• The Ullmann condensation or Ullmann-type reaction is the copper-promoted conversion of aryl halides to aryl ethers, aryl thioethers, aryl nitriles, and...
    7 KB (800 words) - 23:53, 31 August 2024
  • The Ullmann reaction or Ullmann coupling, named after Fritz Ullmann, couples two aryl or alkyl groups with the help of copper. The reaction was first...
    15 KB (1,596 words) - 18:24, 26 September 2024
  • Thumbnail for Ether
    usually does not work well for aryl halides (e.g. bromobenzene, see Ullmann condensation below). Likewise, this method only gives the best yields for primary...
    19 KB (1,835 words) - 11:18, 2 September 2024
  • businessman Ullmann condensation, named after Fritz Ullmann Ullmann's Encyclopedia of Industrial Chemistry, named after Fritz Ullmann Ullmann reaction,...
    2 KB (305 words) - 23:31, 9 May 2024
  • reactions: the Ullmann reaction, the Ullmann condensation, the Graebe-Ullmann synthesis, the Goldberg reaction and the illustrious Jordan-Ullmann-Goldberg synthesis...
    2 KB (202 words) - 21:11, 7 July 2024
  • "Esters, Organic". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a09_565.pub2. ISBN 3527306730. "Claisen Condensation". Organic Chemistry...
    7 KB (627 words) - 23:49, 14 February 2024
  • Thumbnail for Phenol ether
    aryl halides cannot undergo nucleophilic substitution. As such, an Ullmann condensation can be employed: an aryl halide is able to react with phenol (or...
    10 KB (1,142 words) - 09:48, 15 April 2024
  • Thumbnail for Condensation polymer
    In polymer chemistry, condensation polymers are any kind of polymers whose process of polymerization involves a condensation reaction (i.e. a small molecule...
    6 KB (623 words) - 05:31, 3 June 2024
  • Thumbnail for Williamson ether synthesis
    alkylation on the ring since the aryloxide is an ambident nucleophile. Ullmann condensation for the formation of bis-aryl ethers Dimethyl sulfate and Diethyl...
    11 KB (1,339 words) - 23:53, 31 August 2024
  • halides with phenols to give biaryl ethers. This reaction is known as Ullmann condensation. In 1906, I. Goldberg extended this reaction to synthesize an arylamine...
    35 KB (3,976 words) - 11:26, 22 April 2024
  • β-unsaturated aromatic acid or α-substituted β-aryl acrylic acid by the aldol condensation of an aromatic aldehyde and an acid anhydride, in the presence of an...
    4 KB (424 words) - 14:49, 15 June 2024
  • convenient replacement for harsher analogues of this process such as the Ullmann condensation. Thiols and thiophenols can be coupled with aryl halides under...
    31 KB (3,483 words) - 01:36, 25 April 2024
  • Thumbnail for 2-Bromoanisole
    Heck reactions, Buchwald-Hartwig coupling, Suzuki couplings, and Ullmann condensations. The corresponding Grignard reagent readily forms. It is a precursor...
    3 KB (181 words) - 20:05, 23 September 2024
  • Fischer indole synthesis RXNO:0000074 Wurtz reaction RXNO:0000081 Ullmann condensation RXNO:0000084 Barbier reaction RXNO:0000088 Negishi coupling RXNO:0000090...
    5 KB (417 words) - 14:47, 3 May 2023
  • coumarin and a variety of chelating agents. Salicylaldehyde is produced by condensation of phenol with formaldehyde to give hydroxybenzyl alcohol, which is oxidized...
    9 KB (774 words) - 06:21, 21 August 2024
  • Thumbnail for Ester
    can further react, e.g., the Claisen condensation and its intramolecular equivalent, the Dieckmann condensation. This conversion is exploited in the malonic...
    45 KB (4,782 words) - 16:16, 18 September 2024
  • Thumbnail for Organocopper chemistry
    configuration. Organocopper compounds couple with aryl halides (see Ullmann condensation and Ullmann reaction): ArX + ( Ar ′ ) 2 CuLi   ↽ − − ⇀ ArAr ′ CuLi + Ar...
    23 KB (2,441 words) - 02:00, 1 August 2024
  • compound containing an acidic alpha-proton. The Mannich reaction is a condensation reaction.: 140  In the Mannich reaction, primary or secondary amines...
    10 KB (1,017 words) - 16:55, 26 September 2024
  • Thumbnail for Pigment violet 23
    heterocyclic compounds, but derived from carbazoles. It is prepared by condensation of chloranil and 3-amino-N-ethylcarbazole. It has a centrosymmetric angular...
    3 KB (196 words) - 19:37, 31 May 2023
  • Thumbnail for Corannulene
    Pappo, D.; Solel, E.; Keinan, E. (2009). "Corannulene ethers via Ullmann condensation". Organic Letters. 11 (22): 5146–5149. doi:10.1021/ol902352k. PMID 19905024...
    27 KB (2,320 words) - 18:40, 12 August 2023
  • Thumbnail for Acifluorfen
    described in the Rohm & Haas patent includes as its final steps an Ullmann condensation between 2-chloro-4-trifluoromethylphenol and 2-nitro-5-fluorobenzonitrile...
    12 KB (1,034 words) - 12:07, 29 September 2024
  • Thumbnail for 5-Ethyl-2-methylpyridine
    5-Ethyl-2-methylpyridine is a colorless liquid. 5-Ethyl-2-methylpyridine is produced by condensation of paraldehyde (a derivative of acetaldehyde) and ammonia: 4 CH3CHO +...
    3 KB (209 words) - 22:25, 29 December 2021
  • Thumbnail for 3-Methyl-2-pentanone
    industrial importance is low. It is produced by base-catalyzed aldol condensation of 2-butanone with acetaldehyde, forming 4-hydroxy-3-methyl-2-pentanone...
    2 KB (104 words) - 23:08, 19 December 2021
  • Thumbnail for Α,β-Unsaturated carbonyl compound
    produced using an aldol condensation or Knoevenagel condensation. Some commercially significant enones produced by condensations of acetone are mesityl...
    10 KB (1,120 words) - 04:31, 3 October 2024
  • Thumbnail for Phenols
    needed] Phenols are susceptible to Electrophilic aromatic substitutions. Condensation with formaldehyde gives resinous materials, famously Bakelite.[citation...
    11 KB (1,019 words) - 10:53, 11 September 2024
  • Thumbnail for Mesityl oxide
    volatile liquid with a honey-like odor. It is prepared by the aldol condensation of acetone to give diacetone alcohol, which readily dehydrates to give...
    4 KB (192 words) - 11:37, 26 June 2022
  • Thumbnail for Pentanal
    e., oxidations, condensations, and reductions. 2-Octanone, produced for use in the fragrance industry, is obtained by the condensation of acetone and pentanal...
    4 KB (272 words) - 03:48, 15 April 2024
  • Thumbnail for Methylol urea
    solid that decomposes near 110 °C. Methylolurea is the product of the condensation reaction of formaldehyde and urea. As such it is an intermediate in the...
    2 KB (130 words) - 22:06, 1 October 2023
  • Thumbnail for Bisphenol A
    poor solubility in water. BPA is produced on an industrial scale by the condensation reaction of phenol and acetone. Global production in 2022 was estimated...
    64 KB (7,018 words) - 02:53, 7 October 2024
  • Thumbnail for Butyraldehyde
    to the alcohol, oxidation to the acid, and base-catalyzed condensation. Aldol condensation in the presence of a base forms 2-ethyl-2-hexenal, which is...
    6 KB (365 words) - 18:47, 17 December 2023