Nucleophile (redirect from Nucleophilicity)
nucleophilic substitution, whereby a nucleophile becomes attracted to a full or partial positive charge, and nucleophilic addition. Nucleophilicity is...
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In chemistry, a nucleophilic substitution (SN) is a class of chemical reactions in which an electron-rich chemical species (known as a nucleophile) replaces...
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SN2 reaction (redirect from Bimolecular nucleophilic substitution)
The bimolecular nucleophilic substitution (SN2) is a type of reaction mechanism that is common in organic chemistry. In the SN2 reaction, a strong nucleophile...
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In organic chemistry, a nucleophilic addition (AN) reaction is an addition reaction where a chemical compound with an electrophilic double or triple bond...
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Aromatic rings are usually nucleophilic, but some aromatic compounds do undergo nucleophilic substitution. Just as normally nucleophilic alkenes can be made...
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Nucleophilic abstraction is a type of an organometallic reaction which can be defined as a nucleophilic attack on a ligand which causes part or all of...
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reactions in organic chemistry are classified either as electrophilic or nucleophilic depending upon the reagent involved, whether a reactive intermediate...
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Catalytic triad (redirect from N-terminal nucleophilic protease)
β-lactamases). An acid-base-nucleophile triad is a common motif for generating a nucleophilic residue for covalent catalysis. The residues form a charge-relay network...
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SN1 reaction (redirect from Unimolecular nucleophilic substitution)
The unimolecular nucleophilic substitution (SN1) reaction is a substitution reaction in organic chemistry. The Hughes-Ingold symbol of the mechanism expresses...
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Acyl group (redirect from Nucleophilic acyl substitution)
esters, and amides. Carboxylate ions are essentially unreactive towards nucleophilic substitution, since they possess no leaving group. The reactivity of...
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Radical-nucleophilic aromatic substitution or SRN1 in organic chemistry is a type of substitution reaction in which a certain substituent on an aromatic...
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As the name suggests, a non-nucleophilic base is a sterically hindered organic base that is a poor nucleophile. Normal bases are also nucleophiles, but...
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Nucleophilic conjugate addition is a type of organic reaction. Ordinary nucleophilic additions or 1,2-nucleophilic additions deal mostly with additions...
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Alkylation (section Nucleophilic alkylating agents)
dealkylation. Alkylating agents are often classified according to their nucleophilic or electrophilic character. In oil refining contexts, alkylation refers...
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In organic chemistry, the vicarious nucleophilic substitution is a special type of nucleophilic aromatic substitution in which a nucleophile replaces...
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due to high C:H ratio Undergo electrophilic substitution reactions and nucleophilic aromatic substitutions Arenes are typically split into two categories...
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Ketone (section Nucleophilic additions)
electronegativity of the oxygen is greater than that for carbon. Thus, ketones are nucleophilic at oxygen and electrophilic at carbon. Because the carbonyl group interacts...
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Nucleophilic epoxidation is the formation of epoxides from electron-deficient double bonds through the action of nucleophilic oxidants. Nucleophilic epoxidation...
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intramolecular nucleophilic substitution of a halohydrin. Many ethers, ethoxylates and crown ethers, are produced from epoxides. Nucleophilic displacement...
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electron density and enter nucleophilic aromatic substitution only with very strong electron withdrawing groups. Nucleophilic substitution can take place...
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SNi (redirect from Substitution nucleophilic internal)
(substitution nucleophilic internal) refers to a specific, regio-selective but not often encountered reaction mechanism for nucleophilic aliphatic substitution...
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Enzyme catalysis (redirect from Nucleophilic catalysis)
S2CID 4326584. Bender ML (1 January 1962). "Metal Ion Catalysis of Nucleophilic Organic Reactions in Solution". Reactions of Coordinated Ligands. Advances...
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Alcohol (chemistry) (section Nucleophilic substitution)
Primary alkyl halides react with aqueous NaOH or KOH to give alcohols in nucleophilic aliphatic substitution. Secondary and especially tertiary alkyl halides...
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Aryne (section Nucleophilic additions to arynes)
reactive. Their reactivity can be classified in three main classes: (1) nucleophilic additions, (2) pericyclic reactions, and (3) bond-insertion. Upon treatment...
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Amino sugar (section Via nucleophilic displacement)
with glycosidic bond formation at the same time in a one-pot procedure. Nucleophilic displacement can be an effective strategy for the synthesis of amino...
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pronounced. The reactive carbonyl group of the sugar reacts with the nucleophilic amino group of the amino acid and forms a complex mixture of poorly characterized...
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Vinylation (section Nucleophilic vinyl reagents)
In organic chemistry, vinylation is the process of attaching a vinyl group (CH2=CH−) to a substrate. Many organic compounds contain vinyl groups, so the...
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substitution Nucleophilic aromatic substitution Electrophilic substitution Nucleophilic substitution SN1 reaction SN2 reaction Vicarious nucleophilic substitution...
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Methylation (section Nucleophilic methylation)
product mixture. Methylation sometimes involve use of nucleophilic methyl reagents. Strongly nucleophilic methylating agents include methyllithium (CH3Li)...
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Aldehyde (section Nucleophilic addition reactions)
tautomer in strong acid or base solutions, and enolized aldehydes undergo nucleophilic attack at the α position. The formyl group can be readily reduced to...
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