• Thumbnail for Enol ether
    enol ether is an alkene with an alkoxy substituent. The general structure is R2C=CR-OR where R = H, alkyl or aryl. A common subfamily of enol ethers are...
    7 KB (801 words) - 17:32, 12 November 2024
  • In organosilicon chemistry, silyl enol ethers are a class of organic compounds that share the common functional group R3Si−O−CR=CR2, composed of an enolate...
    13 KB (1,369 words) - 19:53, 12 February 2024
  • Thumbnail for Enol
    electrophiles at oxygen. Silylation gives silyl enol ether. Acylation gives esters such as vinyl acetate. In general, enols are less stable than their keto equivalents...
    14 KB (1,158 words) - 12:55, 1 November 2024
  • Thumbnail for Ether
    Ge, Sn, Pb). Such compounds are considered ethers as well. Examples of such ethers are silyl enol ethers R3Si−O−CR=CR2 (containing the Si−O−C linkage)...
    19 KB (1,835 words) - 18:47, 14 October 2024
  • occur. One way to get around this is to turn the aldehyde into a silyl enol ether using trimethylsilyl chloride and a base, such as triethylamine, and then...
    4 KB (488 words) - 21:50, 23 October 2023
  • Thumbnail for Thebaine
    Thebaine (paramorphine), also known as codeine methyl enol ether, is an opiate alkaloid, its name coming from the Greek Θῆβαι, Thēbai (Thebes), an ancient...
    11 KB (730 words) - 23:47, 13 November 2023
  • Thumbnail for Quingestrone
    Quingestrone, also known as progesterone 3-cyclopentyl enol ether (PCPE) and sold under the brand name Enol-Luteovis, is a progestin medication which was previously...
    21 KB (1,940 words) - 04:11, 23 June 2023
  • Thumbnail for Ketone
    that have at least one alpha-hydrogen, undergo keto-enol tautomerization; the tautomer is an enol. Tautomerization is catalyzed by both acids and bases...
    24 KB (2,895 words) - 09:31, 2 November 2024
  • oxidation is a useful, high-yielding chemical reaction between silyl enol ethers and peroxyacids to give the corresponding α-hydroxy carbonyl product...
    28 KB (3,396 words) - 17:19, 26 September 2024
  • is transformed into an enol ether by the Tebbe reagent (Cp2Ti=CH2), and then the glycosyl acceptor is tethered to the enol ether under acid-catalysed conditions...
    7 KB (907 words) - 17:26, 22 October 2017
  • Methyl vinyl ether is an organic compound with the chemical formula CH3OCH=CH2. A colorless gas, it is the simplest enol ether. It is used as a synthetic...
    6 KB (473 words) - 18:01, 25 September 2023
  • Thumbnail for Ethyl vinyl ether
    Ethyl vinyl ether is an organic compound with the chemical formula CH3CH2OCH=CH2. It is the simplest enol ether that is liquid at room temperature. It...
    3 KB (268 words) - 05:00, 13 January 2024
  • Thumbnail for Azadirachtin
    which boasts a plethora of oxygen-bearing functional groups, including an enol ether, acetal, hemiacetal, tetra-substituted epoxide and a variety of carboxylic...
    13 KB (1,248 words) - 15:42, 29 July 2024
  • compounds. The reaction as originally reported involved formation of a silyl enol ether followed by treatment with palladium(II) acetate and benzoquinone to yield...
    13 KB (1,389 words) - 18:18, 21 August 2024
  • Thumbnail for List of androgen esters
    Testopan) – 3-cyclopentyl enol ether of methyltestosterone Quinbolone (Anabolicum, Anabolvis) – 17β-cyclopentenyl enol ether of boldenone (Δ1-testosterone)...
    16 KB (1,466 words) - 18:43, 3 December 2023
  • Thumbnail for Mukaiyama aldol addition
    addition is an organic reaction and a type of aldol reaction between a silyl enol ether (R2C=CR−O−Si(CH3)3) and an aldehyde (R−CH=O) or formate (R−O−CH=O). The...
