Phosphatoantimonate
Phosphatoantimonates are compounds that contain anions that contain phosphorus and antimony in the +5 oxidation state, along with oxygen. Thus they are a compound of phosphate and antimonate, bound together by oxygen.
phosphatoantimonates have been investigated as catalysts,[1] and ion exchange materials.[2]
List
[edit]formula | mw | crystal system | space group | unit cell Å | volume | density | comment | references |
---|---|---|---|---|---|---|---|---|
SbOPO4 | monoclinic | C2c | a = 6.791 b = 8.033 c = 7.046 β = 115.90° Z=4 | [3] | ||||
SbIIISbV3(PO4)6 | trigonal | R3 | a = 16.880 c = 21.196 Z=12 | 5230 | mixed valence | [4] | ||
HSb(PO4)2·2H2O | layered; can be exfoliated; can exchange H+ with other ions; can reversibly dehydrate | [5][6] | ||||||
H3Sb3P2O14•xH2O | layered | [7] | ||||||
H5Sb5P2O20•xH2O | 3D with channels | [7] | ||||||
Li5Sb5P2O20 | [8] | |||||||
(NH4)3Sb3P2O14•3H2O | [9] | |||||||
Na3SbO(PO4)2 | orthorhombic | P212121 | a = 6.964 b = 9.284 c = 12.425 Z = 4 | 1D | [10][11] | |||
Na3Sb3P2O14 | [8] | |||||||
Na5Sb5P2O20 | [8] | |||||||
Mg0.50SbFe(PO4)3 | hexagonal | P3 | a = 8.3443 c = 22.3629 Z=6 | nasicon | [12] | |||
KSb2PO8 | monoclinic | Cc | a=12.306 b=7.086 c=15.037 β=95.82° Z=8 | 1304.5 | 4.498 | colourless; 3D | [13][14] | |
KSb2PO8−xNy | [15] | |||||||
KSbP2O8 | rhombohedral | R3 | a = 4.7623 c = 25.409 Z = 3 | 2D | [13][16] | |||
K2SbPO6 | orthorhombic | Pnma | a= 9.429 b= 5.891 c= 11.030 Z= 4 | 1D | [13][17] | |||
4K2O · 4Sb2O5 · P2O5 · 8H2O K8Sb8P2O29·8H2O | monovlinic | a = 23.952 b = 9.515 c = 8.193 β = 124.77° | 31P NMR shift −−6.77 ppm | [18][19] | ||||
K3Sb3P2O14 | rhombohedral | R3m | a = 7.147 c = 30.936 Z = 3 | reversible hydration; 2D | [13][20] | |||
K3Sb3P2O14, 1.32H2O | rhombohedral | R3m | a = 7.147 c = 30.936 Z=3 | [21] | ||||
K3Sb3P2O14·5H2O | hexagonal | P3 | Z=6 | [22] | ||||
K5Sb5P2O20 | orthorhombic | Pnnm | a= 23.443 b= 18.452 c= 7.149 z= 6 | 3D | [13][23] | |||
K2SbAs0.5P0.5O6 | orthorhombic | [24] | ||||||
ScSbV3(PO4)6 | monoclinic | P21/n | a=11.810 b=8.616 c=8.400 β=90.80° | 854.6 | [4] | |||
NaSbCr(PO4)3 | rhombohedral | R3 | a = 8.329 c = 22.094 Z=6 | 1327 | nasicon | [25] | ||
Ca0.5AlSb(PO4)3 | a=8.56 c=21.87 | 4.128 | nasicon | [26] | ||||
Mn0.50SbFe(PO4)3 | rhombohedral | R3 | a=8.375 c=21.597 | nasicon | [27][28] | |||
