at 457.5, 325, and 239 nm. The nitrito has maxima at 486, 330, and 220 nm. Their IR spectra also differ. The nitrito isomer absorbs at 1460 and 1065 cm−1...
4 KB (438 words) - 11:14, 18 March 2024
Transition metal nitrite complex (redirect from Nitrito complex)
[(NH3)5Co−ONO]2+, referred to as N-nitrito and O-nitrito, respectively. These two forms are sometimes called nitro and nitrito. These isomers can be interconverted...
9 KB (1,050 words) - 15:50, 30 May 2024
nitro ligand is bound through nitrogen. In the red linkage isomer, the nitrito is bound through one oxygen atom. The O-bonded isomer is often written...
3 KB (347 words) - 06:43, 25 July 2023
L.; Hitchman, M. A. (October 1964). "Studies of Nitro and Nitrito Complexes. I. Some Nitrito Complexes of Nickel(II)". Inorganic Chemistry. 3 (10): 1389–1394...
8 KB (771 words) - 20:56, 23 September 2023
the ability of silicon in its crystal phase to coordinate to two oxygen nitrito groups in addition to regular coordination to the four carbon atoms. This...
4 KB (433 words) - 20:48, 9 November 2023
bonded to an oxygen atom that in turn usually is bonded to a carbon atom (nitrito group). There are many major industrial applications of nitration in the...
9 KB (1,031 words) - 18:06, 4 September 2023
(bonded from the nitrogen) and nitrito (bonded from an oxygen). Nitro-nitrito isomerism is common, where the nitrito form is usually less stable. Nitric...
105 KB (12,206 words) - 12:19, 27 September 2024
trianionic coordination complex. In the anion, cobalt is bound by six nitrito ligands, the overall complex having octahedral molecular geometry. The...
4 KB (258 words) - 04:29, 28 December 2023
[O−CO−CO−O]2− dianionic bidentate Water (aqua) O−H2 neutral monodentate Nitrite (nitrito) O−N−O− monoanionic monodentate ambidentate (see also nitro) Isothiocyanate...
35 KB (3,307 words) - 12:53, 22 September 2024
(bonded from the nitrogen) and nitrito (bonded from an oxygen). Nitro-nitrito isomerism is common, where the nitrito form is usually less stable. Nitric...
34 KB (4,298 words) - 07:31, 17 May 2024
complexes by binding to metal ions in several ways. Two examples are the red nitrito complex [Co(NH3)5(ONO)]2+ is metastable, isomerizing to the yellow nitro...
27 KB (2,689 words) - 21:55, 12 September 2024
or nitrogen gas flow are required to prevent contamination by the mixed nitrito-acetate (Pd3(OAc)5NO2). Pd + 4 HNO3 → Pd(NO3)2 + 2 NO2 + 2 H2O Pd(NO3)2...
13 KB (1,182 words) - 00:14, 9 September 2024
isomers have structures (NH3)5CoNO2+2 (nitro isomer) and (NH3)5CoONO2+ (nitrito isomer). Coordination isomerism – this occurs when both positive and negative...
57 KB (5,554 words) - 03:54, 13 August 2024
ferrocyanide: HNO3 + [Fe(CN)6]4- → [Fe(CN)5(NO)]2- + OH− + OCN− Some anionic nitrito complexes undergo acid-induced deoxygenation to give the linear nitrosyl...
17 KB (2,019 words) - 15:22, 2 September 2024
were organized in the summer of 1882. One expedition founded the fort of Nitrito in the Andean valley of Lonquimay, another founded Cunco near Llaima Volcano...
47 KB (5,340 words) - 00:25, 28 September 2024