• Aziridine is an organic compound consisting of the three-membered heterocycle C2H5N. It is a colorless, toxic, volatile liquid that is of significant...
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  • Thumbnail for Aziridines
    In organic chemistry, aziridines are organic compounds containing the aziridine functional group (chemical structure (R−)4C2N−R), a three-membered heterocycle...
    16 KB (1,680 words) - 13:29, 4 September 2024
  • Thumbnail for Wenker synthesis
    aziridine with the help of sulfuric acid. It is used industrially for the synthesis of aziridine itself. The original Wenker synthesis of aziridine itself...
    3 KB (253 words) - 20:59, 13 March 2024
  • The Blum–Ittah aziridine synthesis, also known as the Blum–Ittah-Shahak aziridine synthesis or simply the Blum aziridine synthesis is a name reaction...
    5 KB (483 words) - 14:39, 16 October 2024
  • Thumbnail for Johnson–Corey–Chaykovsky reaction
    chemical reaction used in organic chemistry for the synthesis of epoxides, aziridines, and cyclopropanes. It was discovered in 1961 by A. William Johnson and...
    22 KB (2,314 words) - 16:34, 26 September 2024
  • The chemical formula is C2HNO2. Its core is a three member heterocycle, aziridine. In 1886 Ost and Mente claimed to produce oximide by the reaction of oxamic...
    4 KB (396 words) - 00:59, 13 December 2024
  • It can be viewed as a structural analog of aziridine, with boron replacing the nitrogen atom of aziridine. Borirane is isomeric with ethylideneborane...
    2 KB (79 words) - 06:05, 5 November 2020
  • The De Kimpe aziridine synthesis is a name reaction of organic chemistry, for the generation of aziridines by the reaction of α-chloroimines with nucleophiles...
    2 KB (247 words) - 14:35, 26 September 2024
  • 5-dihydrofuran, coumaran, and dioxane. Reduction of imines, nitriles, and aziridines to primary and secondary amines traditionally is effected by metal hydride...
    23 KB (2,669 words) - 14:31, 20 September 2024
  • Thumbnail for Azomethine ylide
    pharmaceuticals. Azomethine ylides can be generated from many sources, including aziridines, imines, and iminiums. They are often generated in situ, and immediately...
    18 KB (1,988 words) - 01:46, 19 April 2024
  • Thumbnail for Dimethylaziridine carboxylic acid
    carboxylic acid (also pleurocybell aziridine) is a naturally occurring non-proteinogenic amino acid and an aziridine. It is found in pleurocybella porrigens...
    5 KB (439 words) - 17:00, 30 July 2024
  • Thumbnail for Imine
    of an epoxide. Thus, ethylenimine is the three-membered ring species aziridine C2H4NH. The relationship of imines to amines having double and single...
    24 KB (2,710 words) - 22:36, 16 November 2024
  • Thumbnail for Carbonyl condensation
    2-aminobenzaldehyde oligomerizes in solution or in the melt. An α-formyl aziridine, reduced with DIBAL from the ester, reversibly dimerizes to an oxazolidine:...
    5 KB (471 words) - 01:39, 16 October 2024
  • C2H5N (molar mass: 43.07 g/mol, exact mass: 43.0422 u) can refer to: Aziridine Ethanimine or its tautomer, vinylamine N-Methylmethanimine This set index...
    297 bytes (61 words) - 20:58, 27 December 2022
  • Thumbnail for Mitomycins
    Mitomycins (category Aziridines)
    The mitomycins are a family of aziridine-containing natural products isolated from Streptomyces caespitosus or Streptomyces lavendulae. They include mitomycin...
    9 KB (953 words) - 14:07, 17 January 2024
  • Thumbnail for Taurine
    aqueous sodium bisulfite. A direct approach involves the reaction of aziridine with sulfurous acid. In 1993, about 5000–6000 tonnes of taurine were produced...
