Coal slurry

Coal slurry is a mixture of solids (mined coal or coal waste) and liquids (water or organic)[1] produced by a coal preparation plant.

Preparation

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To transform the coal ash into a slurry, coal is separated from non-combustible components and can be fractionated by particle size as well. Coal slurry can be transferred by pipeline or with specialized pumps such as a progressive cavity pump to pump the highly abrasive, corrosive and viscous coal slurry.[2] More than 7 billion tons of coal are mined per year (2010), using approximately 200 litres of water per ton.[3] However, the amount of water required hinges on the surface characteristics of the coal being used. Most coal slurries require the addition of a surfactant to reduce the viscosity, ergo reduce the stress on pipelines and pumps.[4]

Recent studies have employed new methods of slurry preparation, like using ultrasonic irradiation and a mixture of natural and synthetic surfactants to improve the stability and rheological properties of coal slurry.[5][6]

Environmental concerns

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A 2014 coal slurry spill into a river at Patriot Coal, West Virginia. A straw impoundment has been created across the river to try to hold the spillage.[7]

Ideally, coal slurry consists only of crushed coal and water, which can be efficiently separated. In practice, the separation is significantly costly due to the large amounts of water needed and wastewater generated by the process.[8] Furthermore, the slurry consists also of very fine coal dust that results in a waste called blackwater. As blackwater cannot be purified by a water treatment plant,[9] it is stored in large impoundment ponds. Such ponds are susceptible to disastrous releases, such as the Buffalo Creek flood of 1972 or the Martin County coal slurry spill of 2000, which released over 250 million gallons of coal slurry.[10] Coal slurry can contain hazardous chemicals such as arsenic and mercury and can kill aquatic wildlife, as was the case in the Martin County spill.[11] This impounded liquid waste can sometimes total billions of gallons[12] in a single facility.

The scope of coal slurry applications

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To date, coal slurry fuels are recognised to have low energy density and therefore can only be successfully combusted in high compression engines such as diesel or gas turbine power plants (large engines with low energy density requirements). Other engine systems include slow speed diesel engines and turbines used as power plants for shipping and stationary electricity production.[13] However, in the combustion market, for small and medium power plants ranging from 20 kW (27 hp) to 5 MW (6,700 hp), the utilisation of CSs will require boiler’s retrofitting.[14]

Other applications found for these slurries are in systems such as boilers, gasifiers and stationary engines with specific requirements divided into two main areas: chemical and physical as shown in table below.

Aspect Parameter Application
Fuel chemistry [15] Low N < 0.6 wt% (db.)

Low S < 0.1 wt% (db.) (limit for corrosion)

Boiler
Ash < 0.01% wt% (db.) Diesel engine (No. 2 diesel fuel)
Bulk density 0.6-0.9 ton/m3 or higher Boiler and gasifier
Physical and handling property [15] Viscosity ≤1000 mPa at shear rate of 100s−1 at 25 °C (77 °F) (desirable for fuel handling). Boiler

See also

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References

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  1. ^ Shin, Yu-Jen; Shen, Yun-Hwei (1 June 2007). "Preparation of coal slurry with organic solvents". Chemosphere. 68 (2): 389–393. Bibcode:2007Chmsp..68..389S. doi:10.1016/j.chemosphere.2006.12.049. ISSN 0045-6535. PMID 17276487.
  2. ^ Admin. "Transferring coal slurry made easy". www.globalpumps.com.au. Retrieved 11 April 2019.
  3. ^ The Coal Handbook: Towards Cleaner Production. Volume 1; Coal Production. Osborne, D. G. Cambridge: Woodhead Publishing Ltd. 2013. ISBN 9780857097309. OCLC 875224821.{{cite book}}: CS1 maint: others (link)
  4. ^ Guo, D (1 February 1998). "Rheological behaviour of oil-based heavy oil, coal and water multiphase slurries". Fuel. 77 (3): 209–210. doi:10.1016/s0016-2361(97)00172-5. ISSN 0016-2361.
  5. ^ Das, Debadutta; Dash, Uma; Meher, Jibardhan; Misra, Pramila K. (1 September 2013). "Improving stability of concentrated coal–water slurry using mixture of a natural and synthetic surfactants". Fuel Processing Technology. 113: 41–51. doi:10.1016/j.fuproc.2013.02.021.
  6. ^ Guo, Zhaobing; Feng, Ruo; Zheng, Youfei; Fu, Xiaoru (1 July 2007). "Improvement in properties of coal water slurry by combined use of new additive and ultrasonic irradiation". Ultrasonics Sonochemistry. 14 (5): 583–588. doi:10.1016/j.ultsonch.2006.12.001. ISSN 1350-4177. PMID 17236802.
  7. ^ Conlon, Kevin (12 February 2014). "Officials: Coal slurry spill blackens 6 miles of West Virginia creek". CNN. Retrieved 2 May 2017.
  8. ^ Andrews, Graham F., and Karl S. Noah. "The Slurry-column Coal Beneficiation Process." Fuel Processing Technology 52.1-3 (1997): 247-66. Print.
  9. ^ Shiao-Hung Chiang and James T. Cobb "Coal Conversion Processes, Cleaning and Desulfurization" in Kirk-othmer Encyclopedia of Chemical Technology Wiley-VCH, 2000. doi:10.1002/0471238961.0312050103080901.a01
  10. ^ Kilborn, Peter T. "A Torrent of Sludge Muddies a Town's Future." The New York Times. The New York Times, 25 Dec. 2000. Web. 25 Apr. 2019.
  11. ^ Leung, Rebecca. "A Toxic Cover-Up?" CBS News. CBS Interactive, 01 Apr. 2004. Web. 25 Apr. 2019.
  12. ^ "Coal Sludge Impoundments, West Virginia." NASA. NASA, 18 Mar. 2006. Retrieved 10 Apr. 2019.
  13. ^ Gary K Ellem (12 December 2023). "A NOVEL 2ND GENERATION LIQUID BIOFUEL PRODUCTION CONCEPT USING BIOMASS CHAR". Chemeca 2010: Engineering at the Edge; 26–29 September 2010, Hilton Adelaide, South Australia.
  14. ^ Bridgwater, A. V.; Grassi, G. (6 December 2012). Biomass Pyrolysis Liquids Upgrading and Utilization. Springer Science & Business Media. ISBN 978-94-011-3844-4.
  15. ^ a b Abdullah, Hanisom; Mourant, Daniel; Li, Chun-Zhu; Wu, Hongwei (21 October 2010). "Bioslurry as a Fuel. 3. Fuel and Rheological Properties of Bioslurry Prepared from the Bio-oil and Biochar of Mallee Biomass Fast Pyrolysis". Energy & Fuels. 24 (10): 5669–5676. doi:10.1021/ef1008117. ISSN 0887-0624.
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