\documentclass[12pt,border=1pt]{standalone} \usepackage[T1]{fontenc} \usepackage[utf8]{inputenc} \usepackage{chemfig,chemmacros} \usepackage{lmodern} \usetikzlibrary{decorations.pathmorphing} \chemsetup[chemformula]{font-shape=sf,format=\sffamily} \renewcommand*{\familydefault}{\sfdefault} \renewcommand*\printatom[1]{\ensuremath{\mathsf{#1} } } \setatomsep{2.5em} \setdoublesep{.6ex} \setarrowdefault{,2,thick} \setbondstyle{thick} \makeatletter % From: http://tex.stackexchange.com/a/125761 % Initial arguments: % #1, #2: Same as for -U> (above arrow) % #3: Additional label at midpoint (also above arrow) % #4, #5, #6: Like #1, #2, and #3, but below arrow \definearrow9{-X>}{% \CF@arrow@shift@nodes{#7}% \expandafter\draw\expandafter[\CF@arrow@current@style,-CF@full](\CF@arrow@start@node)--(\CF@arrow@end@node)node[midway](Xarrow@arctangent){};% \edef\CF@tmp@str{\ifx\@empty#1\@empty[draw=none]\fi}% \expandafter\draw\CF@tmp@str (Xarrow@arctangent)% arc[radius=\CF@compound@sep*\CF@current@arrow@length*\ifx\@empty#8\@empty0.333\else#8\fi,start angle=\CF@arrow@current@angle-90,% delta angle=-\ifx\@empty#9\@empty60\else#9\fi]node(Xarrow1@start){}; \edef\CF@tmp@str{[\ifx\@empty#2\@empty draw=none,\fi-CF@full]}% \expandafter\draw\CF@tmp@str (Xarrow@arctangent)% arc[radius=\CF@compound@sep*\CF@current@arrow@length*\ifx\@empty#8\@empty0.333\else#8\fi,start angle=\CF@arrow@current@angle-90,% delta angle=\ifx\@empty#9\@empty60\else#9\fi]node(Xarrow1@end){}; \edef\CF@tmp@str{\ifx\@empty#4\@empty[draw=none]\fi}% \expandafter\draw\CF@tmp@str (Xarrow@arctangent)% arc[radius=\CF@compound@sep*\CF@current@arrow@length*\ifx\@empty#8\@empty0.333\else#8\fi,start angle=\CF@arrow@current@angle+90,% delta angle=\ifx\@empty#9\@empty60\else#9\fi]node(Xarrow2@start){}; \edef\CF@tmp@str{[\ifx\@empty#5\@empty draw=none,\fi-CF@full]}% \expandafter\draw\CF@tmp@str (Xarrow@arctangent)% arc[radius=\CF@compound@sep*\CF@current@arrow@length*\ifx\@empty#8\@empty0.333\else#8\fi,start angle=\CF@arrow@current@angle+90,% delta angle=-\ifx\@empty#9\@empty60\else#9\fi]node(Xarrow2@end){}; \edef\CF@tmp@str{\if\string-\expandafter\@car\detokenize{#7.}\@nil-\else+\fi}% \CF@arrow@display@label{#1}{0}\CF@tmp@str{Xarrow1@start}{#2}{1}\CF@tmp@str{Xarrow1@end}% \CF@arrow@display@label{#3}{0.5}\CF@tmp@str\CF@arrow@start@node{}{}{}\CF@arrow@end@node% \edef\CF@tmp@str{\if\string-\expandafter\@car\detokenize{#7.}\@nil+\else-\fi}% \CF@arrow@display@label{#4}{0}\CF@tmp@str{Xarrow2@start}{#5}{1}\CF@tmp@str{Xarrow2@end}% \CF@arrow@display@label{#6}{0.5}\CF@tmp@str\CF@arrow@start@node{}{}{}\CF@arrow@end@node% } \makeatother \begin{document} \definesubmol\nobond{-[,0.2,,,draw=none]} \definesubmol{rb}{Ribotide} \schemestart[][west] \chemname{\chemfig{ {\color{red}P}-O--[:-18]*5(-(<:HO)-(<:OH)-(<:OH)-O-) } }{\color{brown}R5P} \arrow{-X>[{\color{orange}ATP}][{\color{orange}AMP}][{\color{magenta}\ch{Mg^2+} }][][][\color{blue}PRPS1]} \chemname{\chemfig{ {\color{red}P}-O--[:-18]*5(-(<:HO)-(<:OH)-(<:O-[0]{\color{red}P}-[0,,,,red,decorate,decoration=snake, segment length=6pt]{ {\color{red}P} })-O-) } }{\color{brown}PRPP} \arrow{-X>[{\color{orange}Gln},{\color{red}\ch{H2O} }][{\color{brown}Glu},{\color{red}2\ch{P_i} }][{\color{magenta}\ch{Mg^2+} }][][][\parbox{5em}{\centering\color{blue}PPAT\\1}]} \chemname{\chemfig{ {\color{red}P}-O--[:-18]*5(-(<:HO)-(<:OH)-(<NH_2)-O-) } }{\color{brown}5-PRA} \arrow(.