Nitrate nitrite
A nitrate nitrite, or nitrite nitrate, is a coordination complex or other chemical compound that contains both nitrite (NO−2) and nitrate (NO−3) anions. They are mixed-anion compounds, and they are mixed-valence compounds. Some have third anions. Many nitrite nitrate compounds are coordination complexes of cobalt. Such a substance was discovered by Wolcott Gibbs and Frederick Genth in 1857.[citation needed]
Production
[edit]Mercury(II) nitrate and potassium nitrate in water solution produce the salt tripotassium tetranitratomercurate(II) nitrate K3[Hg(NO2)4]NO3.[1]
Properties
[edit]On heating, nitrate nitrites lose NO2 and NO and yield metal oxides.
Related
[edit]Other compounds having an element in two different anion states include the sulfate sulfites, the phosphate phosphites, arsenate arsenites and the selenate selenites.
List
[edit]name | formula | ratio NO3:NO2 | mw | system | space group | unit cell Å | volume | density | properties | references |
---|---|---|---|---|---|---|---|---|---|---|
[Cr(NH3)5(NO2)] ·(NO3)2 | [2] | |||||||||
trans-dinitrotetraamminecobalt(III) nitrate monohydrate | [Co(NO2)2(NH3)4]NO3•H2O | 1:2 | orthorhombic | P212121 | a=10.02, b=6.02, c=16.84, Z=4 | 1.84 | [3] | |||
cis-dinitrotetraamminecobalt(III) nitrate | [Co(NO2)2(NH3)4]NO3 | 1:2 | orthorhombic | P212121 | a=12.19, b=7.18, c=10.92, Z=4 | 1.95 | [4] | |||
[cis-β-Co(trien)(NO2)2]NO3 | 1:2 | monoclinic | P21/n | a = 7.604, b = 13.019, c = 14.472, β = 98.13°, Z = 4 | 1418.26 | 1.682 | racemate | [5] | ||
[cis-α-Co(tren)(NO2)2]NO3•13H2O | 1:2 | P21/c | [6] | |||||||
trans-Co[(en2)(NO2)2]NO3 | 1:2 | [7] | ||||||||
trans-[Co(2,3,2-tet)(NO2)2]NO3 | 1:2 | 373.21 | P21/n | a=8.490, b=8.884, c=18.580 and β=95.08°;, Z=4 | 1395.89 | 1.776 | [8] | |||
trans-[Co(2,3,2-tet)(NO2)2]NO3 | 373.21 | Pn | a=6.493, b=11.731, c=9.325 β=100.13°; M.W.=373.21, Z=2)= | 699.21 | 1.773 | [8] | ||||
cis-[Co(Hao)2(NO2)2]NO3 (Hao = 3-amino-3-methyl-2-butanone oxime) | monoclinic | P21/n | a= 8.1 60, b= 17.250, c= 13.745, β= 104.77° | [9] | ||||||
[Co(pic)2(NO2)2]NO3.½H2O pic=2-picolylamine | [10] | |||||||||
cis-[Co(phen)2(NO2)2]NO3 · 2 H2O phen=1,10-phenanthroline | [11] | |||||||||
Sparteine copper(II) nitrate nitrite | Cu(C15H26N2)(NO3)(NO2) | 1:1 | green | [12] | ||||||
trans-diammine-cis-dinitratonitronitrosyl ruthenium(II) | RuNO(NH3)2(NO3)2(NO2) | |||||||||
bis(nitrotriamminepalladium(II)) tetraamminepalladium(II) tetranitrate | [Pd(NO2)(NH3)3]2[Pd(NH3)4](NO3)4 | 4:1 | 829.20 | tetragonal | I42m | a=7.637 c=21.610 Z=2 | 2.18 | bright yellow | [13] | |
bis(1,10-Phenanthroline)-(nitroso-O)-(nitrato-O,O')-cadmium(ii) | Cd(phen)2(NO3)(NO2) | monoclinic | P21/c | a 6.872 b 9.690 c 20.852 β 93.59° | [14] | |||||
catena-((μ2-Nitroso-O,O')-aqua-(nitrato-O,O')-(1,10-phenanthroline)-cadmium(ii)) | [Cd(phen)(NO3)(NO2)(H2O)]n | monoclinic | Cc | a 11.703Å b 15.242 c 13.451 β 106.321° | [14] | |||||
[NO2(NH3)2Pt(C5H4NO)2Pt(NH3)2NO2](NO3)2.H2O | yellow | [15] | ||||||||
K3[Hg(NO2)4]NO3 | 1:4 | orthorhombic | Pnma | a=12.12 b=10.58 c=9.28 Z=4 | 3.14 | pale yellow | [1] | |||
Pb2(NO2)(NO3)(SeO3) | 1:1 | orthorhombic | Pmn21 | a=5.529, b=10.357, c=6.811, Z=2 | 390 | colourless | [16] | |||
K2Pb(NO2)3(NO3) | 1:3 | 503.4 | orthorhombic | Pbca | a = 6.766, b = 11.999, c = 26.61, Z = 8 | 2160 | 3.095 | yellow orange | [17] | |
[Pb3(OH)4Co(NO2)3](NO3)(NO2)·2H2O | 1:4 | orthorhombic | Pbca | a = 8.9414, b = 14.5330, c = 24.9383, Z = 8 | 3240.6 |
References
[edit]- ^ a b Hall, D.; Holland, R.V. (January 1969). "The crystal structure of K3[Hg(NO2)4]NO3". Inorganica Chimica Acta. 3: 235–238. doi:10.1016/S0020-1693(00)92486-1.
