Cerium(III) sulfate
Names | |
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IUPAC name Cerium(III) sulfate | |
Other names Cerous sulfate | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.033.299 |
EC Number |
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PubChem CID | |
UNII | |
CompTox Dashboard (EPA) | |
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Properties | |
Ce2(SO4)3 | |
Molar mass | 568.42 g/mol (anhydrous) |
Appearance | White to off white solid (anhydrous) |
Density | 2.886 g/mL at (25 °C) |
Melting point | 920 °C (1,690 °F; 1,190 K) (decomposes) |
Boiling point | NA |
9.25 g/100 mL (20 °C) Hygroscopic | |
Hazards | |
GHS labelling: | |
Warning | |
H315, H319, H335 | |
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501 | |
Safety data sheet (SDS) | External MSDS |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Cerium(III) sulfate, also called cerous sulfate, is an inorganic compound with the formula Ce2(SO4)3. It is one of the few salts whose solubility in water decreases with rising temperature. [1]
Cerium(III) sulfate (anhydrous) is a hygroscopic white solid, which begins to decompose above 600°C. It has a monoclinic crystal structure.
Cerium(III) sulfate tetrahydrate is a white solid that releases its water of crystallisation at 220 °C. It has (like the white octahydrate) a monoclinic crystal structure with the space group P21/c (space group 14). The nonahydrate has a hexagonal crystal structure with the space group P63/m (space group 176). Hydrates of this compound are known with 12, 9, 8, 5, 4 and 2 parts of water of crystallisation.
References
[edit]- ^ Daniel L. Reger; Scott R. Goode; David Warren Ball (2 January 2009). Chemistry: Principles and Practice. Cengage Learning. p. 482. ISBN 978-0-534-42012-3. Retrieved 23 March 2013.