Aluminium iodide - Simple English Wikipedia, the free encyclopedia

Aluminium iodide
Ball and stick model of aluminium iodide dimer
Names
Preferred IUPAC name
Aluminium iodide
Other names
Aluminium(III) iodide

Aluminum iodide
Aluminium triiodide

Aluminum triiodide
Identifiers
  • 7784-23-8 (anhydrate) checkY
  • 10090-53-6 (hexahydrate) checkY
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.140
EC Number
  • 232-054-8
UN number UN 3260
  • I[Al](I)I
  • dimer: I[Al-]1(I)[I+][Al-]([I+]1)(I)I
Properties
, (hexahydrate)
Molar mass 407.695 g/mol (anhydrous)
515.786 g/mol (hexahydrate)[1]
Appearance white (anhydrous) or yellow powder (hexahydrate)[1]
Density 3.98 g/cm3 (anhydrous)[1] 2.63 g/cm3 (hexahydrate)[2]
Melting point 188.28 °C (370.90 °F; 461.43 K) (anhydrous)
185 °C, decomposes (hexahydrate)[1][2]
Boiling point 382 °C (720 °F; 655 K) anhydrous, sublimes[1]
very soluble, partial hydrolysis
Solubility in alcohol, ether soluble (hexahydrate)
Structure
Monoclinic, mP16
P21/c, No. 14
a = 1.1958 nm

, b = 0.6128 nm

, c = 1.8307 nm
α = 90°, β = 90°, γ = 90°


8
Thermochemistry
Std enthalpy of
formation
ΔfHo298
-302.9 kJ/mol
Standard molar
entropy
So298
195.9 J/(mol·K)
Specific heat capacity, C 98.7 J/(mol·K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Aluminium iodide is any chemical compound made up of only aluminium and iodine. It is formed by the reaction of aluminium and iodine,[3] or the action of hydrogen iodide on aluminium metal.

  1. 1.0 1.1 1.2 1.3 1.4 Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 4.45. ISBN 1439855110.
  2. 2.0 2.1 Perry, Dale L. (19 April 2016). Handbook of Inorganic Compounds, Second Edition. CRC Press. p. 8. ISBN 978-1-4398-1462-8.
  3. G. W. Watt, J. L. Hall (1953). Inorganic Syntheses. Vol. IV. pp. 117–119.