence of potassium hydroxide it can be esterificated...