Thiophenol is an organosulfur compound with the formula C6H5SH, sometimes abbreviated as PhSH. This foul-smelling colorless liquid is the simplest aromatic...
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The Leuckart thiophenol reaction is the decomposition of a diazoxanthate, by gentle warming in a slightly acidic cuprous medium, to its corresponding aryl...
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RLi + S → RSLi RSLi + HCl → RSH + LiCl Phenols can be converted to the thiophenols via rearrangement of their O-aryl dialkylthiocarbamates. Thiols are prepared...
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encountered organic disulfides in organic synthesis. Minor contamination by thiophenol is responsible for the disagreeable odour associated with this compound...
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Suzuki reaction in a one-pot synthesis: DOM has also been used with thiophenols to prepare compounds that are useful as hindered ligands. Directed metallation...
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oxygen-centered ether—of anisole. It can be prepared by methylation of thiophenol. Alkyllithium reagents deprotonate thioanisole at the methyl group to...
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250 ppm Safety data sheet (SDS) [1] Related compounds Related compounds Thiophenol Sodium phenoxide Except where otherwise noted, data are given for materials...
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conversion is that often, it is the anion that is sought. More so than thiophenol, benzeneselenol is easily oxidized by air. The facility of this reaction...
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Monofunctional compounds Methyl acetate Thiophenol Ethylamine...
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Thallous malonate Thallous sulfate Thiocarbazide Thiofanox Thionazin Thiophenol Thiosemicarbazide Thiourea, (2-chlorophenyl)- Thiourea, (2-methylphenyl)-...
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5 for the methoxide anion, 8.5 for the azide anion, and 10.7 for the thiophenol anion. The values for the relative cation reactivities are −0.4 for the...
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and thioglycolic acid. Hydrosulfides can be used in the production of thiophenol. Upon combining with alkali metal bases, hydrogen sulfide converts to...
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E-Thiothixene. The fourth method originating from D.C Hobbs involved condensing thiophenol with 2-chloro-5-dimethylsulfamoylbenzoic acid in an alkaline DMF solution...
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formation of the ring system involves first alkylation of the anion from thiophenol with dimethylallyl bromide (1) to give the thioether (2). Friedel-Crafts...
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Related compounds Related compounds Methanethiol Butanethiol Ethanol thiophenol Except where otherwise noted, data are given for materials in their standard...
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unsaturated A ring as the main nucleophilic target site for ethyl mercaptan, thiophenol and L-cysteine ethyl ester in vitro. A library of 2, 3-dihydro-3β-substituted...
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Newman–Kwart reaction represents a useful synthetic tool for the preparation of thiophenol derivatives. The Newman–Kwart rearrangement is intramolecular. It is generally...
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doi:10.15227/orgsyn.028.0014 Khazaei; et al. (2012). "synthesis of thiophenols". Synthesis Letters. 23 (13): 1893–1896. doi:10.1055/s-0032-1316557....
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be converted into amino sugars by nitration followed by treatment with thiophenol (Michael addition) to furnish a thioglycoside donor. This is a versatile...
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in chlorination reactions; converts carboxylic acids to acyl chlorides Thiophenol an organosulfur compound; the simplest aromatic thiol Titanium tetrachloride...
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analogues of this process such as the Ullmann condensation. Thiols and thiophenols can be coupled with aryl halides under Buchwald-Hartwig-type conditions...
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was a German chemist who discovered the Leuckart reaction and Leuckart thiophenol reaction. He was the son of Karl Georg Friedrich Rudolf Leuckart (1822–1898)...
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ethylxanthate followed by hydrolysis of the intermediate xanthate ester gives thiophenol: [C6H5N2]+ + C2H5OCS−2 → C6H5SC(S)OC2H5 + N2 C6H5SC(S)OC2H5 + H2O → C6H5SH...
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Leimgruber–Batcho indole synthesis Letts nitrile synthesis Leuckart reaction Leuckart thiophenol reaction Leuckart–Wallach reaction Leuckart amide synthesis Levinstein...
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1-Ethanedithiol; Ethanethiol; 1,3-Propanedithiol; 1,2-Benzenedithiol; Thiophenol Except where otherwise noted, data are given for materials in their standard...
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ISBN 9783527306732. Melvin S. Newman; Frederick W. Hetzel (1971). "Thiophenols from Phenols: 2-Naphthalenethiol". Organic Syntheses. 51: 139. doi:10...
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basic ligands, being derived from conjugate acids with pKa's of 6.5 (thiophenol) to 10.5 (butanethiol). Consequently, thiolate ligand often bridge pairs...
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Diphenyl ether Diphenyl selenide Diphenyl telluride Diphenyl disulfide Thiophenol Diphenyl sulfone Except where otherwise noted, data are given for materials...
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statements H315, H319, H335 Related compounds Related compounds Salicylic acid Thiophenol Except where otherwise noted, data are given for materials in their standard...
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ether cleavage using hydrobromic acid or using lithium hydroxide and thiophenol in NMP leads to 3,4-dihydroxy-5-nitrobenzaldehyde (DHNB), which is being...
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