-45--){-X>[*0{ {\color{orange}ATP},{\color{brown}Gly} }][*0{ {\color{orange}ADP},{\color{red}\ch{P_i} } }][*0{\color{magenta}\ch{Mg^2+} }][][][*0\parbox{5em}{\centering\color{blue}GART (E1)\\2}]}[-90,1.5] \chemname*{\chemfig{O=[:30](-[2]-[::-60]NH_2)-[:-30]NH-[6,,1]!{rb} } }{\color{brown}GAR} \arrow{-X>[][][\parbox{5em}{\centering\color{blue}GART (E2)\\3}][\parbox{2.75cm}{ {\color{orange}\ch{N^{10} }-formyl-THF} }][{\color{orange}THF}][][-2em]}[180,3] \chemname*{\chemfig{ O=[:30] *6(-NH(-[6]!{rb})-[,,,,draw=none]O=-NH--) } }{\color{brown}FGAR} \arrow{-X>[][][\parbox{5em}{\centering\color{blue}PFAS\\4}][{\color{orange}Gln},{\color{orange}ATP},{\color{red}\ch{H2O} }][{\color{brown}Glu},{\color{orange}ADP},{\color{red}\ch{P_i} }][{\color{magenta}\ch{Mg^2+} }][-2em]}[180,2.5] \chemname*{\chemfig{ HN=[:30] *6(-NH(-[6]!{rb})-[,,,,draw=none]O=-NH--) } }{\color{brown}FGAM} \arrow{-X>[][][\parbox{5em}{\centering\color{blue}GART (E3)\\5}][{\color{orange}ATP}][{\color{orange}ADP},{\color{red}\ch{P_i} }][{\color{magenta}\ch{Mg^2+} }][-2em]}[180] \chemname*{\chemfig{*5((-H_2N)-N(-!{rb})-=N-=)} }{\color{brown}AIR} \arrow{-X>[*0{ {\color{orange}ATP},{\color{red}\ch{HCO3^-} } }][*0{ {\color{orange}ADP},{\color{red}\ch{P_i} } }][*0{\color{magenta}\ch{Mg^2+} }][][][*0\parbox{5em}{\centering\color{blue}PAICS (E1)\\6}]}[-90] \chemname*{\chemfig{*5((-HN_2)-N(-!{rb}) -=N- (-[:150](=[::-60]O)-[::60]OH) =)} }{\color{brown}CAIR} \arrow{-X>[{\color{orange}ATP},{\color{brown}ASP}][{\color{orange}ADP},{\color{red}\ch{P_i} }][{\color{magenta}\ch{Mg^2+} }][][][\parbox{5em}{\centering\color{blue}PAICS (E2)\\7}]} \chemname*{\chemfig{ O=[:30] *6(-O^{-} -[,,,,draw=none]-[,,,,draw=none]\chembelow{N}{H} (-[:30](=[2]O)-[:-36]*5(=(-H_2N)-N(-!{rb})-=N-)) - (-(=[::60]O)-[::-60]O^{-}) --) } }{\color{brown}SACAIR} \arrow{-X>[][{\color{brown}Fumarate}][][][][\parbox{5em}{\centering\color{blue}ADSL\\8}]}\quad \chemname*{\chemfig{*5((-HN_2)-N(-!{rb}) -=N- (-[:120](=[::-60]O)-[::60]NH_2) =)} }{\color{brown}AICAR} \arrow(.-50--){-X>[*0\parbox{2.75cm}{ {\color{orange}\ch{N^{10} }-formyl-THF} }][*0{ {\color{orange}THF} } ][][][][*0\parbox{5em}{\centering\color{blue}ATIC (E1)\\9}]}[-90,1.5] \chemname*{\chemfig{*5((-HN-[::-60]=[::60]O)-N(-!{rb}) -=N- (-[:150](=[::-60]O)-[::60]NH_2) =)} }{\color{brown}FAICAR} \arrow{-X>[][][\parbox{5em}{\centering\color{blue}ATIC (E2)\\10}][][{\color{red}\ch{H2O} }][][-2em]}[180,2.5] \chemname*{\chemfig{ *6(=N- (*5(-N(-!{rb})-=N-=)) --(=O) -[,,,2]HN-[,,2]=) } }{\color{brown}IMP} \schemestop \end{document}