Ferrous tungstate
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IUPAC names
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Other names Iron(II) tungstate | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.034.188 |
PubChem CID | |
CompTox Dashboard (EPA) | |
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Properties | |
FeWO4, sometimes expressed FeO4W | |
Molar mass | 303.68 g/mol |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Ferrous tungstate (FeWO4) is an inorganic compound. It can be synthesized from iron(III) chloride and sodium tungstate under hydrothermal conditions with the presence of L-cysteine reduces Fe3+ to Fe2+.[1] Ferberite is composed of this compound.[2]
Synthesis techniques
[edit]Hydrothermal process
[edit]The hydrothermal process[definition needed] is a method for synthesizing FeWO4 crystals. Reagents used in this process are ethylenediaminetetraacetic acid disodium salt (Na2EDTA) and hexamethylenetetramine (HMT). Na2EDTA helps in controlling the morphology of FeWO4 crystals by binding to metal ions and preventing their premature precipitation and HMT acts as a pH buffer and a source of ammonia.[3]
See also
[edit]References
[edit]- ^ Zhang, Jian; Zhang, Yan; Yan, Jing-Yi; Li, Shi-Kuo; Wang, Hai-Sheng; Huang, Fang-Zhi; Shen, Yu-Hua; Xie, An-Jian (2012). "A novel synthesis of star-like FeWO4 nanocrystals via a biomolecule-assisted route". Springer. 14 (4). doi:10.1007/s11051-012-0796-6.
- ^ "Ferberite". 13 March 2014.
- ^ Zhang, Jian; Wang, Yang; Li, Shikuo; Wang, Xiufang; Huang, Fangzhi; Xie, Anjian; Shen, Yuhua (2011). "Controlled synthesis, growth mechanism and optical properties of FeWO4 hierarchical microstructures". CrystEngComm. 13 (19): 5744. doi:10.1039/C1CE05416C.