    29 KB (3,081 words) - 19:17, 11 November 2024
  • Thumbnail for Oseltamivir total synthesis
    equivalent of allylamine. With the librated methanesulfonic acid, the aziridine opens cleanly to yield a diamine that immediately undergoes a second transimination...
    20 KB (2,310 words) - 22:53, 18 November 2024
  • Thumbnail for Methotrexate
    Ranimustine Streptozocin Alkyl sulfonates: Busulfan (Mannosulfan Treosulfan) Aziridines: Carboquone Thiotepa Triaziquone Triethylenemelamine Platinum-based Carboplatin#...
    41 KB (3,764 words) - 13:54, 13 December 2024
  • These are chelating ligands. Polyethylenimine is a polymer derived from aziridine. Other synthetic polyamines include 1,3,5-triazinane (not to be confused...
    15 KB (1,642 words) - 20:09, 11 December 2024
  • Thumbnail for Tretinoin
    Ranimustine Streptozocin Alkyl sulfonates: Busulfan (Mannosulfan Treosulfan) Aziridines: Carboquone Thiotepa Triaziquone Triethylenemelamine Platinum-based Carboplatin#...
    31 KB (2,913 words) - 23:49, 9 December 2024
  • Thumbnail for N-Sulfinyl imine
    aldehydes and ketones, β-amino ketones, α-amino phosphonates, aziridine 2-carboxylates, and aziridine 2-phosphonates. Many of these same transformations can...
    15 KB (1,583 words) - 03:48, 22 October 2022
  • isoindole: Nitrene cycloaddition. With alkenes, nitrenes react to form aziridines, very often with nitrenoid precursors such as nosyl- or tosyl-substituted...
    17 KB (1,851 words) - 22:57, 21 December 2024
  • Thumbnail for Aziridinium
    Aziridinium (category Aziridines)
    Aziridiniums are the ionic form of the class of molecules known as aziridines. Aziridines can be used to insert nitrogen atoms during synthesis, but without...
    3 KB (221 words) - 05:02, 25 September 2024
  • Thumbnail for Epoxide
    Thibodeaux C. J. (2012). "Enzymatic Chemistry of Cyclopropane, Epoxide, and Aziridine Biosynthesis". Chem. Rev. 112 (3): 1681–1709. doi:10.1021/cr200073d. PMC 3288687...
    22 KB (2,324 words) - 21:50, 25 August 2024
  • unusual conversion of 1-alkyl-2-(bromomethyl)aziridines into 1-alkyl-2-(N-alkyl-N-ethylaminomethyl)aziridines using methyllithium Matthias D'hooghe and Norbert...
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  • Thumbnail for Heterocyclic compound
    heteroatom Heteroatom Saturated Unsaturated Boron Borirane Borirene Nitrogen Aziridine Azirine Oxygen Oxirane (ethylene oxide, epoxides) Oxirene Phosphorus Phosphirane...
    20 KB (1,019 words) - 10:03, 11 December 2024
  • Thumbnail for Amine
    tertiary amines. Examples of cyclic amines include the 3-membered ring aziridine and the six-membered ring piperidine. N-methylpiperidine and N-phenylpiperidine...
    36 KB (3,789 words) - 03:06, 29 November 2024
  • (2013-08-20). "Directed Nickel-Catalyzed Negishi Cross Coupling of Alkyl Aziridines". Journal of the American Chemical Society. 135 (36): 13605–13609. doi:10...
    7 KB (445 words) - 00:36, 18 April 2024
  • synthesis Blaise reaction Blanc reaction Blanc chloromethylation Blum–Ittah aziridine synthesis Bodroux reaction Bodroux–Chichibabin aldehyde synthesis Bogert–Cook...
    37 KB (3,428 words) - 16:27, 11 November 2024
  • reaction are also known. Aminoazides are accessible by the epoxide and aziridine ring cleavage, respectively. The azo-transfer compounds, trifluoromethanesulfonyl...
    28 KB (2,880 words) - 17:35, 1 August 2024