• Ferrocene is an organometallic compound with the formula Fe(C5H5)2. The molecule is a complex consisting of two cyclopentadienyl rings sandwiching a central...
    53 KB (5,194 words) - 17:00, 2 November 2024
  • Thumbnail for 1,1'-Bis(diphenylphosphino)ferrocene
    ferrocene, commonly abbreviated dppf, is an organophosphorus compound commonly used as a ligand in homogeneous catalysis. It contains a ferrocene moiety...
    6 KB (421 words) - 13:52, 11 January 2024
  • Thumbnail for (1,1'-Bis(diphenylphosphino)ferrocene)palladium(II) dichloride
    1'‑Bis(diphenylphosphino)ferrocene]palladium(II) dichloride is a palladium complex containing the bidentate ligand 1,1'-bis(diphenylphosphino)ferrocene (dppf), abbreviated...
    4 KB (254 words) - 13:52, 11 January 2024
  • Thumbnail for Ferrocenecarboxaldehyde
    compound with the formula (C5H5)Fe(C5HCHO). The molecule consists of ferrocene substituted by an formyl group on one of the cyclopentadienyl rings. It...
    6 KB (537 words) - 04:40, 3 November 2024
  • Thumbnail for Manganese
    neighboring metal iron forms an air-stable, low-spin derivative in the form of ferrocene (Fe(C5H5)2). When conducted under an atmosphere of carbon monoxide, reduction...
    86 KB (9,745 words) - 07:25, 17 November 2024
  • Thumbnail for Decamethylferrocene
    anions (Cp*−, (CH3)5C−5). It can also be viewed as a derivative of ferrocene, with a methyl group replacing each hydrogen atom of its cyclopentadienyl...
    7 KB (603 words) - 09:15, 29 June 2024
  • Thumbnail for Ferrocenophanes
    Ferrocenophanes, also called ansa ferrocenes (from ansa: handle in greek), are organometallic compounds which are derived from ferrocene. They are a subset of ansa-metallocenes...
    4 KB (465 words) - 14:52, 21 October 2023
  • Thumbnail for Ferrocene-containing dendrimers
    Ferrocene-containing dendrimers are dendrimers that contain ferrocene substituents. Some ferrocene-containing dendrimers feature ferrocene cores and others...
    3 KB (349 words) - 19:36, 14 November 2020
  • Thumbnail for Carbon
    dimer); metallocenes containing cyclopentadienyl ligands (for example, ferrocene); and transition metal carbene complexes. Many metal carbonyls and metal...
    95 KB (10,882 words) - 12:57, 7 November 2024
  • 15843-42-2 FeC5O5 iron pentacarbonyl pentacarbonyl iron 13463-40-6 FeC10H10 ferrocene 102-54-5 FeCl2 iron(II) chloride 7758-94-3 FeCl3 iron(III) chloride 7705-08-0...
    183 KB (107 words) - 22:11, 6 September 2024
  • additive) MTBE Ethanol Methylcyclopentadienyl manganese tricarbonyl (MMT) Ferrocene Iron pentacarbonyl Toluene Isooctane BTEX - a hydrocarbon mixture of benzene...
    25 KB (3,224 words) - 20:34, 6 October 2024
  • Thumbnail for Hapticity
    Dunitz, Orgel, and Rich described the structure of the "sandwich complex" ferrocene by X-ray crystallography where an iron atom is "sandwiched" between two...
    13 KB (1,321 words) - 20:45, 16 January 2024
  • Thumbnail for Sublimation (phase transition)
    Crystals of ferrocene after purification by vacuum sublimation...
    23 KB (2,415 words) - 18:10, 16 November 2024
  • Thumbnail for Cobalt
    a structural analog to ferrocene, with cobalt in place of iron. Cobaltocene is much more sensitive to oxidation than ferrocene. Cobalt carbonyl (Co2(CO)8)...
    117 KB (12,028 words) - 02:36, 10 November 2024
  • Thumbnail for Alkali metal
    characterised. Cobaltocene, Co(C5H5)2, is a metallocene, the cobalt analogue of ferrocene. It is a dark purple solid. Cobaltocene has 19 valence electrons, one...
