Nitride iodide

An iodide nitride is a mixed anion compound containing both iodide (I−) and nitride ions (N3−). Another name is metalloiodonitrides. They are a subclass of halide nitrides or pnictide halides.[1] Some different kinds include ionic alkali or alkaline earth salts, small clusters where metal atoms surround a nitrogen atom, layered group 4 element 2-dimensional structures (which could be exfoliated to a monolayer), and transition metal nitrido complexes counter-balanced with iodide ions. There is also a family with rare earth elements and nitrogen and sulfur in a cluster.

Related mixed-anion compounds include halogen variations: nitride fluoride, nitride chloride, and nitride bromide, and pnictogen variations phosphide iodide, arsenide iodide and antimonide iodides.

Production

[edit]

Nitride iodides may be produced by heating metal nitrides with metal iodides. The ammonolysis process heats a metal iodide with ammonia.[2] A related method heats a metal or metal hydride with ammonium iodide. The nitrogen source could also be an azide or an amide.[2]

List

[edit]
name formula formula
weight 		crystal
system 		space
group 		unit cell Å volume density comments ref
Li4NCl hexagonal R3 a=366.225 c=1977.18 Z=3 [3]
calcium nitride iodide Ca2NI P63/mmc a = 3.8095, c = 14.530, Z = 2 [4]
α-TiNI orthorhombic Pmmn a=3.941 b=3.51.5 c=8.955 Z=2 black [5]
NCr(I)(NiPr2)2 [6]
Cr(I)(N)(N(C(CD3)2CH3)(C6H3FMe))2 [7]
Zn2NI orthorhombic Pnma a=6.3590 b=6.2529 c=7.9549 <6 GPa [8]
strontium nitride iodide Sr2NI 316.15 trigonal R3m a = 4.0049 c = 23.055 Z=3 320.24 4.918 orange [9]
α-ZrNI orthorhombic Pmmn a=4.114 b=3.724 c=9.431 Z=2 orange [10][5]
β-ZrNI trigonal R3m a=3.718 c=31.381 Z=6 brown [5]
[(pcp)Mo(IV)(N)(I)][Na(15-crown-5)] pcp=C6H3(OPiPr2)2 [11]
Ba2NI
LiLa4N2I7 orthorhombic Pnma a = 13.7417, b = 12.1345, c = 10.7991 Z=4 @100K [12]
NaLa4N2I7 orthorhombic Pna21 a=14.0018 b=10.9315 c=12.1021 Z=4 5.361 colourless air sensitive [13]
Ce15N7I24 4245.6 orthorhombic Pnma a=12.060 b=32.216 c=16.360 Z=4 5.48 red; air sensitive [14]
NaCe4N2I7 orthorhombic Pna21 a=13.9703 b=10.8932 c=12.0194 Z=4 5.446 red air sensitive [13]
NaPr4N2I7 orthorhombic Pna21 a=13.9412 b=10.8578 c=11.9389 Z=4 5.524 yellowish green air sensitive [13]
NaNd4N2I7 orthorhombic Pna21 a=13.9135 b=10.86 c=11.86 Z=4 5.638 pinkish blue air sensitive [13]
(NdI2)3N [15]
(NdI2)3N(DME)4 [16]
NdI(S2N2)(THF) [17]
Nd3I5(S2N2)(S2)(THF)10 2088.72 monoclinic P21 a=12.393 b=43.389 c=12.684 β=90.013 Z=4 6820 2.034 yellow [15]
Ln3I5(S2)(S2N2)(THF)4(Phen)3 [18]
Ln3I5(S2)(S2N2)(THF)3(Py)7 [18]
(SmI)3N2(THF) [16]
ErI(S2N2)(THF) [17]
Nd2ErClI4-(S2)(S2N2)(THF)7 [17]
Nd2ErCl2I3(S2)(S2N2)(THF)7 [17]
(DyI2)3N [19]
Dy3I5(S2)(S2N2)(THF)10 [19]
Nd2DyI5(S2)(S2N2)(THF)7 [17]
Nd2DyI5(S3)(S2N2)(THF)9 2034.88 monoclinic P21/c a=23.1102 b=12.6551 c=23.8268 β =111.201 Z=4 6496.8 2.080 [20]
Nd2TbI5(S2)(S2N2)(THF)9 monoclinic P21/c a =23.1704 b =12.6340 c =23.8340, β =111.274° Z=4 [21]
Nd2TmI5(S2)(S2N2)(THF)9 monoclinic P21/c a =23.075 b =12.6540 c =23.809, β =111.460° Z=4 [21]
Nd2YbI5(S3)(S2N2)(THF)9 monoclinic P21/c a=23.0959 b=12.6632 c=23.8387 β =111.363 Z=4 6493.0 2.092 [20]
α-HfNI orthorhombic Pmmn a=4.10.67 b=3.6944 c=9.382 Z=2 [5][10]
β-HfNI trigonal R3m a=3.689 c=31.329 Z=6 brown [5]
ThNI tetragonal P4/nmm a=4.107 c=9.242 orange to golden grey [5][22]
UNI tetragonal P4/nmm a=3.99 c=9.20 Z=2 [5][23]

