Thallium(III) nitrate
Names | |
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IUPAC name thallium(III) trinitrate | |
Other names thallic nitrate | |
Identifiers | |
3D model (JSmol) | |
ChEBI | |
ChemSpider | |
ECHA InfoCard | 100.033.918 |
PubChem CID | |
UNII | |
UN number | 2727 |
CompTox Dashboard (EPA) | |
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Properties | |
Tl(NO3)3 | |
Molar mass | 390.398 g/mol |
Appearance | colorless solid |
Melting point | 103 °C (217 °F; 376 K) |
Boiling point | decomposes |
decomposes | |
Hazards | |
GHS labelling: | |
Danger | |
NFPA 704 (fire diamond) | |
NIOSH (US health exposure limits): | |
IDLH (Immediate danger) | 15 mg/m3 |
Safety data sheet (SDS) | Fisher Scientific |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Thallium(III) nitrate, also known as thallic nitrate, is a thallium compound with chemical formula Tl(NO3)3.[1] It is normally found as the trihydrate. It is a colorless and highly toxic salt. It is a strong oxidizing agent useful in organic synthesis. Among its many transformations, it oxidizes methoxyl phenols to quinone acetals, alkenes to acetals, and cyclic alkenes to ring-contracted aldehydes.[2]
References
[edit]- ^ "Material Safety Data Sheet". Thermo Fisher Scientific.
- ^ Sibi, Mukund P.; Silva, Luiz F.; Carneiro, Vânia M. T. (2008-09-15). John Wiley & Sons, Ltd (ed.). Thallium(III) Nitrate Trihydrate. Chichester, UK: John Wiley & Sons, Ltd. doi:10.1002/047084289x.rt085.pub2. ISBN 978-0-471-93623-7.