| Heat | Lane | Name | Country | Mark | Q | React |
| 1 | 6 | Dwain Chambers |  United Kingdom | 6.69 | Q | 0.261 |
| 1 | 2 | Isaac Uche |  Nigeria | 6.74 | Q | 0.269 |
| 1 | 1 | Ihor Bodrov |  Ukraine | 6.76 | q | 0.138 |
| 1 | 5 | Amr Ibrahim Mostafa Seoud |  Egypt | 6.78 NR | q | 0.220 |
| 1 | 3 | Gibrilla Pato Bangura |  Sierra Leone | 6.89 | | 0.250 |
| 1 | 7 | Khalil Al-Hanahneh |  Jordan | 7.14 | | 0.291 |
| 1 | 8 | Aisea Tohi |  Tonga | 7.24 PB | | 0.213 |
| 1 | 4 | Reginaldo Micha Ndong |  Equatorial Guinea | 7.72 PB | | 0.452 |
| 2 | 5 | Leroy Dixon |  United States | 6.64 | Q | 0.142 |
| 2 | 3 | Francis Obikwelu |  Portugal | 6.70 | Q | 0.266 |
| 2 | 2 | Fabio Cerutti |  Italy | 6.73 | q | 0.190 |
| 2 | 7 | Kael Becerra |  Chile | 6.75 | q | 0.151 |
| 2 | 8 | Danny D'Souza |  Seychelles | 7.02 NR | | 0.219 |
| 2 | 4 | Moudjib Toyb |  Comoros | 7.03 | | 0.188 |
| 2 | 6 | Michael Alicto |  Guam | 7.27 PB | | 0.230 |
| 2 | 1 | Federico Gorrieri |  San Marino | 7.49 SB | | 0.197 |
| 3 | 3 | Kim Collins |  Saint Kitts and Nevis | 6.70 | Q | 0.166 |
| 3 | 5 | Andrey Yepishin |  Russia | 6.76 | Q | 0.246 |
| 3 | 8 | José Carlos Moreira |  Brazil | 6.79 | | 0.250 |
| 3 | 2 | Seth Amoo |  Ghana | 6.88 | | 0.264 |
| 3 | 1 | Seng Song Poh |  Singapore | 6.93 SB | | 0.172 |
| 3 | 6 | Sébastien Gattuso |  Monaco | 6.94 NR | | 0.246 |
| 3 | 7 | Taufik Rahmadi |  Indonesia | 6.97 PB | | 0.215 |
| 3 | 4 | Tavita Solomona |  Samoa | 7.35 PB | | 0.255 |
| 4 | 7 | Simone Collio | Italy | 6.71 | Q | 0.162 |
| 4 | 1 | Martial Mbandjock |  France | 6.72 | Q | 0.171 |
| 4 | 8 | Dmytro Hlushchenko | Ukraine | 6.77 | q | 0.255 |
| 4 | 2 | Adrian Durant |  United States Virgin Islands | 6.78 | q | 0.156 |
| 4 | 5 | Omar Jouma Bilal Al-Salfa |  United Arab Emirates | 6.88 | | 0.262 |
| 4 | 3 | Jack Howard |  Federated States of Micronesia | 7.13 SB | | 0.189 |
| 4 | 4 | Abraham Kepsen |  Vanuatu | 7.44 PB | | 0.252 |
| 4 | 6 | Kermeliss Olonghot |  Republic of the Congo | DNS | | |
| 5 | 7 | Olusoji Fasuba | Nigeria | 6.64 | Q | 0.167 |
| 5 | 8 | Brendan Christian |  Antigua and Barbuda | 6.67 | Q | 0.141 |
| 5 | 2 | Henry Vizcaino |  Cuba | 6.70 | q | 0.161 |
| 5 | 5 | Chun Wai Leung |  Hong Kong | 6.97 | | 0.221 |
| 5 | 4 | Idrissa Sanou |  Burkina Faso | 7.03 | | 0.275 |
| 5 | 3 | Aleksandr Abrahamyan |  Armenia | 7.38 PB | | 0.290 |
| 5 | 6 | Dylab Menzies |  Norfolk Island | 7.42 SB | | 0.168 |
| 6 | 5 | Simeon Williamson | United Kingdom | 6.69 | Q | 0.159 |
| 6 | 2 | Marius Broening |  Germany | 6.74 | Q | 0.257 |
| 6 | 1 | Maarten Heisen |  Netherlands | 6.77 | q | 0.248 |
| 6 | 4 | Ramil Guliyev |  Azerbaijan | 6.84 | | 0.249 |
| 6 | 6 | Darren Gilford |  Malta | 6.99 SB | | 0.157 |
| 6 | 7 | Hin Fong Pao |  Macau | 7.07 SB | | 0.235 |
| 6 | 3 | Rabangaki Nawai |  Kiribati | 7.26 PB | | 0.246 |
| 6 | 8 | Leon Mengloi |  Palau | 7.51 PB | | 0.273 |
| 7 | 4 | Yhann Plummer |  Jamaica | 6.64 PB | Q | 0.169 |
| 7 | 8 | Vicente de Lima | Brazil | 6.71 | Q | 0.152 |
| 7 | 5 | Alex Trembach |  Israel | 6.93 | | 0.174 |
| 7 | 2 | Adrian Ferreira |  Paraguay | 7.19 PB | | 0.206 |
| 7 | 3 | Kilakone Siphonexay |  Laos | 7.41 PB | | 0.266 |
| 7 | 7 | Daniel Bailey | Antigua and Barbuda | DSQ | | |
| 7 | 6 | Ben Youssef Meité |  Ivory Coast | DNS | | |
| 7 | 1 | Sompote Suwannarangsri |  Thailand | DNS | | |
| 8 | 8 | Michael Rodgers | United States | 6.62 | Q | 0.137 |
| 8 | 6 | Ángel David Rodríguez |  Spain | 6.69 | Q | 0.169 |
| 8 | 5 | Rolando Palacios |  Honduras | 6.83 | | 0.287 |
| 8 | 4 | Jared Lewis |  Saint Vincent and the Grenadines | 6.89 | | 0.168 |
| 8 | 2 | Lerone Clarke | Jamaica | 6.89 | | 0.383 |
| 8 | 3 | Francis Manioru |  Solomon Islands | 7.22 SB | | 0.257 |
| 8 | 7 | Shahriful Bahrin Zainal |  Brunei | 7.44 NR | | 0.255 |
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