    9 KB (958 words) - 06:34, 11 February 2024
  • Thumbnail for Epoxide
    In organic chemistry, an epoxide is a cyclic ether, where the ether forms a three-atom ring: two atoms of carbon and one atom of oxygen. This triangular...
    22 KB (2,324 words) - 21:50, 25 August 2024
  • Thumbnail for Penmesterol
    enol ether, is a synthetic, orally active anabolic-androgenic steroid (AAS) that was developed in the early 1960s. It is the 3-cyclopentyl enol ether...
    4 KB (236 words) - 17:48, 11 November 2023
  • Carbonyl compounds, such as aldehydes and ketones, can be converted to enols or enol ethers. These species, being nucleophilic at the α-carbon, can attack especially...
    9 KB (957 words) - 09:12, 30 April 2024
  • where alkyl = methyl, ethyl, etc. A dialkyl ether is an ether with two alkyl groups, e.g., diethyl ether O(CH2CH3)2. In medicinal chemistry, the incorporation...
    12 KB (1,221 words) - 23:26, 4 August 2024
  • Thumbnail for Progestogen ester
    3-cyclopentyl enol ethers of 17α-hydroxyprogesterone and 17α-hydroxyprogesterone acetate, respectively, while progesterone 3-acetyl enol ether (never marketed)...
    22 KB (2,387 words) - 00:35, 9 December 2023
  • Thumbnail for Benzyl group
    Benzyl group (redirect from Benzyl ether)
    benzylated in presence of phenol functional groups using Cu(acac)2 Benzyl ethers can be removed under reductive conditions, oxidative conditions, and the...
    15 KB (1,603 words) - 15:22, 22 October 2024
  • Thumbnail for Ester
    bonded with an ether. March, J. Advanced Organic Chemistry 4th Ed. J. Wiley and Sons, 1992: New York. ISBN 0-471-60180-2. "Chemistry of Enols and Enolates...
    46 KB (4,840 words) - 14:46, 25 October 2024
  • Thumbnail for Anabolic steroid
    17α-alkylated are orally active. Some examples include the testosterone 17-ethers cloxotestosterone, quinbolone, and silandrone,[citation needed] which are...
    209 KB (21,565 words) - 19:39, 16 November 2024
  • instead of an alkene yields an enol, which tautomerizes into a ketone. Using an alcohol instead of water yields an ether (see also Hofmann-Sand reaction)...
    10 KB (1,156 words) - 03:06, 17 October 2024
  • Thumbnail for Triamcinolone acetonide
    20β-Dihydroprogesterone Dimepregnen Diosgenin P1-185 Progesterone Progesterone 3-acetyl enol ether Quingestrone Retroprogesterone derivatives: 20α-Dihydrodydrogesterone...
    16 KB (1,220 words) - 14:16, 5 September 2024
  • Thumbnail for Ethyl group
    äldre C4H10, ethyl, den nyare C2H6, methyl, … " (One may then give names to ether radicals; one can call the older [one] C4H10, ethyl, the newer [one] C2H6...
    4 KB (467 words) - 23:21, 12 September 2024
  • Thumbnail for Nandrolone
    becomes an enol ether moiety. Treatment of this product (2) with weak acid, oxalic acid for e.g., leads to the hydrolysis of the enol ether, producing...
    48 KB (4,571 words) - 14:08, 8 September 2024
  • Thumbnail for Trenbolone
    20β-Dihydroprogesterone Dimepregnen Diosgenin P1-185 Progesterone Progesterone 3-acetyl enol ether Quingestrone Retroprogesterone derivatives: 20α-Dihydrodydrogesterone...
    23 KB (1,906 words) - 08:25, 12 July 2024
  • Thumbnail for Imine
    intermediates in the synthesis of heterocycles. Aromatic imines react with an enol ether to a quinoline in the Povarov reaction. Imines react, thermally, with...
    24 KB (2,710 words) - 22:36, 16 November 2024