Mn0.5AlSb(PO4)3 | rhombohedral | R3c | a=8.270 c=21,799 | 3.56 | nasicon | [26] | ||
Ca0.5CrSb(PO4)3 | a=8.61 c=22.08 | 4.321 | nasicon | [26] | ||||
Mn0.5CrSb(PO4)3 | monoclinic | P21/n | a=12.280 b=8.814 c=8.613 β=91.03° | 3.45 | [26] | |||
Sb1.50Fe0.50(PO4)3 | hexagonal | R32 | a=8.305 c=22.035 | [29] | ||||
(Sb0.50Fe0.50)P2O7 | orthorhombic | Pna21 | a=7.865 b=15.699 c=7.847 | pyrophosphate | [29] | |||
CaSb0.50Fe1.50(PO4)3 | rhombohedral | R3c | a=8.514 c=21.871 | nasicon | [30] | |||
Ca0.50SbFe(PO4)3 | rhombohedral | R3 | a=8.257 c=22.276 | nasicon | [27][30] | |||
Mn0.5FeSb(PO4)3 | rhombohedral | R3c | a=8.374 c=21.593 | 3.68 | nasicon | [26] | ||
NaSbFe(PO4)3 | rhombohedral | R3 | a = 8.361 c = 22.222 Z=6 | 1345 | nasicon | [25] | ||
Co[Sb(PO4)2]2·6H2O | [5] | |||||||
Ni0.50SbFe(PO4)3 | hexagonal | P3 | a = 8.3384 c = 22.3456 | nasicon | [12] | |||
Rb3Sb3P2O14 | [8] | |||||||
Rb3Sb3P2O14•3H2O | rhombohedral | R3m | a=7.1445 c=31.802 | [9] | ||||
Rb5Sb5P2O20 | [8] | |||||||
Sr0.50SbFe(PO4)3 | rhombohedral | R3 | a = 8.227 c = 22.767 | nasicon | [27] | |||
SrSb0.50Cr0.50(PO4)2 | monoclinic | C2/c | a= 16.5038 b= 5.1632 c= 8.0410 β = 115.85° Z=4 | 617 | yavapaiite | [31] | ||
SrSb0.50Fe1.50(PO4)3 | rhombohedral | R3c | a = 8.339 c = 22.704 | nasicon | [27] | |||
Sr(SbV0.50FeIII0.50)(PO4)2 | monoclinic | C2/c | a = 16.5215 b = 5.1891 c = 8.0489 β = 115.70° Z=4 | yavapaiite | [32] | |||
Sr(Ga0.5Sb0.5)(PO4)2 | monoclinic | C2/c | a=16.455; b=5.158 c= 8.005 β=115.49° Z=4 | 613 | [33] | |||
YSbV3(PO4)6 | R3 | a=17.019 c=21.233 | 5326 | [4] | ||||
Cd0.50SbFe(PO4)3 | rhombohedral | R3 | a=8.313 c=21.996 | nasicon | [27][28] | |||
SbV1.50InIII0.50(PO4)3 | monoclinic | P21/n | a=11.801 b=8.623 c=8.372 β=90.93° | [34] | ||||
SbV0.50InIII0.50P2O7 | orthorhombic | Pna21 | a=7.9389 b=16.0664 c=7.9777 | pyrophosphate | [34] | |||
InSbV3(PO4)6 | monoclinic | P21/n | a=11.792 b=8.622 c=8.379 β=90.91° | 851.8 | [4] | |||
NaSbIn(PO4)3 | rhombohedral | R3 | a=8.329 c = 23.031 Z=6 | 1383 | nasicon | [25] | ||
Cs3Sb3P2O14•3H2O | rhombohedral | R3m | a=7.153 c=32.840 | [9] | ||||
Cs4MgSb6P4O28 | 1858.39 | tetragonal | I41/a | a=16.5170 c=10.7355 Z=4 | 2928.8 | 4.22 | band gap 4.50 eV | [35] |
Cs4ZnSb6P4O28 | tetragonal | I41/a | a=16.4821 c=10.7453 Z=4 | 2919.1 | 4.32 | band gap 4.48 eV | [35] | |
K0.8Ba1.6Sb4O9(PO4)2 (0 < x < 0.4) | orthorhombic | Pnma | a = 20.998 b = 7.168 c = 9.569 | [36] | ||||
