四氯合铜(II)酸四甲基铵是一种配位化合物,化学式为[(CH3)4N]2[CuCl4]。
将氯化铜的乙醇溶液和四甲基氯化铵的乙醇溶液按化学计量比混合,得到四氯合铜(II)酸四甲基铵沉淀。[1]在水溶液中的反应,通过缓慢挥发,也能得到该配合物。[3]
该配合物和三溴乙酸银在硝基甲烷中反应,生成氯化银沉淀及蓝绿色的[(CH3)4N]2[Cu(O2CCBr3)4]配合物。[2]
参考文献[编辑]
- ^ 1.0 1.1 Furlani, Claudio; Morpugo, Giorgio. Properties and electronic structure of tetrahalocopper(II) complexes. Theoretica Chimica Acta, 1963. 1: 102-115. doi:10.1007/BF00529392.
- ^ 2.0 2.1 Puri, Jugal Kishore; Chhoker, Rajni. Synthesis and characterization of metal tribromoacetates and their alkali metal derivatives. Journal of Chemistry, 2013. doi:10.1155/2013/392310.
- ^ Sveleba, S. A.; Zhmurko, V. S.; Pankivskyi, Yu. I. Behavior of the optical birefringence in conditions of the "viscous" interaction. Acta Physica Polonica, A, 2000. 97 (2): 337-348. doi:10.12693/APhysPolA.97.337.
|
---|
| 铜(0,I) | |
---|
| 铜(I) | |
---|
| 铜(I,II) | |
---|
| 铜(II) | |
---|
| 铜(III) | |
---|
| 铜(IV) | |
---|
|