Aziridine is an organic compound consisting of the three-membered heterocycle C2H5N. It is a colorless, toxic, volatile liquid that is of significant...
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In organic chemistry, aziridines are organic compounds containing the aziridine functional group (chemical structure (R−)4C2N−R), a three-membered heterocycle...
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Wenker synthesis (redirect from Wenker aziridine synthesis)
aziridine with the help of sulfuric acid. It is used industrially for the synthesis of aziridine itself. The original Wenker synthesis of aziridine itself...
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The Blum–Ittah aziridine synthesis, also known as the Blum–Ittah-Shahak aziridine synthesis or simply the Blum aziridine synthesis is a name reaction...
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chemical reaction used in organic chemistry for the synthesis of epoxides, aziridines, and cyclopropanes. It was discovered in 1961 by A. William Johnson and...
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The chemical formula is C2HNO2. Its core is a three member heterocycle, aziridine. In 1886 Ost and Mente claimed to produce oximide by the reaction of oxamic...
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It can be viewed as a structural analog of aziridine, with boron replacing the nitrogen atom of aziridine. Borirane is isomeric with ethylideneborane...
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The De Kimpe aziridine synthesis is a name reaction of organic chemistry, for the generation of aziridines by the reaction of α-chloroimines with nucleophiles...
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5-dihydrofuran, coumaran, and dioxane. Reduction of imines, nitriles, and aziridines to primary and secondary amines traditionally is effected by metal hydride...
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Azomethine ylide (section From aziridines)
pharmaceuticals. Azomethine ylides can be generated from many sources, including aziridines, imines, and iminiums. They are often generated in situ, and immediately...
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carboxylic acid (also pleurocybell aziridine) is a naturally occurring non-proteinogenic amino acid and an aziridine. It is found in pleurocybella porrigens...
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of an epoxide. Thus, ethylenimine is the three-membered ring species aziridine C2H4NH. The relationship of imines to amines having double and single...
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2-aminobenzaldehyde oligomerizes in solution or in the melt. An α-formyl aziridine, reduced with DIBAL from the ester, reversibly dimerizes to an oxazolidine:...
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C2H5N (molar mass: 43.07 g/mol, exact mass: 43.0422 u) can refer to: Aziridine Ethanimine or its tautomer, vinylamine N-Methylmethanimine This set index...
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Mitomycins (category Aziridines)
The mitomycins are a family of aziridine-containing natural products isolated from Streptomyces caespitosus or Streptomyces lavendulae. They include mitomycin...
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aqueous sodium bisulfite. A direct approach involves the reaction of aziridine with sulfurous acid. In 1993, about 5000–6000 tonnes of taurine were produced...
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equivalent of allylamine. With the librated methanesulfonic acid, the aziridine opens cleanly to yield a diamine that immediately undergoes a second transimination...
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Ranimustine Streptozocin Alkyl sulfonates: Busulfan (Mannosulfan Treosulfan) Aziridines: Carboquone Thiotepa Triaziquone Triethylenemelamine Platinum-based Carboplatin#...
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These are chelating ligands. Polyethylenimine is a polymer derived from aziridine. Other synthetic polyamines include 1,3,5-triazinane (not to be confused...
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Ranimustine Streptozocin Alkyl sulfonates: Busulfan (Mannosulfan Treosulfan) Aziridines: Carboquone Thiotepa Triaziquone Triethylenemelamine Platinum-based Carboplatin#...
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aldehydes and ketones, β-amino ketones, α-amino phosphonates, aziridine 2-carboxylates, and aziridine 2-phosphonates. Many of these same transformations can...
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isoindole: Nitrene cycloaddition. With alkenes, nitrenes react to form aziridines, very often with nitrenoid precursors such as nosyl- or tosyl-substituted...
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Aziridinium (category Aziridines)
Aziridiniums are the ionic form of the class of molecules known as aziridines. Aziridines can be used to insert nitrogen atoms during synthesis, but without...
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Thibodeaux C. J. (2012). "Enzymatic Chemistry of Cyclopropane, Epoxide, and Aziridine Biosynthesis". Chem. Rev. 112 (3): 1681–1709. doi:10.1021/cr200073d. PMC 3288687...
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unusual conversion of 1-alkyl-2-(bromomethyl)aziridines into 1-alkyl-2-(N-alkyl-N-ethylaminomethyl)aziridines using methyllithium Matthias D'hooghe and Norbert...
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heteroatom Heteroatom Saturated Unsaturated Boron Borirane Borirene Nitrogen Aziridine Azirine Oxygen Oxirane (ethylene oxide, epoxides) Oxirene Phosphorus Phosphirane...
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tertiary amines. Examples of cyclic amines include the 3-membered ring aziridine and the six-membered ring piperidine. N-methylpiperidine and N-phenylpiperidine...
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(2013-08-20). "Directed Nickel-Catalyzed Negishi Cross Coupling of Alkyl Aziridines". Journal of the American Chemical Society. 135 (36): 13605–13609. doi:10...
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synthesis Blaise reaction Blanc reaction Blanc chloromethylation Blum–Ittah aziridine synthesis Bodroux reaction Bodroux–Chichibabin aldehyde synthesis Bogert–Cook...
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Organic azide (section From epoxides and aziridines)
reaction are also known. Aminoazides are accessible by the epoxide and aziridine ring cleavage, respectively. The azo-transfer compounds, trifluoromethanesulfonyl...
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