References

[edit]
  1. ^ Headspith, David A.; Francesconi, M. Grazia (October 2009). "Transition Metal Pnictide-Halides: A Class of Under-Explored Compounds". Topics in Catalysis. 52 (11): 1611–1627. doi:10.1007/s11244-009-9282-5. ISSN 1022-5528. S2CID 93522549.
  2. ^ a b Schurz, Christian M.; Shlyk, Larysa; Schleid, Thomas; Niewa, Rainer (January 2011). "Superconducting nitride halides MNX (M = Ti, Zr, Hf; X = Cl, Br, I)". Zeitschrift für Kristallographie. 226 (4): 395. Bibcode:2011ZK....226..395S. doi:10.1524/zkri.2011.1350. ISSN 0044-2968. S2CID 93973409.
  3. ^ Marx, Rupert (February 1997). "Preparation and Crystal Structure of Lithium Nitride Chloride Li4NCl". Journal of Solid State Chemistry. 128 (2): 241–246. Bibcode:1997JSSCh.128..241M. doi:10.1006/jssc.1996.7196.
  4. ^ Hadenfeldt, C.; Herdejürgen, H. (February 1987). "Darstellung und Kristallstruktur der Calciumnitridhalogenide Ca2NCl und Ca2NBr". Zeitschrift für anorganische und allgemeine Chemie (in German). 545 (2): 177–183. doi:10.1002/zaac.19875450220. ISSN 0044-2313.
  5. ^ a b c d e f g Schurz, Christian M.; Shlyk, Larysa; Schleid, Thomas; Niewa, Rainer (January 2011). "Superconducting nitride halides MNX (M = Ti, Zr, Hf; X = Cl, Br, I)". Zeitschrift für Kristallographie. 226 (4): 395. Bibcode:2011ZK....226..395S. doi:10.1524/zkri.2011.1350. ISSN 0044-2968. S2CID 93973409.
  6. ^ Odom, Aaron L.; Cummins, Christopher C. (1996-02-06). "A Chromium(VI) Nitrido−Silylmethyl Complex and a Chromium(V) μ-Nitrido Dimer: Synthetic and Structural Details". Organometallics. 15 (3): 898–900. doi:10.1021/om950842k. ISSN 0276-7333.
  7. ^ Mindiola, Daniel J.; Cummins, Christopher C. (1998). "Deprotonated 2,3:5,6-Dibenzo-7- aza bicyclo[2.2.1]hepta-2,5-diene as a Nitrido Nitrogen Source by Anthracene Elimination: Synthesis of an Iodide(nitride)chromium(VI) Complex". Angewandte Chemie International Edition. 37 (7): 945–947. doi:10.1002/(SICI)1521-3773(19980420)37:7<945::AID-ANIE945>3.0.CO;2-X. PMID 29711483.
  8. ^ Li, Xiaofeng; Xue, Lin; Tang, Lijuan; Hu, Ziyu (2015). "Pressure modulates the phase stability and physical properties of zinc nitride iodine". RSC Advances. 5 (96): 78754–78759. Bibcode:2015RSCAd...578754L. doi:10.1039/C5RA14426D. ISSN 2046-2069.
  9. ^ Bailey, Andrew S.; Gregory, Duncan H.; Hubberstey, Peter; Wilson, Claire (2007-09-15). "Crystal growth and redetermination of strontium nitride iodide, Sr 2 NI". Acta Crystallographica Section E. 63 (9): i177. Bibcode:2007AcCrE..63I.177B. doi:10.1107/S1600536807039797. ISSN 1600-5368.
  10. ^ a b Yamanaka, Shoji; Itoh, Kojiro; Fukuoka, Hiroshi; Yasukawa, Masahiro (2000-02-01). "High-Pressure Synthesis of the Polymorph of Layer Structured Compounds MNX (M = Zr, Hf; X = Cl, Br, I)". Inorganic Chemistry. 39 (4): 806–809. doi:10.1021/ic991058l. ISSN 0020-1669. PMID 11272580.
  11. ^ Song, Jinyi; Liao, Qian; Hong, Xin; Jin, Li; Mézailles, Nicolas (2021-05-25). "Conversion of Dinitrogen into Nitrile: Cross-Metathesis of N 2 -Derived Molybdenum Nitride with Alkynes". Angewandte Chemie International Edition. 60 (22): 12242–12247. doi:10.1002/anie.202015183. ISSN 1433-7851. PMID 33608987. S2CID 231969654.
  12. ^ Schurz, Christian M.; Niewa, Rainer; Schleid, Thomas (January 2020). "LiLa4N2I7 as the first lithium-containing nitride halide of the lanthanides: Synthesis, crystal structure and spectroscopic characterization". Solid State Sciences. 99: 106047. Bibcode:2020SSSci..9906047S. doi:10.1016/j.solidstatesciences.2019.106047. S2CID 209706784.
