Cobaltocene, known also as bis(cyclopentadienyl)cobalt(II) or even "bis Cp cobalt", is an organocobalt compound with the formula Co(C5H5)2. It is a dark...
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which has many analogues for other metals, such as chromocene (CrCp2), cobaltocene (CoCp2), and nickelocene (NiCp2). When the Cp rings are mutually parallel...
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has the highest electron count of the transition metal metallocenes. Cobaltocene, Co(C5H5)2, with only 19 valence electrons is, however, a stronger reducing...
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organometallic complexes described below. Cobaltocene is a structural analog to ferrocene, with cobalt in place of iron. Cobaltocene is much more sensitive to oxidation...
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Alkali metal (section Cobaltocene and derivatives)
are characterised. Cobaltocene, Co(C5H5)2, is a metallocene, the cobalt analogue of ferrocene. It is a dark purple solid. Cobaltocene has 19 valence electrons...
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the structural data of ferrocene and the new complexes nickelocene and cobaltocene. Near the same time, he focused also on the then baffling chemistry resulting...
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diamagneticity and high symmetry. They also synthesize nickelocene and cobaltocene and confirmed they had the same structure. Fischer described the structure...
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archetypal organoiron complex. It is an air-stable, sublimable compound. Cobaltocene is a structural analogue of ferrocene, but is highly reactive toward...
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Reaction of the anhydrous compound with sodium cyclopentadienide gives cobaltocene Co(C 5H 5) 2. This 19-electron species is a good reducing agent, being...
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mentioned above. A QRE with ferrocene or another internal standard, such as cobaltocene or decamethylferrocene, referenced back to ferrocene is ideal for nonaqueous...
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(14 e−) TiCl4 (8 e−) Some complexes have more than 18 electrons. Examples: Cobaltocene (19 e−) Nickelocene (20 e−) The hexaaquacopper(II) ion [Cu(H2O)6]2+ (21 e−)...
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dichloride 12793-14-5 C10H10Cl2Ti titanocene dichloride 1271-19-8 C10H10Co cobaltocene 1277-43-6 C10H10F6FeP ferrocenium hexafluorophosphate 11077-24-0 C10H10Fe...
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CoCp*2 The permethylated form is more air-sensitive than the parent cobaltocene, owing to the inductive effects of methyl groups. It is a thermally stable...
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Kristallstrukturen" [Formation of [Co(C5H5)2]NO3 and [Co(C5H5)2]2[Co(NCO)4] from Cobaltocene, Ozone and Acetonitrile and their Crystal Structures]. Zeitschrift für...
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NaCo(CO)4. It is a catalyst in carbonylation and hydrosilylation reactions. Cobaltocene (Co(C5H5)2) is a cyclopentadiene complex of cobalt. It has 19 valence...
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Royal Institute of Technology. Her doctorate considered nickelocene, cobaltocene and cyclopentadienyl (tributylphosphine)-copper in organic synthesis...
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bis(benzene)chromium is an efficient organometallic radical scavenger. In contrast to cobaltocene, which traps radicals (R.) to form 19-valence electron species (η5-C5H5)(η4-C5H5R)Co...
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unpaired electron, paramagnetic, substitutionally labile. Examples: cobaltocene. d8 Complexes which are d8 high-spin are usually octahedral (or tetrahedral)...
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H335 NFPA 704 (fire diamond) 2 0 0 Related compounds Related compounds cobaltocene, nickelocene, chromocene, ferrocene, osmocene, bis(benzene)chromium Except...
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consequently lower growth rates. Solid organometallocenes such as ferrocene, cobaltocene, nickelocene are also common catalysts. It is found that the temperature...
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generated by the high pressure carbonylation of bis(cyclopentadienyl)cobalt (cobaltocene) at elevated temperature and pressures: Co(C5H5)2 + 2 CO → C5H5Co(CO)2...
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electron transfer: comparisons of self-exchange kinetics for cobaltocenium-cobaltocene and related redox couples with theoretical predictions" (PDF). The Journal...
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the criteria are: vanadocene, [V(η5-C5H5)2] chromocene, [Cr(η5-C5H5)2] cobaltocene, [Co(η5-C5H5)2] rhodocene, [Rh(η5-C5H5)2] nickelocene, [Ni(η5-C5H5)2]...
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treating with suitable organic and organometallic reducing agents, such as cobaltocene and tetrakisdimethylaminoethylene. alkali metal fullerides can be subjected...
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1/n [(C5H5)TiCl2]n + ZnCl2 A related reduction can be effected with cobaltocene: (C5H5)TiCl3 + (C5H5)2Co → [(C5H5)2Co]+[(C5H5)TiCl3]− Other evidence...
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Pauson and Wilkinson. The cobalt derivative is a poorer reductant than cobaltocene. The indenyl effect was discovered by Hart-Davis and Mawby in 1969 through...
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M(II) monomers. Ferrocene-containing dendrimers and dendrimers with cobaltocene and arylchromiumtricarbonyl units have been reported in end-functional...
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octaphenylrhodocene has a sandwich structure with a staggered conformation. Unlike cobaltocene, which has become a useful one-electron reducing agent in research, no...
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alkene, allyl, diene, and Cp ligands. A famous sandwich compound is cobaltocene, a rare example of low-spin Co(II) complex. This 19-electron metallocene...
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