Ferrocene is an organometallic compound with the formula Fe(C5H5)2. The molecule is a complex consisting of two cyclopentadienyl rings sandwiching a central...
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ferrocene, commonly abbreviated dppf, is an organophosphorus compound commonly used as a ligand in homogeneous catalysis. It contains a ferrocene moiety...
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1'‑Bis(diphenylphosphino)ferrocene]palladium(II) dichloride is a palladium complex containing the bidentate ligand 1,1'-bis(diphenylphosphino)ferrocene (dppf), abbreviated...
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Ferrocenecarboxaldehyde (redirect from Ferrocene aldehyde)
compound with the formula (C5H5)Fe(C5HCHO). The molecule consists of ferrocene substituted by an formyl group on one of the cyclopentadienyl rings. It...
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neighboring metal iron forms an air-stable, low-spin derivative in the form of ferrocene (Fe(C5H5)2). When conducted under an atmosphere of carbon monoxide, reduction...
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Decamethylferrocene (redirect from Decamethyl Ferrocene)
anions (Cp*−, (CH3)5C−5). It can also be viewed as a derivative of ferrocene, with a methyl group replacing each hydrogen atom of its cyclopentadienyl...
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Ferrocenophanes (redirect from Ansa ferrocenes)
Ferrocenophanes, also called ansa ferrocenes (from ansa: handle in greek), are organometallic compounds which are derived from ferrocene. They are a subset of ansa-metallocenes...
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Ferrocene-containing dendrimers are dendrimers that contain ferrocene substituents. Some ferrocene-containing dendrimers feature ferrocene cores and others...
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dimer); metallocenes containing cyclopentadienyl ligands (for example, ferrocene); and transition metal carbene complexes. Many metal carbonyls and metal...
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15843-42-2 FeC5O5 iron pentacarbonyl pentacarbonyl iron 13463-40-6 FeC10H10 ferrocene 102-54-5 FeCl2 iron(II) chloride 7758-94-3 FeCl3 iron(III) chloride 7705-08-0...
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Antiknock agent (section Ferrocene)
additive) MTBE Ethanol Methylcyclopentadienyl manganese tricarbonyl (MMT) Ferrocene Iron pentacarbonyl Toluene Isooctane BTEX - a hydrocarbon mixture of benzene...
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Dunitz, Orgel, and Rich described the structure of the "sandwich complex" ferrocene by X-ray crystallography where an iron atom is "sandwiched" between two...
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Crystals of ferrocene after purification by vacuum sublimation...
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a structural analog to ferrocene, with cobalt in place of iron. Cobaltocene is much more sensitive to oxidation than ferrocene. Cobalt carbonyl (Co2(CO)8)...
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characterised. Cobaltocene, Co(C5H5)2, is a metallocene, the cobalt analogue of ferrocene. It is a dark purple solid. Cobaltocene has 19 valence electrons, one...
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a staggered conformation. The first metallocene to be classified was ferrocene, and was discovered simultaneously in 1951 by Kealy and Pauson, and Miller...
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above. A QRE with ferrocene or another internal standard, such as cobaltocene or decamethylferrocene, referenced back to ferrocene is ideal for nonaqueous...
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Ferrocene – an iron atom sandwiched between two C5H5 ligands...
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chlorobenzene: 2 FeCl3 + C6H5Cl → 2 FeCl2 + C6H4Cl2 + HCl For the preparation of ferrocene ferrous chloride is generated in situ by comproportionation of FeCl3 with...
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+7. Iron also forms many coordination compounds; some of them, such as ferrocene, ferrioxalate, and Prussian blue have substantial industrial, medical...
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Compounds Ferrocene is an archetypal organoiron complex. It is an air-stable, sublimable compound. Cobaltocene is a structural analogue of ferrocene, but is...
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Acetylferrocene (category Ferrocenes)
organoiron compound with the formula (C5H5)Fe(C5H4COCH3). It consists of ferrocene substituted by an acetyl group on one of the cyclopentadienyl rings. It...
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doi:10.1039/C2DT12247B. PMID 22362072. Roux C, Biot C (April 2012). "Ferrocene-based antimalarials". Future Medicinal Chemistry. 4 (6): 783–797. doi:10...
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are called metallocenes. A famous example of this type of complex is ferrocene (FeCp2), which has many analogues for other metals, such as chromocene...
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reaction. Illustrative are the conversions of benzene to acetophenone and ferrocene to acetylferrocene: (C5H5)2Fe + (CH3CO)2O → (C5H5)Fe(C5H4COCH3) + CH3CO2H...
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oxidizing agent: vs. ferrocene/ferrocenium, [NO]+ in CH2Cl2 solution has a redox potential of 1.00 V (or 1.46–1.48 V vs SCE), vs. ferrocene/ferrocenium, [NO]+...
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Oil bleaching (section Ferrocene and bleaching)
do this, a compound called ferrocene was used, which dyed the oil red. The fuel oil coloured by the addition of ferrocene became unsuitable for use as...
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bound the metal centre; or, in organometallic compounds, such as the ferrocene [Fe(C2H5)2], where two cyclopentadienyl anions are bound to the FeII centre...
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the structure for ferrocene as postulated by Pauson and Keally. Shortly thereafter, he published the structural data of ferrocene and the new complexes...
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two benzene ligands, which has a sandwich structure, similar to that of ferrocene. In 1954, Walter Hafner, a PhD student of Ernst Otto Fischer at the time...
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