• The Hunsdiecker reaction (also called the Borodin reaction or the Hunsdiecker–Borodin reaction) is a name reaction in organic chemistry whereby silver...
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  • Thumbnail for Alexander Borodin
    1942. The method is generally known as either the Hunsdiecker reaction or the Hunsdiecker–Borodin reaction. During 1862, Borodin returned to the Medical–Surgical...
    25 KB (2,686 words) - 03:54, 14 July 2024
  • Cläre Hunsdiecker (née Dieckmann) (1903–1995) was a German chemist who worked with her husband Heinz Hunsdiecker (1904–1981) to improve a reaction of Alexander...
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  • Thumbnail for Acetyl hypochlorite
    short lived intermediate in the Hunsdiecker reaction. Acetyl hypochlorite is reported to be produced by the reaction of acetic anhydride and dichlorine...
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  • Fragmentation reactions or homolysis, for instance the Norrish reaction, the Hunsdiecker reaction and certain decarboxylations. For fragmentations taking place...
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  • Heinz Hunsdiecker (22 January 1904 – 22 November 1981) was a German chemist who together with his wife Cläre Hunsdiecker (1903–1995) improved a reaction of...
    2 KB (145 words) - 22:16, 16 October 2023
  • Thumbnail for Carboxylic acid
    Schmidt reaction converts carboxylic acids to amines. Carboxylic acids are decarboxylated in the Hunsdiecker reaction. The Dakin–West reaction converts...
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  • acetate and a lithium halide. The reaction is a variation of the Hunsdiecker reaction. A New Method for Halodecarboxylation of Acids Using Lead(IV) Acetate...
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  • synthesis Hudlicky fluorination Huisgen cycloaddition Hunsdiecker reaction, Hunsdiecker–Borodin reaction Hurd-Mori 1,2,3-thiadiazole synthesis Hydroboration...
    38 KB (3,429 words) - 20:03, 6 June 2024
  • substitution reaction involves radicals. An example is the Hunsdiecker reaction. Coupling reactions are a class of metal-catalyzed reactions involving an...
    12 KB (1,456 words) - 21:30, 14 April 2024
  • Thumbnail for Hypohalite
    chemistry, often as acyl hypohalites (see the Hunsdiecker reaction). Sodium hypohalite is used in the haloform reaction as a test for methyl ketones. The Cl-O...
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  • methods, such as the Balz–Schiemann reaction, are used to prepare fluorinated aromatic compounds. In the Hunsdiecker reaction, carboxylic acids are converted...
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  • Thumbnail for 1.1.1-Propellane
    of bicyclo[1.1.1]pentane 1 in a Hunsdiecker reaction to the corresponding dibromide 2 followed by a coupling reaction with n-butyllithium. The final product...
    7 KB (738 words) - 14:11, 23 May 2024
  • Born and Robert Oppenheimer Borodin–Hunsdiecker reaction – Alexander Borodin, Hienz Hunsdiecker, and Clare Hunsdiecker (née Dieckmann) Borrmann effect (a...
    72 KB (6,827 words) - 23:46, 21 July 2024
  • Thumbnail for Radical substitution
    group for a proton. The Wohl–Ziegler reaction involves allylic bromination of alkenes. The Hunsdiecker reaction converts silver salts of carboxylic acids...
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  • Thumbnail for Haloalkane
    the synthesis of haloalkanes from carboxylic acids are Hunsdiecker reaction and Kochi reaction. Many chloro and bromoalkanes are formed naturally. The...
    20 KB (2,413 words) - 13:06, 14 April 2024
  • Barton decarboxylation (category Substitution reactions)
    formation of gas which drives the reaction forward. Barton–McCombie deoxygenation Hunsdiecker reaction Kochi reaction Krapcho decarboxylation Kolbe electrolysis...
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  • Thumbnail for Bicyclobutane
    1-bromo-3-chlorocyclobutane can also be prepared via a modified Hunsdiecker reaction from 3-chlorocyclobutanecarboxylic acid using mercuric oxide and...
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  • Thumbnail for Basketane
    dicarboxylic acid 6. The acid is decarboxylated with a modified Hunsdiecker reaction to a dibromide 7, which is reductively debrominated with tributyltin...
    11 KB (1,088 words) - 15:57, 2 February 2024
  • coupling RXNO:0000103 Gabriel synthesis RXNO:0000106 Hunsdiecker reaction RXNO:0000140 Suzuki reaction RXNO:0000147 Emde degradation RXNO:0000148 Claisen...
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  • decarboxylations are generally radical reactions. These include the Kolbe electrolysis and Hunsdiecker-Kochi reactions. The Barton decarboxylation is an unusual...
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  • Thumbnail for Vinyl iodide functional group
    substitution of carboxylic acid to iodide is demonstrated by a modified Hunsdiecker reaction. Homolytic cleavage of O-I bond generates CO2 and vinyl radical....
    28 KB (3,003 words) - 02:54, 18 December 2023
  • Thumbnail for 1-Bromopropane
    routes include treating propanol with phosphorus tribromide or via a Hunsdiecker reaction with butyric acid. Like many other liquid halocarbons, 1-bromopropane...
    15 KB (1,420 words) - 22:18, 14 March 2024
  • Crich, D.; Motherwell, W. B. (1983). "A practical alternative to the hunsdiecker reaction". Tetrahedron Letters. 24 (45): 4979. doi:10.1016/S0040-4039(01)99826-0...
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  • Thumbnail for Carbon nanotube chemistry
    functionalized with urea, guanidine, thiourea and aminosilane. Using the Hunsdiecker reaction, carbon nanotubes treated with nitric acid can react with iodosobenzenediacetate...
    34 KB (3,689 words) - 19:31, 12 April 2024
  • Thumbnail for Adolf Lieben
    "Gazzetta Chimica Italiana, Palermo," etc. Lieben haloform reaction Hunsdiecker reaction  This article incorporates text from a publication now in the...
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  • Thumbnail for Benzoic acid
    be effected by heating in quinoline in the presence of copper salts. Hunsdiecker decarboxylation can be achieved by heating the silver salt. It is excreted...
    28 KB (2,436 words) - 08:44, 17 January 2024
  • National Academy of Sciences. He developed the Kochi reaction, a variation on the Hunsdiecker reaction. Kochi was of Japanese descent and he and his family...
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  • Thumbnail for Bromofluoromethane
    ineffective methods: From salts of fluoroacetic acid using a Hunsdiecker type of reaction. From dibromofluoromethane by reductive debromination with a...
    3 KB (202 words) - 18:34, 13 August 2023
  • to disulfides.: 406–408  In air, tris(thiophenyl)stibine catalyzes a Hunsdiecker-like decarboxylative oxidation of anhydrides to alcohols.: 411  In ultraviolet...
    8 KB (758 words) - 05:54, 15 April 2024