The Ullmann reaction or Ullmann coupling, named after Fritz Ullmann, couples two aryl or alkyl groups with the help of copper. The reaction was first...
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The Ullmann condensation or Ullmann-type reaction is the copper-promoted conversion of aryl halides to aryl ethers, aryl thioethers, aryl nitriles, and...
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Carbazole (redirect from Graebe–Ullmann reaction)
hydrazine. A third method for the synthesis of carbazole is the Graebe–Ullmann reaction. In the first step, an N-phenyl-1,2-diaminobenzene (N-phenyl-o-phenylenediamine)...
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this way n Me2SiCl2 + 2n Na → (Me2Si)n + 2n NaCl Wurtz–Fittig reaction Ullmann reaction Adolphe Wurtz (1855). "Sur une nouvelle classe de radicaux organiques"...
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These reactions are also called cross-coupling reactions. The product is unsymmetrical, R−R'. Coupling reactions are illustrated by the Ullmann reaction: Coupling...
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new carbon–carbon bond. Examples include the Heck reaction, Ullmann reaction, and Wurtz–Fittig reaction. Many variations exist. Substituted compounds are...
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the Ullmann reaction; Goldberg is the only woman scientist unambiguously recognized for her own named reaction: the amidation (Goldberg) reaction. This...
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following reactions: the Ullmann reaction, the Ullmann condensation, the Graebe-Ullmann synthesis, the Goldberg reaction and the illustrious Jordan-Ullmann-Goldberg...
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businessman Ullmann condensation, named after Fritz Ullmann Ullmann's Encyclopedia of Industrial Chemistry, named after Fritz Ullmann Ullmann reaction, in chemistry...
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dechlorinating agent are required. In one classic application, the Ullmann reaction, chloroarenes are coupled to biphenyl]]s. For example, the activated...
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Simmons–Smith reaction Sonogashira coupling Staudinger reaction Stille reaction Sulfidation Suzuki reaction Transmetalation Ullmann reaction Upjohn dihydroxylation...
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Hydration reaction Condensation reaction Hydrolysis Miller, Raimund; Abaecherli, Claudio; Said, Adel; Jackson, Barry (2001). "Ketenes". Ullmann's Encyclopedia...
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thiophene-2-carboxylic acid. It is used as a reagent to promote the Ullmann reaction between aryl halides. Copper(I) thiophene-2-carboxylate at Sigma-Aldrich...
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Organocopper compounds couple with aryl halides (see Ullmann condensation and Ullmann reaction): ArX + ( Ar ′ ) 2 CuLi ↽ − − ⇀ ArAr ′ CuLi + Ar ′ X...
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substrate for many coupling processes including the Heck reaction, Suzuki reaction, and Ullmann reaction. Shimizu, Shinkichi; Watanabe, Nanao; Kataoka, Toshiaki;...
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cleavage Gomberg–Bachmann reaction Gomberg–Bachmann–Hey reaction Gomberg radical reaction Gould–Jacobs reaction Graebe–Ullmann synthesis Grignard degradation...
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alkylation reactions. Other reactions that can be catalyzed by the use of chiral biaryl compounds are the Grignard reaction, Ullmann reaction, and the Suzuki...
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Biphenyl (section Reactions and uses)
They are prepared by various coupling reactions including the Suzuki-Miyaura reaction and the Ullmann reaction. Polychlorinated biphenyls were once used...
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Diphenyl ether (section Synthesis and reactions)
production of phenol. Related compounds are prepared by Ullmann reactions. The compound undergoes reactions typical of other phenyl rings, including hydroxylation...
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In chemistry, a hydration reaction is a chemical reaction in which a substance combines with water. In organic chemistry, water is added to an unsaturated...
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Redox (redirect from Redox reaction)
reduction–oxidation or oxidation–reduction: 150 ) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the...
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The Perkin reaction is an organic reaction developed by English chemist William Henry Perkin that is used to make cinnamic acids. It gives an α,β-unsaturated...
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The Kolbe–Schmitt reaction or Kolbe process (named after Hermann Kolbe and Rudolf Schmitt) is a carboxylation chemical reaction that proceeds by treating...
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In organic chemistry, the Mannich reaction is a three-component organic reaction that involves the amino alkylation of an acidic proton next to a carbonyl...
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Transamination (redirect from Transamination reaction)
Chemistry: Reactions, Mechanisms, and Structure, 5th ed. Wiley, 2001, p. 503. ISBN 0-471-58589-0 • Gerald Booth "Naphthalene Derivatives" in Ullmann's Encyclopedia...
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In organic chemistry, a rearrangement reaction is a broad class of organic reactions where the carbon skeleton of a molecule is rearranged to give a structural...
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Ullmann's Encyclopedia of Industrial Chemistry is a major reference work related to industrial chemistry by chemist Fritz Ullmann, first published in...
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Ether (section Williamson and Ullmann ether syntheses)
group attached to it in a reaction with an SN2 mechanism. C6H5OH + OH− → C6H5–O− + H2O C6H5–O− + R–X → C6H5OR The Ullmann condensation is similar to...
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Tishchenko reaction is an organic chemical reaction that involves disproportionation of an aldehyde in the presence of an alkoxide. The reaction is named...
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