  13. ^ a b c d Schurz, Christian M.; Schleid, Thomas (October 2010). "The first quaternary lanthanide(III) nitride iodides: NaM4N2I7 (M=La–Nd)". Journal of Solid State Chemistry. 183 (10): 2253–2260. Bibcode:2010JSSCh.183.2253S. doi:10.1016/j.jssc.2010.07.025.
  14. ^ Mattausch, Hansj Ürgen; Kremer, Reinhard K.; Simon, Arndt (April 1996). "Synthese, Kristallstruktur und magnetische Eigenschaften von Ce15N7I24". Zeitschrift für anorganische und allgemeine Chemie (in German). 622 (4): 649–654. doi:10.1002/zaac.19966220413. ISSN 0044-2313.
  15. ^ a b Fagin, A. A.; Fukin, G. K.; Cherkasov, A. V.; Shestakov, A. F.; Pushkarev, A. P.; Balashova, T. V.; Maleev, A. A.; Bochkarev, M. N. (2016). "Ln 3 I 5 (S 2 N 2 )(S 2 )(THF) 10 – a new type of molecular compounds". Dalton Transactions. 45 (11): 4558–4562. doi:10.1039/C5DT04742K. ISSN 1477-9226. PMID 26842841.
  16. ^ a b Kuzyaev, Dmitry M.; Maleev, Alexander A.; Kulikova, Tatyana I.; Vorozhtsov, Dmitry L.; Bochkarev, Mikhail N. (February 2017). "Reactivity of Neodymium and Samarium Nitrides". Journal of Chemical Research. 41 (2): 82–84. doi:10.3184/174751917X14839766277332. ISSN 1747-5198. S2CID 99205962.
  17. ^ a b c d e Fagin, A. A.; Kuznetsova, O. V.; Rumyantsev, R. V.; Baranov, E. V.; Fukin, G. K.; Bochkarev, M. N. (March 2022). "Lanthanide Iodide Nitride Sulfide Clusters". Russian Journal of Coordination Chemistry. 48 (3): 146–152. doi:10.1134/S1070328422020026. ISSN 1070-3284. S2CID 247387448.
  18. ^ a b Fagin, A. A.; Kuzyaev, D. M.; Burin, M. A.; Kuznetsova, O. V.; Khamaletdinova, N. M.; Kulikova, T. I.; Shestakov, A. F.; Lopatina, T. I.; Vorozhtsov, D. L.; Bochkarev, M. N. (February 2018). "On the Reactivity and Stability of Iodide–Nitride–Sulfide Clusters of Neodymium and Dysprosium". Russian Journal of Coordination Chemistry. 44 (2): 127–131. doi:10.1134/S1070328418020045. ISSN 1070-3284. S2CID 103790629.
  19. ^ a b Fagin, A.A.; Kuznetsova, O.V.; Balashova, T.V.; Cherkasov, A.V.; Fukin, G.K.; Bochkarev, M.N. (January 2018). "Iodide-sulfides of dysprosium: Elucidation of the pathway to lanthanide iodide-sulfide-nitride clusters". Inorganica Chimica Acta. 469: 227–230. doi:10.1016/j.ica.2017.09.030.
  20. ^ a b Fagin, A. A.; Kuznetsova, O. V.; Rumyantcev, R. V.; Fukin, G. K.; Marugin, A. V.; Bochkarev, M. N. (September 2019). "Neodymium–Dysprosium and Neodymium–Ytterbium Iodide–Sulfide–Nitride Clusters: Synthesis and Luminescence". Journal of Cluster Science. 30 (5): 1277–1281. doi:10.1007/s10876-019-01552-5. ISSN 1040-7278. S2CID 146044754.
  21. ^ a b Fagin, A.A.; Kuzyaev, D.M.; Maleev, A.A.; Baranov, E.V.; Rumyantcev, R.V.; Fukin, G.K.; Shestakov, A.F.; Suchkov, A.I.; Marugin, A.V.; Bochkarev, M.N. (May 2019). "Heterolanthanide three-nuclear iodide-sulfide-nitride clusters. Unusual synthesis way and structure". Inorganica Chimica Acta. 490: 200–203. doi:10.1016/j.ica.2019.03.021. S2CID 107891753.
  22. ^ Juza, Robert; Sievers, Rolf (December 1968). "Nitridhalogenide des Thoriums". Zeitschrift für anorganische und allgemeine Chemie (in German). 363 (5–6): 258–272. doi:10.1002/zaac.19683630505. ISSN 0044-2313.
  23. ^ Juza, R.; Meyer, W. (April 1969). "Über Uran-Nitrid-Chlorid, -Bromid und -Jodid". Zeitschrift für anorganische und allgemeine Chemie (in German). 366 (1–2): 43–50. doi:10.1002/zaac.19693660105. ISSN 0044-2313.
Retrieved from "https://en.wikipedia.org/w/index.php?title=Nitride_iodide&oldid=1262760621"