2,2′-Bipyridine (bipy or bpy, pronounced /ˈbɪpiː/) is an organic compound with the formula (C5H4N). This colorless solid is an important isomer of the...

salts with many anions. The sulfate salt [Fe(bipy)3]SO4 is produced by combining ferrous sulfate with excess bipy in aqueous solution. This result illustrates...

Tris(bipyridine)ruthenium(II) chloride is the chloride salt coordination complex with the formula [Ru(bpy)3]Cl2. This polypyridine complex is a red crystalline...

is the coordination complex with the formula RuCl2(bipy)2, where bipy is 2,2'-bipyridine. It is a dark green diamagnetic solid that is a...

Mo(CO)4(bipy), derived from Mo(CO)6. RuCl2(bipy)2, a popular precursor to mixed ligand complexes. [Ru(bipy)3]2+, a well studied luminophore. [Fe(bipy)3]2+...

2'- and 4,4'-bipyridine. Because the 2,2'-bipy can chelate the metal, the shape of the peak for the 2,2'-bipy will be distorted (tailed) when metal ions...

< NCS− (N–bonded) < CH3CN < py (pyridine) < NH3 < en (ethylenediamine) < bipy (2,2'-bipyridine) < phen (1,10-phenanthroline) < NO2− (N–bonded) < PPh3...

Structure of [Ru(bipy)3]2+, a broadly used photosensitizer....

more stable complexes with heterocyclic amines, such as [Ag(py)4]2+ and [Ag(bipy)2]2+: these are stable provided the counterion cannot reduce the silver back...

dipyridine, is a popular ligand in coordination chemistry 2,2′-Bipyridine (2,2′-bipy) is a chelating ligand that forms complexes with most transition metal ions...

strong C-T bands. Most famous is Ru(bipy)32+, which upon irradiation gives excited states described as [Ru(III)(bipy−)(bipy)2]2+. The CT excited state is long-lived...

: 789  Cl ClO− 4 + 2 H+ + 2 e− ⇌ ClO− 3 + H2O 1.23 2 Ru [Ru(bipy) 3]3+ +  e− ⇌ [Ru(bipy) 3]2+ 1.24 1 Xe [HXeO 4]− + 3H2O + 6 e− ⇌ Xe(g) + 7 OH− 1.24...

be described as [MIII(bipy-)(bipy)2]2+, i.e. an oxidized metal ion bound to one bipy radical anion as well as two ordinary bipy ligands. Such charge-separated...

1002/anie.201706323. Additionally, Ta(0) has also been previously reported in Ta(bipy)3, but this has been proven to contain Ta(V). Ta(I) has been observed in...

1002/anie.201706323. Additionally, Ta(0) has also been previously reported in Ta(bipy)3, but this has been proven to contain Ta(V). Ta(I) has been observed in...

most strongly affects the length of metal-ligand bonds: For the [Co(bipy)3]+/[Co(bipy)3]2+ pair, self exchange proceeds at 109 M−1s−1. In this case, the...

common photosensitizer, tris-(2,2’-bipyridyl)ruthenium (abbreviated as [Ru(bipy)3]2+ or [Ru(bpy)3]2+), the lifetime of the triplet excited state is approximately...

H2 Ru(bipy)3Cl2, an intensely luminescent salt with a long-lived excited state, arising as follows: 2 RuCl3·xH2O + 6 bipy + CH3CH2OH → 2 [Ru(bipy)3]Cl2...

ammine complexes into nitrosyl complexes: H2O + [Ru(terpy)(bipy)(NH3)]+ → [Ru(terpy)(bipy)(NO)]2+ + 5 H+ + 6 e− In some ammine complexes, the N–H bond...

C2O42− < H2O < NCS− < CH3CN < py (pyridine) < NH3 < en (ethylenediamine) < bipy (2,2'-bipyridine) < phen (1,10-phenanthroline) < NO2− < PPh3 < CN− < CO Crystal...

aquo and a Ru(IV) oxo (bipy = (2,2'-bipyridine, py = pyridine): [(bipy)2(py)RuIV(O)]2+ + [(bipy)2(py)RuII(OH2)]2+ → 2 [(bipy)2(py)RuIII(OH)]2+ Electrochemical...

Pauson–Khand reaction. Mo(CO)6 reacts with 2,2′-bipyridine to afford Mo(CO)4(bipy). UV-photolysis of a THF solution of Mo(CO)6 gives Mo(CO)5(THF). The thermal...

respective pKa's of 4.86 and 4.3 for their conjugate acids, phenanthroline and bipy are of comparable basicity. In phenanthroline, the two nitrogen donors are...

R3Si− N donors: NH3 N3− imidazole NO RNO NO2− py amino acid N3- RN2- RCN bipy phen porphyrin (Me3Si)2N− N2 NCS- P donors: PR3 PR2− PR2OH O donors: H2O...

Ethylenediamine (en) NH2−CH2−CH2−NH2 neutral bidentate 2,2'-Bipyridine (bipy) NC5H4−C5H4N neutral bidentate easily reduced to its (radical) anion or even...

Networks Encapsulating One-Dimensional Covalent Chains: [M(4,4′-bipy)(H2O)4](4-abs)2·nH2O (4,4′-bipy = 4,4′-Bipyridine; 4-abs = 4-Aminobenzenesulfonate) (M =...

V, nearly 1 V more negative than the reduction potential of excited [Ru(bipy)3]2+. Lamansky, Sergey; Djurovich, Peter; Murphy, Drew; Abdel-Razzaq, Feras;...

R3Si− N donors: NH3 N3− imidazole NO RNO NO2− py amino acid N3- RN2- RCN bipy phen porphyrin (Me3Si)2N− N2 NCS- P donors: PR3 PR2− PR2OH O donors: H2O...

R3Si− N donors: NH3 N3− imidazole NO RNO NO2− py amino acid N3- RN2- RCN bipy phen porphyrin (Me3Si)2N− N2 NCS- P donors: PR3 PR2− PR2OH O donors: H2O...

R3Si− N donors: NH3 N3− imidazole NO RNO NO2− py amino acid N3- RN2- RCN bipy phen porphyrin (Me3Si)2N− N2 NCS- P donors: PR3 PR2− PR2OH O donors: H2O...