Ba2Sb4O9(PO4)2 | orthorhombic | Pnma | a = 20.9237 b = 7.1836 c = 9.5189 Z = 4 | [36] | ||||
BaSb0.50Cr0.50(PO4)2 | monoclinic | C2/m | a= 8.140 b= 5.175 c= 7.802 β = 94. 387° Z=2 | 328 | yavapaiite | [31] | ||
BaSb2/3Mn1/3(PO4)2 | monoclinic | C2/m | a= b= c=7.8808 β=94.4° Z=2 | 337 | [37] | |||
Ba(Sb0.50FeIII0.50)(PO4)2 | monoclinic | C2/m | a = 8.1568 b = 5.1996 c = 7.8290 β = 94.53° Z=2 | yavapaiite | [32] | |||
BaSb2/3Co1/3(PO4)2 | monoclinic | C2/m | c=7.8581 β=94.7° Z=2 | 333 | [37] | |||
BaSb2/3Cu1/3(PO4)2 | monoclinic | C2/m | c=7.8795 β=95.3° Z=2 | 331 | [37] | |||
BaSb2/3Zn1/3(PO4)2 | monoclinic | C2/m | c=7.8497 β=94.8° Z=2 | 332 | [37] | |||
Ba(Ga0.5Sb0.5)(PO4)2 | monoclinic | C2/m | a= 8.106 b= 5.178 c= 7.806 β=94.79° Z=2 | 327 | [33] | |||
Tl3Sb3P2O14•3H2O | rhombohedral | R3m | a=7.135 c=31.447 | [9] | ||||
PbSb0.50Cr0.50(PO4)2 | monoclinic | C2/c | a= 16.684 b= 5.156 c= 8.115 β = 115.35° Z=4 | 631 | yavapaiite | [31] | ||
Pb(Sb0.50FeIII0.50)(PO4)2 | monoclinic | C2/c | a = 16.6925 b = 5.1832 c = 8.1215 β = 115.03° | yavapaiite | [32] | |||
PbSb0.50Fe1.50(PO4)3 | rhombohedral | R3c | a = 8.313 c = 23.000 Z=6 | 1377 | nasicon | [38] | ||
Pb0.50SbFe(PO4)3 | rhombohedral | R3 | a = 8.2397 c = 22.7801 Z=6 | 1339 | nasicon | [38] | ||
Pb(Ga0.5Sb0.5)(PO4)2 | monoclinic | C2/c | a=16.622 b=5.163 c=8.067 β=114.85° | 628 | [33] | |||
BiSbV3(PO4)6 | trigonal | R3 | a=17.034 c=21.260 | 5342.1 | [4] | |||
CaSb0.50Bi1.50(PO4)3 | monoclinic | P21/m | a = 4.9358 b = 6.9953 c = 4.7075 β = 96.2° | [39] |
References
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: CS1 maint: DOI inactive as of May 2024 (link) - ^ a b Pagnoux, C.; Mar, A.; Verbaere, A.; Piffard, Y. (February 1995). "Synthesis and Structure of K2xBa2-xSb4O9(PO4)2 (0 < x < 0.4)". Journal of Solid State Chemistry. 114 (2): 399–405. doi:10.1006/jssc.1995.1061.
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- ^ a b "Structure and spectroscopic characterization of the two PbSb0.5Fe1.5(PO4)3 and Pb0.5SbFe(PO4)3 phosphates with Nasicon type-structure". J. Mater. Environ. Sci. 6 (12): 3483–3490. 2015.
- ^ Aatiq, Abderrahim; Tigha, My Rachid (March 2014). "Structure of a new Ca II 1/3 Sb V 1/6 Bi III 1/2 PO 4 phosphate". Powder Diffraction. 29 (1): 14–19. Bibcode:2014PDiff..29...14A. doi:10.1017/S0885715613000717. ISSN 0885-7156.