- ^ Shepard, Whiting N.; Forster, Leslie S. (1971). "The2 E?4 A 2 transition in tetragonal Cr3+ complexes". Theoretica Chimica Acta. 20 (2): 135–142. doi:10.1007/BF00569260. ISSN 0040-5744. S2CID 95534463.
- ^ Oonishi, Isao; Muto, Fumio; Komiyama, Yoshimichi (October 1969). "The Molecular and Crystal Structure of trans -Dinitrotetramminecobalt(III) Nitrate Monohydrate". Bulletin of the Chemical Society of Japan. 42 (10): 2791–2796. doi:10.1246/bcsj.42.2791. ISSN 0009-2673.
- ^ Oonishi, Isao; Fujimaki, Hiroto; Muto, Fumio; Komiyama, Yoshimichi (March 1970). "The Crystal Structure of cis -Dinitrotetraamminecobalt (III) Nitrate". Bulletin of the Chemical Society of Japan. 43 (3): 733–739. doi:10.1246/bcsj.43.733. ISSN 0009-2673.
- ^ Bernal, Ivan; Cetrullo, James (October 1986). "The phenomenon of conglomerate crystallization. VII. Clavic dissymmetry in coordination compounds.V. An investigation of the crystallization behavior of [cis-β-Co(triethylenetetramine)(NO2)2]X (X = I, NO3) and the crystal structure of racemic [cis-β-Co(trien)(NO2)2]NO3". Inorganica Chimica Acta. 120 (2): 109–117. doi:10.1016/S0020-1693(00)86096-X.
- ^ Bernal, Ivan; Cetrullo, James; Myrczek, Jozef (October 1993). "The phenomenon of conglomerate crystallization Part XXXI. The crystallization behavior of [cis-Co(en)2(NO2)2Br and of : counter-ion effects on crystallization pathway of racemate solutions". Materials Chemistry and Physics. 35 (3–4): 290–300. doi:10.1016/0254-0584(93)90145-C.
- ^ Charpeutier, T.; Virlet, J. (October 1998). "Triple quantum MQMAS spectroscopy of (I=7/2) in Na3Co(NO2)6 and trans-Co[(en2)(NO2)2]NO3 interplay between the quadrupole coupling and anisotropic shielding tensors". Solid State Nuclear Magnetic Resonance. 12 (4): 227–242. doi:10.1016/S0926-2040(98)00051-4. PMID 9800268.
- ^ a b Bernal, Ivan; Somoza, Fernando; Chen, Ya-Chen; Massoud, Salah S. (April 1997). "The Phenomenon of Conglomerate Crystallization. Part 48. Two Polymorphs of Racemic Trans-[Co(2,3,2-Tet) (No2)2]No3(I and Ii)". Journal of Coordination Chemistry. 41 (3): 233–247. doi:10.1080/00958979708023574. ISSN 0095-8972.
- ^ Murray, Don E.; Schlemper, Elmer O.; Siripaisarnpipat, Sutatip; Murmann, R. Kent (1986). "A structural and isotopic NO 2 – exchange rate comparison of trans-[Co(ao–H–ao)(NO 2 ) 2 ] and cis-[Co(Hao) 2 (NO 2 ) 2 ]NO 3". J. Chem. Soc., Dalton Trans. (9): 1759–1765. doi:10.1039/DT9860001759. ISSN 0300-9246.
- ^ Sutton, Gj (1960). "Some Studies in Inorganic Complexes. VIII. Cobalt(II) and Cobalt(III) with 2-Picolylamine". Australian Journal of Chemistry. 13 (4): 473. doi:10.1071/CH9600473. ISSN 0004-9425.
