French
DeutschPlutonium(III) iodide
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| Identifiers | |
|---|---|
3D model (JSmol) | |
PubChem CID | |
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| Properties | |
| Appearance | green solid[1] |
| Density | 6.92 g·cm−3[2] |
| Melting point | 777 °C[1] |
| Structure | |
| orthorhombic | |
| Ccmm (No. 63) | |
| Related compounds | |
Other anions | plutonium(III) hydride plutonium(III) fluoride plutonium(III) chloride plutonium(III) bromide |
Other cations | neptunium(III) iodide americium(III) iodide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Plutonium(III) iodide is the iodide of plutonium with the chemical formula PuI3.
Preparation
[edit]Plutonium(III) iodide can be formed by the reaction of plutonium and mercury(II) iodide:[3]
- 2 Pu + 3 HgI2 → 2 PuI3 + 3 Hg
It can also be produced by reacting plutonium and hydrogen iodide at 450 °C. Even if there is only a small amount of oxygen and water in the reaction, the generated plutonium(III) iodide will immediately hydrolyze into plutonium iodide oxide.[3]
- 2 Pu + 6 HI → 2 PuI3 + 3 H2
Properties
[edit]Plutonium(III) iodide is a green solid with a melting point of 777 °C. It is orthorhombic (plutonium(III) bromide structure), space group Ccmm (No. 63), lattice parameters a = 433 pm, b = 1395 pm and c = 996 pm.[2]
References
[edit]- ^ a b Holleman, Arnold Frederik; Wiberg, Egon (2001), Wiberg, Nils (ed.), Inorganic Chemistry, translated by Eagleson, Mary; Brewer, William, San Diego/Berlin: Academic Press/De Gruyter, p. 1969, ISBN 0-12-352651-5
- ^ a b c d e Gmelins Handbuch der anorganischen Chemie, System Nr. 71, Transurane, Teil C, S. 154–155.
- ^ a b Georg Brauer (Hrsg.), unter Mitarbeit von Marianne Baudler u. a.: Handbuch der Präparativen Anorganischen Chemie. 3., umgearbeitete Auflage. Band II, Ferdinand Enke, Stuttgart 1978, ISBN 3-432-87813-3, S. 1304.
External reading
[edit]- Clark, David L.; Hecker, Siegfried S.; Jarvinen, Gordon D.; Neu, Mary P. (2006), Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean (eds.), "Plutonium", The Chemistry of the Actinide and Transactinide Elements, Dordrecht: Springer Netherlands, pp. 813–1264, doi:10.1007/1-4020-3598-5_7, ISBN 978-1-4020-3555-5, retrieved 2023-09-15