Osmium tetroxide (also osmium(VIII) oxide) is the chemical compound with the formula OsO4. The compound is noteworthy for its many uses, despite its toxicity...
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solid osmium is difficult to machine, form, or work. Osmium forms compounds with oxidation states ranging from −4 to +8. The most common oxidation states...
52 KB (5,873 words) - 22:19, 3 October 2024
Hassium tetroxide (category Oxides)
Hassium tetroxide (also hassium(VIII) oxide) is the inorganic compound with the formula HsO4. It is the highest oxide of hassium, a transactinide transition...
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Osmium compounds are compounds containing the element osmium (Os). Osmium forms compounds with oxidation states ranging from −2 to +8. The most common...
23 KB (2,391 words) - 17:46, 26 September 2024
Hassium (redirect from Eka-osmium)
homologue to osmium was that minerals supposedly containing sergenium formed volatile oxides when boiled in nitric acid, similarly to osmium. Cherdyntsev's...
101 KB (14,098 words) - 10:30, 8 October 2024
Group 7 element (section Oxides)
rare example of a molecular binary metal oxide. Other examples are ruthenium(VIII) oxide and osmium(VIII) oxide. It adopts a centrosymmetric corner-shared...
83 KB (8,982 words) - 17:57, 11 September 2024
Nitrosylsulfuric acid – NOHSO4 Osmium hexafluoride – OsF6 Osmium tetroxide (osmium(VIII) oxide) – OsO4 Osmium trioxide (osmium(VI) oxide) – OsO3 Tributyltin –...
119 KB (8,735 words) - 14:26, 16 September 2024
Osmium octafluoride is an inorganic chemical compound of osmium metal and fluorine with the chemical formula OsF8. Some sources consider it to be a still...
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Iridium (section Oxidation states)
group, it is considered the second-densest naturally occurring metal (after osmium) with a density of 22.56 g/cm3 (0.815 lb/cu in) as defined by experimental...
82 KB (7,874 words) - 17:24, 12 October 2024
OsI osmium(I) iodide 76758–38–8 OsI2 osmium(II) iodide 59201–57–9 OsI3 osmium(III) iodide 59201–58–0 OsO2 osmium(IV) oxide 12036–02–1 OsO4 osmium(VIII) oxide...
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amount of osmium tetroxide, which after reaction is regenerated with reoxidants such as potassium ferricyanide or N-methylmorpholine N-oxide. This dramatically...
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Noble metal (section Oxides)
platinum, and the other platinum group metals (ruthenium, rhodium, palladium, osmium, iridium) are most often so classified. Silver, copper, and mercury are...
27 KB (2,733 words) - 03:13, 17 September 2024
Ruthenium tetroxide (redirect from Ruthenium(VIII) oxide)
alcohols to carboxylic acids. When used in this fashion, the ruthenium(VIII) oxide is used in catalytic amounts and regenerated by the addition of sodium...
14 KB (1,379 words) - 00:48, 8 September 2024
Potassium osmate (category Osmium compounds)
formula K2[OsO2(OH)4]. This diamagnetic purple salt contains osmium in the VI (6+) oxidation state. When dissolved in water a red solution is formed. When...
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obtained by the reaction of osmium with a variety of oxidizing agents, including, sodium chlorate, osmium tetroxide, and nitric oxide at about 600 °C. Using...
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Highest Oxidation States of the 5d Transition Metals: a Quantum-Chemical Study (PDF) (Report). Chemical Society. Retrieved 2011-06-20. "Osmium heptafluoride"...
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Iron compounds (section Oxides and hydroxides)
its group oxidation state of +8, although its heavier congeners ruthenium and osmium can, with ruthenium having more difficulty than osmium. Ruthenium...
27 KB (2,957 words) - 03:23, 7 August 2024
Ruthenium (section Oxides and chalcogenides)
metal that can assume the group oxidation state +8, and even then it is less stable there than the heavier congener osmium: this is the first group from...
48 KB (5,475 words) - 16:28, 5 October 2024
Reoxidant (section Oxidations with TEMPO)
Nash; Jeremy S. Parker (2008). "Pyridine-N-Oxide as a Mild Reoxidant Which Transforms Osmium-Catalyzed Oxidative Cyclization". Angew. Chem. Int. Ed. 47 (15):...
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Osmium hexafluoride, also osmium(VI) fluoride, (OsF6) is a compound of osmium and fluorine, and one of the seventeen known binary hexafluorides. Osmium...
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elements in the periodic table. It consists of iron (Fe), ruthenium (Ru), osmium (Os) and hassium (Hs). "Group 8" is the modern standard designation for...
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chemical compound with the chemical formula (NH4)2OsCl6. Reduction of osmium(VIII) oxide with iron dichloride in an acidic medium in the presence of ammonium...
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Iridium compounds (section Oxides)
compounds containing iridium in the +6 oxidation state include IrF6 and the oxides Sr2MgIrO6 and Sr2CaIrO6. iridium(VIII) oxide (IrO4) was generated under matrix...
17 KB (1,795 words) - 18:08, 5 January 2024
Iridium(IV) oxide, IrO2, is the only well-characterised oxide of iridium. It is a blue-black solid. The compound adopts the TiO2 rutile structure, featuring...
11 KB (1,167 words) - 03:13, 31 May 2024
Ruthenium(IV) oxide is the inorganic compound with the formula RuO2. This black solid is the most common oxide of ruthenium. It is widely used as an electrocatalyst...
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Ruthenium compounds (section Oxides and chalcogenides)
(Ru). Ruthenium compounds can have oxidation states ranging from 0 to +8, and −2. The properties of ruthenium and osmium compounds are often similar. The...
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problem was remedied in compound 4.12. Next dihydroxylation with Osmium(VIII) oxide formed the diol 4.13 with the primary alcohol on addition of base...
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Hydrolysis constant (section Osmium(VIII))
M.; Zsednai, Á.; Csányi, L.J. (1983). "The acidic behaviour of osmium(VIII) and osmium(VI". Transition Met. Chem. 8: 328–332. doi:10.1007/BF00618563....
123 KB (5,187 words) - 01:29, 17 August 2024
Plutonium (section Mixed oxide fuel)
allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides...
139 KB (14,972 words) - 03:21, 5 October 2024
Superhard material (section Osmium diboride)
bonding (M = metal) lead to high hardness. Dense heavy metals, such as osmium, rhenium, tungsten etc., are particularly apt at forming hard borides because...
54 KB (6,863 words) - 12:15, 18 July 2024