- ^ Ghaschghaie, Natascha (2010). "HETEROLEPTISCHE COBALT(III)-CHELATKOMPLEXE MIT BIOLIGANDEN" (PDF).
- ^ Lee, Yong-Min; Kim, Yong-Kyu; Jung, Hee-Cheul; Kim, Young-Inn; Choi, Sung-Nak (2002-03-20). "Copper(II) Oxyanion Complexes Derived from Sparteine Copper(II) Dinitrate: Synthesis and Characterization of 4- and 5-Coordinate Copper(II) Complexes". Bulletin of the Korean Chemical Society. 23 (3): 404–412. doi:10.5012/BKCS.2002.23.3.404.
- ^ Boer, F. Peter; Carter, Virginia B.; Turley, June W. (April 1971). "Single-crystal x-ray and Raman studies of bis(nitrotriamminepalladium(II)) tetraamminepalladium(II) tetranitrate". Inorganic Chemistry. 10 (4): 651–661. doi:10.1021/ic50098a001. ISSN 0020-1669.
- ^ a b Fan, Ruiqing; Zhang, Yanjiao; Yin, Yanbin; Su, Qing; Yang, Yulin; Hasi, Wuliji (June 2009). "Syntheses, structures, and luminescent properties of cadmium (II) complexes: 3D supramolecular [Cd(phen)(NO3)(NO2)(H2O)]n and Cd(phen)2(NO3)(NO2) constructed by π–π stacking interactions". Synthetic Metals. 159 (11): 1106–1111. doi:10.1016/j.synthmet.2009.04.007.
- ^ Hollis, L. Steven; Lippard, Stephen J. (May 1982). "Effect of axial ligands on the platinum-platinum bond in binuclear .alpha.-pyridonate-bridged platinum(III) complexes. Structures of [X(NH3)2Pt(C5H4NO)2Pt(NH3)2X](NO3)2.H2O, X = NO3, NO2". Inorganic Chemistry. 21 (5): 2116–2117. doi:10.1021/ic00135a087. ISSN 0020-1669.
- ^ Effenberger, Herta (February 1987). "Darstellung und Kristallstruktur von Pb2(NO2)(NO3)(SeO3)". Monatshefte für Chemie. 118 (2): 211–216. doi:10.1007/BF00810054. S2CID 101945551.
- ^ Nardelli, Mario; Pelizzi, Giancarlo (January 1980). "Crystal structure of K2Pb(NO2)3(NO3)·H2O". Inorganica Chimica Acta. 38: 15–19. doi:10.1016/S0020-1693(00)91928-5.
HNO2 | He | ||||||||||||||||||
LiNO2 | Be(NO2)2 | B | C(NO2)4, CH(NO2)3, CH2(NO2)2, CH3(NO2) | N(NO2)3 H2NNO2 xNO3NO2 | N2O3 | NO2F | Ne | ||||||||||||
NaNO2 | Mg(NO2)2 | Al(NO2)3 | Si | P | S | NO2Cl | Ar | ||||||||||||
KNO2 | Ca(NO2)2 | Sc(NO2)3 | Ti | VO(NO2)3 | Cr(NO2)3 | Mn(NO2)2 | Fe(NO2)3 | Co(NO2)2, Co(NO2)3 | Ni(NO2)2 | Cu(NO2)2 | Zn(NO2)2 | Ga(NO2)3 | Ge | As | Se | NO2Br | Kr | ||
RbNO2 | Sr(NO2)2 | Y(NO2)3 | Zr | Nb | Mo | Tc | Ru | Rh | Pd(NO2)2 | AgNO2 | Cd(NO2)2 | In | Sn | Sb | Te | NO2I | Xe | ||
CsNO2 | Ba(NO2)2 | Hf | Ta | W | Re | Os | Ir | Pt(NO2)2, [Pt(NO2)4]2− | Au | Hg2(NO2)2, Hg(NO2)2 | TlNO2 | Pb(NO2)2 | Bi(NO2)3 BiO(NO2) | Po | At | Rn | |||
Fr | Ra | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||
↓ | |||||||||||||||||||
La(NO2)3 | Ce(NO2)3 | Pr(NO2)3 | Nd(NO2)3 | Pm | Sm(NO2)3 | Eu(NO2)2 | Gd(NO2)3 | Tb | Dy | Ho | Er | Tm | Yb | Lu | |||||
Ac | Th | Pa | UO2(NO2)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr |