In macromolecular chemistry, a catenane (from Latin catena 'chain') is a mechanically interlocked molecular architecture consisting of two or more interlocked...
13 KB (1,377 words) - 00:03, 11 October 2024
supramolecular chemistry, specifically the synthesis of catenane. The major challenge for the synthesis of catenane is to interlock molecules in a controlled fashion...
10 KB (1,041 words) - 18:35, 5 October 2024
which there exist topoisomers include DNA, which can form knots, and catenanes. Each topoisomer of a given DNA molecule possesses a different linking...
1 KB (114 words) - 10:51, 17 July 2023
linked catenane structures, via topological Hopf links, resulting in a higher dimensionality than the repeating unit. They are a class of catenanes where...
36 KB (3,693 words) - 06:06, 11 November 2024
Building upon the assembly of mechanically linked molecules such as catenanes and rotaxanes as developed by Jean-Pierre Sauvage in the early 1980s,...
63 KB (5,806 words) - 14:51, 21 October 2024
supramolecular assembly is the synthesis of catenane. The major challenge for the synthesis of catenane is to interlock molecules in a controlled fashion...
32 KB (3,769 words) - 20:04, 3 November 2024
resembles the Olympic rings. The molecule is a linear pentacatenane or a [5]catenane. It was synthesized and named by Fraser Stoddart and coworkers in 1994...
4 KB (121 words) - 17:29, 29 September 2022
Nobel Prize work was done in 1983, when he was the first to synthesize a catenane, a complex of two interlocking ring-shaped molecules, which were bonded...
10 KB (809 words) - 07:00, 13 September 2024
delivers a switchable molecule based not on a rotaxane but on a related catenane This compound is based on two ring systems: one ring holds the photoswichable...
15 KB (1,890 words) - 23:50, 3 August 2023
rotaxanes and other mechanically interlocked molecular architectures, such as catenanes, has been focused on their efficient synthesis or their utilization as...
18 KB (1,832 words) - 19:25, 5 June 2024
mechanically interlocked molecular architectures, such as rotaxanes and catenanes. Illustrative, α-cyclodextrin form second-sphere coordination complex...
22 KB (2,498 words) - 03:10, 23 September 2024
Topoisomerase IV can unknot right-handed knots and decatenate right-handed catenanes without acting on right-handed plectonemes in negatively supercoiled DNA...
3 KB (375 words) - 21:08, 29 March 2021
topoisomers. Also, two or more such molecules may be bound together in a catenane by such topological linkages, even if there is no chemical bond between...
41 KB (5,523 words) - 06:03, 19 July 2024
supramolecular assembly is the synthesis of catenane. The major challenge for the synthesis of catenane is to interlock molecules in a controlled fashion...
35 KB (4,104 words) - 14:03, 23 August 2024
rise to tertiary conformations of DNA, such as supercoils, knots and catenanes. Potential topological issues associated with the double-helical structure...
57 KB (6,173 words) - 00:11, 11 December 2023
triazole ligation supramolecular chemistry: calixarenes, rotaxanes, and catenanes dendrimer design carbohydrate clusters and carbohydrate conjugation by...
48 KB (5,450 words) - 19:30, 21 October 2024
Examples of mechanically interlocked molecular architectures include catenanes, rotaxanes, molecular knots, and molecular Borromean rings. Work in this...
12 KB (1,303 words) - 02:13, 6 January 2024
origin, but the latter uses a P1 plasmid-type origin, making it a chromid. Catenane Möbius strip Nucleoid Plasmid Ribbon theory Rolling circle replication...
21 KB (2,745 words) - 15:34, 29 June 2024
cleavage of single and double stranded DNA to relax supercoils, untangle catenanes, and condense chromosomes in eukaryotic cells. Topoisomerase inhibitors...
85 KB (9,593 words) - 14:56, 17 October 2024
dynamics and entanglement, including strategies to construct rotaxanes, catenanes and molecular knots and some of the earliest synthetic molecular motors...
22 KB (1,686 words) - 23:17, 4 October 2024
molecular architectures in Supramolecular chemistry comprises a.o., Catenane and Rotaxane molecules, and Molecular knot Interlock fabric, a double-knitted...
1 KB (149 words) - 12:10, 3 May 2022
founded in the 16th century. Borromean rings, a link with three closed loops Catenane, a molecule with two linked loops Solomon's knot, two loops which are doubly...
9 KB (892 words) - 16:20, 15 November 2022
mechanically-interlocked molecular architectures such as molecular Borromean rings, catenanes and rotaxanes utilising molecular recognition and molecular self-assembly...
40 KB (3,245 words) - 00:49, 14 August 2024
al. in 2000 to describe molecular knots by analogy with rotaxanes and catenanes, which are other mechanically interlocked molecular architectures. The...
21 KB (2,316 words) - 10:52, 12 January 2024
after oligonucleotide synthesis. Some synthetic macromolecules, such as catenanes and rotaxanes, dendrimers and hyperbranched polymers, and other assemblies...
70 KB (8,236 words) - 05:45, 20 September 2024
catenatriphosphazenes. Related compounds in organic chemistry are the catenanes. The notation sn stands for stereospecific numbering, and indicates a...
21 KB (2,425 words) - 08:23, 21 October 2024
Examples of mechanically interlocked molecular architectures include catenanes, rotaxanes, molecular knots, molecular Borromean rings and ravels. In...
34 KB (3,711 words) - 08:07, 12 November 2024
often bioactive and could be useful for drug delivery. Cryptand Rotaxane Catenane Molecular knot Effective molarity Macrocyclic stereocontrol Macrocyclic...
27 KB (3,288 words) - 22:37, 24 August 2024
ends are linked with each other to obtain two closed rings. A bistable catenane (a ring with two π-donor components) is already a simple example of a molecular...
9 KB (938 words) - 15:02, 7 September 2024
showed how the ability of the two rings in [2]catenane to rotate alone each other enables [2]catenane to be used as a mechanical protecting group via...
12 KB (1,003 words) - 13:18, 28 June 2024