乙基沙林 - 维基百科,自由的百科全书
乙基沙林 | |
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IUPAC名 Propan-2-yl ethylphosphonofluoridate | |
别名 | GE、EA-1209、 TL-1620、T-2109、 异丙基-P-乙基膦酰氟 |
识别 | |
CAS号 | 1189-87-3 ![]() |
PubChem | 65566 |
ChemSpider | 59009 |
SMILES |
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性质 | |
化学式 | C5H12FO2P |
摩尔质量 | 154.12 g·mol−1 |
密度 | 1.1012 g·cm−3(20 °C)[1] |
沸点 | 74 °C(16 torr)[2] 91~93 °C(40 torr)[1] 170 °C |
蒸氣壓 | 1.97 mmHg |
危险性 | |
主要危害 | 剧毒 |
致死量或浓度: | |
LD50(中位剂量) | 690 mg/kg(鼠,腹膜内)[3] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
乙基沙林(GE),又称EA-1209、[4] TL-1620或T-2109,[5]是G系列中的一种有机磷神经性毒剂。它是沙林的乙氟膦酸类似物。[6][7]有文献对其谱图及反应性做了研究。[8][9]它的毒性是沙林的八分之一,但持久性比沙林高2-3倍。[10][11]
参考文献
[编辑]- ^ 1.0 1.1 Drozd, G. I.; Ivin, S. Z.; Kulakova, V. N.; Sheluchenko, V. V. Alkoxyalkyl(aryl)difluoromonohydridophosphoranes. Zhurnal Obshchei Khimii, 1968. 38 (3): 576-581. ISSN 0044-460X.
- ^ R. Schmutzler. 868. Phosphorus–fluorine chemistry. Part VIII. Some comments on the “group shift theory,” as applied to the 31 P nuclear magnetic resonance spectra of certain phosphorus fluorides. J. Chem. Soc. 1964, 0 (0): 4551–4557 [2022-03-02]. ISSN 0368-1769. doi:10.1039/JR9640004551 (英语).
- ^ ChemIDplus. [2022-03-01]. (原始内容存档于2022-03-01).
- ^ Physical properties of standard agents, candidate agents, and related compounds at several temperatures (PDF). [2022-03-01]. (原始内容 (PDF)存档于2017-02-26).
- ^ Chemical Warfare Agents, and Related Chemical Problems. Parts I-II. [2022-03-01]. (原始内容存档于2021-12-12).
- ^ Handbook of chemical and biological warfare agents 2nd. CRC Press. ISBN 9780849314346.
- ^ Compendium of chemical warfare agents. Springer. ISBN 9780387346267.
- ^ David J. McGarvey, John R. Stuff, Barry R. Williams, H. Dupont Durst. Vapor-Phase Infrared Spectral Study of Analogs of the Nerve Agent Sarin. Spectroscopy Letters. 2000-11, 33 (6): 795–819 [2022-03-02]. ISSN 0038-7010. doi:10.1080/00387010009350158 (英语).
- ^ Neimysheva, A. A.; Knunyants, I. L. Spectral characteristics and reactivity of carboxylic, phosphonic, phosphinic, and sulfonic acid halides. Reaktsionnaya Sposobnost Organicheskikh Soedinenii, 1968. 5 (1): 127-140. ISSN 0375-9520.
- ^ Franks, S. Manual of Military Chemistry. Volume 1. Chemistry of Chemical Warfare Agents.. Assistant Chief of Staff for Intelligence (Army), Washington, D.C. 1968: 247 [2024-01-03]. (原始内容存档于2023-05-29).
- ^ Department Of The Army Office Of The Chief, Chemical Corps. CMLWH. A1.13 - RLF/TSE/5190/blac. 17 February 1948.
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