Ammonium hexafluoroantimonate

Ammonium hexafluoroantimonate
Names
IUPAC name
azanium;hexafluoroantimony(1-)
Other names
Ammonium antimony fluoride
Identifiers
3D model (JSmol)
  • InChI=1S/6FH.H3N.Sb/h6*1H;1H3;/q;;;;;;;+5/p-5
    Key: ZPHCPPBIGJXZTF-UHFFFAOYSA-I
  • [NH4+].F[Sb-](F)(F)(F)(F)F
Properties
F6H4NSb
Molar mass 253.789 g·mol−1
Appearance White crystalline powder
Density g/cm3
soluble
Hazards
GHS labelling:
GHS02: FlammableGHS06: Toxic
Danger
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ammonium hexafluoroantimonate is an inorganic chemical compound with the chemical formula NH4SbF6.[1][2]

Synthesis

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Also, a reaction of antimony pentafluoride and ammonium hexafluoromanganate:

4SbF5 + 2(NH4)2MnF6 → NF4SbF6 + 2MnF3 + F2

Physical properties

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It is soluble in water. It can form needle-shaped or columnar crystals.

Uses

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The compound is used in fine chemistry and organic synthesis, for example as a catalyst, and can replace organic fluorides. [3]

References

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  1. ^ "CAS 52503-06-7 Ammonium hexafluoroantimonate - Alfa Chemistry". alfa-chemistry.com. Retrieved 31 August 2024.
  2. ^ Ma, Hailing; Zhang, Xin; Ju, Feifei; Tsai, Sang-Bing (14 February 2018). "A Study on Curing Kinetics of Nano-Phase Modified Epoxy Resin". Scientific Reports. 8 (1): 3045. Bibcode:2018NatSR...8.3045M. doi:10.1038/s41598-018-21208-0. ISSN 2045-2322. PMC 5813017. PMID 29445228.
  3. ^ Organometallic Compounds. R. H. Chandler. 1976. p. 180. Retrieved 31 August 2024.