    214 KB (23,516 words) - 16:21, 14 November 2024
  • Thumbnail for Metallocene
    a staggered conformation. The first metallocene to be classified was ferrocene, and was discovered simultaneously in 1951 by Kealy and Pauson, and Miller...
    22 KB (2,174 words) - 20:56, 18 September 2024
  • Thumbnail for Reference electrode
    above. A QRE with ferrocene or another internal standard, such as cobaltocene or decamethylferrocene, referenced back to ferrocene is ideal for nonaqueous...
    11 KB (1,276 words) - 10:23, 1 May 2024
  • Thumbnail for Chemical reaction
    Ferrocene – an iron atom sandwiched between two C5H5 ligands...
    66 KB (8,043 words) - 01:08, 14 October 2024
  • chlorobenzene: 2 FeCl3 + C6H5Cl → 2 FeCl2 + C6H4Cl2 + HCl For the preparation of ferrocene ferrous chloride is generated in situ by comproportionation of FeCl3 with...
    11 KB (896 words) - 15:08, 30 June 2024
  • Thumbnail for Iron
    +7. Iron also forms many coordination compounds; some of them, such as ferrocene, ferrioxalate, and Prussian blue have substantial industrial, medical...
    150 KB (17,078 words) - 12:22, 24 August 2024
  • Thumbnail for Organometallic chemistry
    Compounds Ferrocene is an archetypal organoiron complex. It is an air-stable, sublimable compound. Cobaltocene is a structural analogue of ferrocene, but is...
    31 KB (3,157 words) - 20:03, 24 September 2024
  • Thumbnail for Acetylferrocene
    Acetylferrocene (category Ferrocenes)
    organoiron compound with the formula (C5H5)Fe(C5H4COCH3). It consists of ferrocene substituted by an acetyl group on one of the cyclopentadienyl rings. It...
    3 KB (220 words) - 02:33, 15 November 2024
  • Thumbnail for Malaria
    doi:10.1039/C2DT12247B. PMID 22362072. Roux C, Biot C (April 2012). "Ferrocene-based antimalarials". Future Medicinal Chemistry. 4 (6): 783–797. doi:10...
    251 KB (26,002 words) - 00:57, 18 November 2024
  • Thumbnail for Cyclopentadienyl complex
    are called metallocenes. A famous example of this type of complex is ferrocene (FeCp2), which has many analogues for other metals, such as chromocene...
    7 KB (818 words) - 04:02, 11 November 2024
  • Thumbnail for Acetic anhydride
    reaction. Illustrative are the conversions of benzene to acetophenone and ferrocene to acetylferrocene: (C5H5)2Fe + (CH3CO)2O → (C5H5)Fe(C5H4COCH3) + CH3CO2H...
    17 KB (1,440 words) - 15:31, 14 November 2024
  • oxidizing agent: vs. ferrocene/ferrocenium, [NO]+ in CH2Cl2 solution has a redox potential of 1.00 V (or 1.46–1.48 V vs SCE), vs. ferrocene/ferrocenium, [NO]+...
    6 KB (615 words) - 16:48, 5 November 2024
  • do this, a compound called ferrocene was used, which dyed the oil red. The fuel oil coloured by the addition of ferrocene became unsuitable for use as...
    8 KB (927 words) - 03:33, 5 November 2024
  • Thumbnail for Ferrous
    bound the metal centre; or, in organometallic compounds, such as the ferrocene [Fe(C2H5)2], where two cyclopentadienyl anions are bound to the FeII centre...
    9 KB (975 words) - 20:00, 6 November 2024
  • Thumbnail for Ernst Otto Fischer
    the structure for ferrocene as postulated by Pauson and Keally. Shortly thereafter, he published the structural data of ferrocene and the new complexes...
    8 KB (857 words) - 13:57, 20 August 2024
  • Thumbnail for Bis(benzene)chromium
    two benzene ligands, which has a sandwich structure, similar to that of ferrocene. In 1954, Walter Hafner, a PhD student of Ernst Otto Fischer at the time...
    17 KB (1,555 words) - 13:31, 21 October 2023