derived from the Latin mercurio captāns ('capturing mercury') because the thiolate group (RS−) bonds very strongly with mercury compounds. Thiols having the...

Transition metal thiolate complexes are metal complexes containing thiolate ligands. Thiolates are ligands that can be classified as soft Lewis bases...

a heme-iron center. The iron is tethered to the protein via a cysteine thiolate ligand. This cysteine and several flanking residues are highly conserved...

{RS-SR + 2 Na -> 2 NaSR,}}} followed by protonation of the resulting metal thiolate: NaSR + HCl ⟶ HSR + NaCl {\displaystyle {\ce {NaSR + HCl -> HSR + NaCl}}}...

Thiolate-protected gold clusters are a type of ligand-protected metal cluster, synthesized from gold ions and thin layer compounds that play a special...

Sodium hydrosulfide is the chemical compound with the formula NaSH. This compound is the product of the half-neutralization of hydrogen sulfide (H2S) with...

twisted together, then stabilized and hardened by disulfide bridges. Thiolated polymers (=thiomers) can form disulfide bridges with cysteine substructures...

formal charge; the nitrogen atom remains formally positively charged. The thiolate anion can be formed by reaction with sodium carbonate, and zinc pyrithione...

thallium(I) ethoxide to give the thallium thiolate: (CH3)3CSH + TlOC2H5 → (CH3)3CSTl + HOC2H5 This thallium thiolate can be used to convert acyl chlorides...

scaffolds supporting three-dimensional tissue formation. Furthermore, thiolated xanthan gum (see thiomers) has shown potential for drug delivery, since...

thiolated polysaccharides ( see thiomers). Thiol groups are covalently attached to polysaccharides such as hyaluronic acid or chitosan. As thiolated polysaccharides...

DTT is limited to pH values above 7, since only the negatively charged thiolate form -S− is reactive (the protonated thiol form -SH is not); the pKa of...

colorless liquid, the compound has found some use as a masked form of thiolate. it is typically prepared from 3-chloropropionitrile via initial reaction...

the most common oxidation state with soft ligands such as thioethers, thiolates, and organophosphines. Au(I) compounds are typically linear. A good example...

gastrointestinal and ocular residence time of thiolated cyclodextrins is therefore substantially prolonged. Furthermore, thiolated cyclodextrins are actively taken...

A zinc finger is a small protein structural motif that is characterized by the coordination of one or more zinc ions (Zn2+) which stabilizes the fold....

as a component of compounds of the formula C2H5HgX where X = chloride, thiolate, or another organic group. Most famously X = the mercaptide group of thiosalicylic...

and tyrosine; the amine forms of lysine, arginine, and histidine; the thiolate anion of cysteine; the carboxylates of aspartate and glutamate; and the...

cationic starches, hydroxyethyl starch, carboxymethylated starches and thiolated starches. As an additive for food processing, food starches are typically...

The thiolated polymer (thiomer) forms disulfide bonds within its polymeric network and with cysteine-rich subdomains of the mucus layer. Thiolated alginates...

synthase. Two such reported compounds are thiolate-ligated oxoiron(IV) and cyclam-acetate oxoiron(IV). Thiolate-ligated oxoiron(IV) is formed by the oxidation...

1,2,3,4-thiatriazol-5-thiolate bis(1,2,3,4-thiatriazol-5-yl)disulfane 1,2,3,4-thiatriazol-5-thiol 1,2,3,4-thiatriazol-5-thiolate 1,2,3,4-thiatriazol-5-thiolato-...

motif CxxxCxxC or a close variant. This sequence provides three cysteinyl thiolate ligands that bind to three of the four metals in the 4Fe-4S cluster. The...

be obtained in this way: CH3SH + CH3ONa → CH3SNa + CH3OH The resulting thiolate anion is a strong nucleophile. It can be oxidized to dimethyl disulfide:...

relative stabilities of transition metal complexes. A recent study of metal-thiolate complexes indicates that an interplay between covalent and electrostatic...

zinc to form a reactive thiolate reacts with the Me-Cob. The activated methyl group is transferred from Me-Cob to the Hcy thiolate, which regenerates Co(I)...

with a coordination number 2, i.e. two ligands are attached to Hg, the thiolate and the ethyl group. The carboxylate group confers solubility in water...

are the sulfur analogs of alcohols; treatment of thiols with base gives thiolate ions. Thioethers are the sulfur analogs of ethers. Sulfonium ions have...

Hydroxide OH− Hydride H− Alkali metals Li+,Na+,K+ Platinum Pt2+ Alkoxide RO− Thiolate RS− Titanium Ti4+ Palladium Pd2+ Halogens F−,Cl− Halogens I− Chromium Cr3+...

Chemistry of Complexes of (n-1)d10ns Metal Ions with β-N-Donor Substituted Thiolate Ligands (m=0, 2)". Coordination Chemistry Reviews. 249 (7–8): 799–827....